全文获取类型
收费全文 | 4371篇 |
免费 | 220篇 |
国内免费 | 86篇 |
专业分类
电工技术 | 49篇 |
综合类 | 206篇 |
化学工业 | 2584篇 |
金属工艺 | 76篇 |
机械仪表 | 145篇 |
建筑科学 | 59篇 |
矿业工程 | 31篇 |
能源动力 | 101篇 |
轻工业 | 816篇 |
水利工程 | 2篇 |
石油天然气 | 280篇 |
武器工业 | 18篇 |
无线电 | 39篇 |
一般工业技术 | 234篇 |
冶金工业 | 24篇 |
原子能技术 | 5篇 |
自动化技术 | 8篇 |
出版年
2024年 | 17篇 |
2023年 | 36篇 |
2022年 | 75篇 |
2021年 | 80篇 |
2020年 | 86篇 |
2019年 | 107篇 |
2018年 | 87篇 |
2017年 | 114篇 |
2016年 | 151篇 |
2015年 | 129篇 |
2014年 | 192篇 |
2013年 | 220篇 |
2012年 | 322篇 |
2011年 | 292篇 |
2010年 | 218篇 |
2009年 | 230篇 |
2008年 | 202篇 |
2007年 | 232篇 |
2006年 | 285篇 |
2005年 | 232篇 |
2004年 | 222篇 |
2003年 | 169篇 |
2002年 | 157篇 |
2001年 | 142篇 |
2000年 | 142篇 |
1999年 | 110篇 |
1998年 | 80篇 |
1997年 | 75篇 |
1996年 | 67篇 |
1995年 | 46篇 |
1994年 | 40篇 |
1993年 | 29篇 |
1992年 | 28篇 |
1991年 | 13篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有4677条查询结果,搜索用时 0 毫秒
1.
Carboxyl‐terminated butadiene‐acrylonitrile rubber (CTBN) has often been used to improve the toughness of cyanate ester (CE) resin while sacrificing modulus and thermostability. In this paper, the addition of the appropriate amount of epoxy resin (EP) to the CE/CTBN system is shown to not only increase the modulus and thermostability of the blend, but also improve the toughness. The values of impact strength showed a maximum for the CE/CTBN/EP 100/5/5 blend. The temperature of 10 % weight loss (T10) improves from 376 °C for CE/CTBN 100/5 to 407 °C for the CE/CTBN/EP 100/5/2.5 blend. It is proposed that addition of the appropriate amount of EP can decrease the mobility and increase the stability of CTBN via the reaction between the terminal carboxyl group of CTBN and the hydroxyl group of EP. But a very high EP concentration will decrease the crosslinking density of CE, consequently reducing the mechanical properties and thermostability of the blends. Copyright © 2004 Society of Chemical Industry 相似文献
2.
A series of new alternating aromatic poly(ester‐imide)s were prepared by the polycondensation of the preformed imide ring‐containing diacids, 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl (2a) and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl (2b) with various aromatic dihydroxy compounds in the presence of pyridine and lithium chloride. A model compound (3) was also prepared by the reaction of 2b with phenol, its synthesis permitting an optimization of polymerization conditions. Poly(ester‐imides) were fully characterized by FTIR, UV‐vis and NMR spectroscopy. Both biphenylene‐ and binaphthylene‐based poly(ester‐imide)s exhibited excellent solubility in common organic solvents such as tetrahydrofuran, m‐cresol, pyridine and dichloromethane. However, binaphthylene‐based poly(ester‐imide)s were more soluble than those of biphenylene‐based polymers in highly polar organic solvents, including N‐methyl‐2‐pyrrolidone, N,N‐dimethylacetamide, N,N‐dimethylformamide and dimethyl sulfoxide. From differential scanning calorimetry thermograms, the polymers showed glass‐transition temperatures between 261 and 315 °C. Thermal behaviour of the polymers obtained was characterized by thermogravimetric analysis, and the 10 % weight loss temperatures of the poly(ester‐imide)s was in the range 449–491 °C in nitrogen. Furthermore, crystallinity of the polymers was estimated by means of wide‐angle X‐ray diffraction. The resultant poly(ester‐imide)s exhibited nearly an amorphous nature, except poly(ester‐imide)s derived from hydroquinone and 4,4′‐dihydroxybiphenyl. In general, polymers containing binaphthyl units showed higher thermal stability but lower crystallinity than polymers containing biphenyl units. Copyright © 2005 Society of Chemical Industry 相似文献
3.
Tatsuro Kijima Kouji Ohshima Hideo Kise 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1994,59(1):61-65
Racemic amino acid esters were optically resolved via hydrolysis in organic solvents by the catalysis of an industrial alkaline protease, “Alcalase”. The products which were composed mainly of L-amino acids were insoluble and easily separated by filtration. The activity of the enzyme and enantiomeric excess of the products were significantly dependent on the nature of solvent and the water content in the reaction media. Generally, high values of enantiomeric excess were obtained at low water contents. Many natural and unnatural amino acids were resolved by this method. 相似文献
4.
Wax esters enriched in ω-3 fatty acids have been recently shown to be readily absorbed by rats after dietary supplementation. Wax esters are less prone to oxidation and can be better formulated than liquid ω-3 derivatives. All these characteristics suggest a possible use of wax esters enriched in ω-3 as food supplements. However, some naturally occurring wax esters are defined as scarcely digestible (jojoba oil, spermaceti). On the other hand, wax esters have been found in several sources of marine origin, which can enter normal foodstuff. In order to better understand the digestibility of wax esters, we have analysed some foods from marine sources. The content of triglycerides and wax esters of the foods has been determined. Moreover, wax esters have been analysed for their composition in alcohols and fatty acids. Wax esters have been shown to be a part of the neutral lipid extract of the foods analysed. Their content, if compared with the content in triglycerides, shows striking differences. In the case of two botargo preparations, it has been shown that wax esters are more than 90% of the total neutral lipid extract. The content of fatty acids and alcohols found in the foods analysed is consistent with published data. 相似文献
5.
A. Domingue K. Piyakis E. Sacher M. Di Renzo S. D nomm e T. H. Ellis 《The Journal of Adhesion》1993,40(2):151-162
The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer. 相似文献
6.
以DRC为催化剂,在无溶剂条件下,通过氢化松香与乙醇的直接酯化反应合成氢化松香乙酯。探索了反应温度、催化剂用量、反应时间、物料配比等因素对反应酯化率的影响,确定最佳反应条件为:反应温度180℃,催化剂用量为原料氢化松香质量的6%,反应时间6h,醇与酸的摩尔比为3∶1。在最佳条件下酯化率达92.2%。还探讨了用阴离子交换树脂柱层析分离纯化氢化松香乙酯粗产物的方法。此外,利用红外光谱对氢化松香乙酯精制产物进行了表征;用GC-MS分别对氢化松香乙酯粗产物及其精制产物进行了定性和定量分析,比较了柱层析前后化学组成的变化。 相似文献
7.
A rapid test to measure performance,emission and wear of a diesel engine fueled with palm oil diesel
H. Masjuki A. M. Zaki S. M. Sapuan 《Journal of the American Oil Chemists' Society》1993,70(10):1021-1025
Results of performance, emission and tribological evaluations of palm oil methyl ester and its blends with conventional diesel
in an automobile diesel engine test bed are presented. Polymerization and carbon deposits on the fuel injector were monitored.
CO, CO2, O2, combustion efficiency and temperature of exhaust gases were also measured. Palm oil methyl ester and its blends have great
potential as alternative diesel fuel. Performance and exhaust gas emission for palm oil methyl ester and its blends with conventional
diesel are comparable with those of conventional diesel fuel. Palm oil methyl ester does not pose a severe environmental problem
and will not deteriorate engine and bearing components. 相似文献
8.
Kanit Krisnangkura 《Journal of the American Oil Chemists' Society》1991,68(1):56-58
Equations were developed for the estimation of gross heat of combustion (HG) of triglycerides (TGs) and fatty acid methyl
esters (FAMEs) from their saponification number (SN) and iodine value (IV). HG of TG=1,896,000/SN − 0.6 IV — 1600 and HG of
FAME=618,000/SN − 0.08 IV — 430. When these equations were tested on cottonseed oil, soybean oil, partially hydrogenated soybean
oil, peanut oil, sunflower oil, sunflower oil methyl esters, soybean oil methyl esters and cottonseed oil methyl esters, predicted
HG values agreed well with those reported in the literature. 相似文献
9.
Paula Relgio Marie-Thrse Charreyre Jos Paulo S. Farinha Jos M.G. Martinho Christian Pichot 《Polymer》2004,45(26):8639-8649
N,N-dimethylacrylamide (DMA) and N-acryloxysuccinimide (NAS) were copolymerized by the reversible addition–fragmentation chain transfer (RAFT) polymerization technique, to obtain random and block copolymer precursors onto which different side-groups may be statistically grafted via the reactive NAS units. These reactive copolymers have interesting applications in various fields such as coatings and paints, water purification and biology. Random poly(DMA-co-NAS) copolymer chains were synthesized with a 75/25 molar ratio, high conversion, an excellent molecular weight (MW) control from 5000 to 130 000 g mol−1, and low polydispersity index (Mw/Mn<1.1). Poly(DMA-b-NAS) block copolymers were synthesized by a two step method, in which a poly(DMA) homopolymer was prepared first and then used as macro-chain transfer agent to polymerize NAS. For example, a poly(DMA-b-NAS) sample was obtained with an average molecular weight of 44 300/7400 g mol−1 corresponding to 447 DMA and 44 NAS units. Such block copolymers had not yet been synthesized by any controlled polymerization technique. They can be used to prepare polymers with exactly the same backbone and an increasing number of different side groups (e.g. hydrophobic, ionic or fluorescent). 相似文献
10.
Keiichi Honda 《Journal of chemical ecology》1981,7(6):1089-1113
The larval osmeterial secretions of sixPapilio species examined displayed a remarkable qualitative change at the fourth larval ecdysis. The secretions of 4th (penultimate) instar larvae ofP. machaon, P. memnon, P. helenus, P. bianor, andP. maackii principally comprised mono- and/or sesquiterpenoids. The compounds identified from these species included -pinene, sabinene, -myrcene, limonene, -phellandrene, (Z)--ocimene, (E)--ocimene, -elemene, -caryophyllene, (E)--farnesene, -selinene, (E,E)--farnesene, germacrene-A, germacrene-B, caryophyllene oxide, methyl 3-hydroxy-n-butyrate, and acetic acid. In contrast, the secretion of 4th larval instar ofP. xuthus, although containing similar terpenic compounds, was accompanied by large amounts of aliphatic acids and their esters: isobutyric acid, 2-methylbutyric acid, methyl isobutyrate and methyl 2-methylbutyrate. On the other hand, the osmeterial secretions of 5th (last) instar larvae varied little in quality among the six species, and the identified compounds consisted of isobutyric acid, 2-methylbutyric acid, methyl isobutyrate, ethyl isobutyrate, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, and isovaleric acid, the last of which was specific toP. bianor andP. maackii. The chemical alteration of osmeterial exudate synchronized at the final larval ecdysis with the larval morphological change (particularly in body coloration) that appears to be of defensive significance against predators. 相似文献