靛蓝染料废水的处理研究

采用膜技术和絮凝方法处理牛仔布印染过程中的生产废水。对经处理后的水色度和COD的去除进行了比较。膜法处理后的水要优于絮凝处理后的水，可回用于生产。     

2004年上半年染料、有机颜料生产及进出口情况浅析

20 0 4年上半年 ,染料和有机颜料工业主要经济指标完成情况良好 ,进出口数量和经济效益继续保持稳定增长。 2 0 0 4年上半年染料产量总计为 2 94 377t,同期比增长 17 4 % ;有机颜料产量为 5 3816t,同期比增长16 4 %。染料出口 10 816 3 9t,同期比增长 9 1% ;有机颜料出口 5 0 85 7 2t,同期比增长 2 1 1%。染料进口 332 2 6 3t,同期比增长 2 1% ;有机颜料进口 16 6 10 5t,同期比下降 1 9%。进口增速稳中有降。     

靛蓝染液组分浓度在线检测系统

为实现靛蓝染液组分浓度的在线检测,提高检测的准确度和精确度,设计开发了采用电位滴定法在线实时检测靛蓝染液中各组分浓度的系统。系统以工控机为核心,基于研华板卡PCI1710,在C#环境下,实现工控机对设备的控制以及对检测数据的采集,采用二阶微商法确定电位滴定的终点。通过对检测结果的分析可知误差在2%以内,说明系统可以满足工业生产的需要。     

分光光度法测定含氯矿物中微量硝酸根

目前用于测定硝酸根的方法较多,但对于含氯矿物中微量硝酸根的测定新方法尚未见报道。基于在硫酸介质中,硝酸根对靛蓝二磺酸钠的氧化作用,使靛蓝二磺酸钠发生褪色反应,而且褪色程度与硝酸根含量呈线性关系,建立了分光光度法测定含氯矿物中微量硝酸根的新方法,并对存在的相关问题进行了探讨。该方法硝酸根在0~1.2μg/mL符合朗伯—比耳定律,摩尔吸光系数ε=5.3×103L/(mol.cm),标准偏差S=0.003 87(RSD,n=6);平均回收率可达99.3%。方法简便、快速、准确,用于含氯矿物中微量硝酸根测定,结果满意。     

A Catalytic Nanoreactor Based on in Vivo Encapsulation of Multiple Enzymes in an Engineered Protein Nanocompartment

Bacterial protein compartments concentrate and sequester enzymes, thereby regulating biochemical reactions. Here, we generated a new functional nanocompartment in Escherichia coli by engineering the MS2 phage capsid protein to encapsulate multiple cargo proteins. Sequestration of multiple proteins in MS2‐based capsids was achieved by SpyTag/SpyCatcher protein fusions that covalently crosslinked with the interior surface of the capsid. Further, the functional two‐enzyme indigo biosynthetic pathway could be targeted to the engineered capsids, leading to a 60 % increase in indigo production in vivo. The enzyme‐loaded particles could be purified in their active form and showed enhanced long‐term stability in vitro (about 95 % activity after seven days) compared with free enzymes (about 5 % activity after seven days). In summary, this engineered in vivo encapsulation system provides a simple and versatile way for generating highly stable multi‐enzyme nanoreactors for in vivo and in vitro applications.     

水滑石焙烧产物对阴离子染料靛蓝胭脂红的吸附特性

碳酸根型水滑石焙烧产物对阴离子染料具有特异的吸附性能。该研究考察了两种具有不同镁铝摩尔比的镁铝复合氧化物对靛蓝胭脂红的吸附性能,并探讨了焙烧温度、投加量、初始染料浓度、溶液初始pH以及共存阴离子这几个因素的影响。结果表明经过500℃焙烧处理后的水滑石对染料的去除效果最好,去除率高达95%,平衡吸附量高达811.5 mg/g（1.74 mmol/g）;且吸附过程不受初始溶液pH和共存阴离子的影响。水滑石焙烧产物直接用于印染废水处理,脱色率达68%~84%。     

Dressed in Blue: The Impact of Woad on English Clothing,c. 1350–c. 1670

Abstract

This paper seeks to explore the changing importance of blue colours, blue dyes and woad in particular in England in the late Middle Ages and early modern period. It does so by considering six themes — the popularity and fashionability of blue; blue and its significance within the Order of the Garter; blue as a colour worn by the lower social groups and its association with poverty and livery; colour symbolism of blue; blue and court entertainments; blue and the liturgy — but it will start with a review of blue colours and blue dyes.     

Photocatalytic degradation of indigo carmine dye using TiO<Subscript>2</Subscript> impregnated activated carbon

The photocatalytic degradation of indigo carmine dye was studied using hydrothermally prepared TiO₂ impregnated activated carbon (TiO₂: AC). A comparison between the degradation of the indigo carmine dye using commercial TiO₂ and TiO₂: AC revealed the efficiency of the title compound. The degradation reaction was optimized with respect to the dye concentration and catalyst amount. The reduction in the chemical oxygen demand (COD) revealed the mineralization of dye along with colour removal. The active compound like TiO₂ was impregnated onto the activated carbon surface under mild hydrothermal conditions (<250°C, P ∼ 40 bars). The impregnated activated carbon samples were characterized using powder X-ray diffraction (XRD) and scanning electron microscope (SEM).     

牛仔水洗条件与靛蓝沾色的关系

模拟生产实际情况，收集纯靛蓝牛仔布水洗残液进行靛蓝染料的再沾色试验。通过测定白衬布的R值，定量分析沾色的程度，研究了水洗温度、pH值、纤维素酶种类、表面活性剂以及水洗时间对沾色的影响。结果表明，影响靛蓝再沾色的主要因素是纤维素酶种类、表面活性剂以及水洗时间，而温度、pH值的影响较小。     

金纳米粒子改性靛蓝染料的制备及性能研究

以2-硝基苯甲醛为稳定剂制备了金纳米粒子,进而合成了金纳米粒子改性靛蓝染料,通过X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、紫外分光光度计(UV-vis)等确认了其结构。对染色棉织物进行了上染率、力学性能和抗菌性能等测试。研究结果表明:金纳米粒子改性靛蓝对棉织物的染色性能优于商业靛蓝,经其染色的棉织物具有良好的抗菌性能,对金黄色葡萄球菌与大肠杆菌的抑菌率分别为95%和90%。