Thermal degradation of corn starch based biodegradable plastic plates and determination of kinetic parameters by isoconversional methods using thermogravimetric analyzer

Oil shortage and awareness of environment pollution leads to the extensive use of biodegradable starch-based materials against synthetic plastics. The accumulated wastes of these plastics takes more time for natural recycling and the process is complex. Therefore the best option of recycling would be to convert these polymers into a source of energy by pyrolysis. So to understand the pyrolytic behaviour, kinetics of such waste plastics is studied by using thermogravimetric analysis at different heating rates of 10 °C, 20 °C, 40 °C, 60 °C, 80 °C and 100 °C in nitrogen atmosphere followed by characterization of the pyrolysis products. The kinetic parameters are obtained for two major stages of decomposition in two different temperature ranges 250–620 °C and 620–855 °C by iso-conversional methods such as Friedman, Coats-Redfern, FWO and Kissinger methods. The regression coefficient data (>0.9) of kinetic plots obtained for different methods best fits to the kinetic equation. Empirical formula of the compound is determined by ultimate analysis is CH_2.214S_0.0018O_0.6910. Proximate analysis gives the idea of volatile component which is74.33%. The range of average value of activation energy is 120.7013 kJ/mol to 140.7707 kJ/mol for the biodegradable plastic plate with different conversion (0.1–0.6) and (0.1–0.3) respectively at two different temperatures. The pyrolysis products obtained using a semi-batch reactor are characterized to know their composition and other properties.     

氟塑料—石墨板式换热器在高温强腐蚀换热工况中的应用

通过氟塑料－石墨板式换热器在化纤生产中高温强腐蚀换热工况中的实际应用，并与常规换热器的使用情况的对比分析，阐述了这种新型换热设备的特点。     

利用废旧塑料生产阻燃建筑装饰材料探讨

本文介绍了一种综合利用废旧热塑性塑料和锯末粉通过加入阻燃剂改性 ,生产防火阻燃型建筑装饰材料的方法。所生产的产品 ,其阻燃性能均达到国家标准 (GB5464 - 85)中规定的不燃性材料的要求。     

塑料挤出型材车间公用工程设计

鉴于当今人们对塑料门窗需求量的增大，通过对5个塑料挤出型材车间的设计，将其公用工程设计整理成文，总结出塑料挤出型材车间的采暖通风设计，压缩空气系统设计，制冷系统设计的较详尽的方案，以供有关设计技术人员参考。     

绿色再生混凝土利用途径与评定思路

就再生混凝土骨料进行深入系统的研究 ,建立了一套与现行评价天然骨料标准相一致的评定方法 ,具有工程实际意义 ,为将来实际应用作好了基础理论研究     

我国聚甲醛工业的供需分析

从国内聚甲醛树脂的生产、贸易及消费状况出发 ,分析了国内聚甲醛工业的供需现状并提出短期预测。     

绿色包装材料——生物降解塑料

对绿色包装材料-生物降解塑料的降解机理、特点，国内外研究现状和进展及存在的问题和发展前景进行了介绍。     

塑料薄膜透气测试装置及测试方法研究

根据塑料薄膜透气原理，设计了一种简易薄膜透气测试装置，并对测试方法及结果处理进行了探讨。     

蒸汽凝结水除油试验研究

介绍了利用类萃取技术进行蒸汽凝结水除油的过程。利用具有亲油功能的HOL-100树脂,经过试验和工业应用证明,萃取除油可以达到1．0mg/L以下,可满足炼油化工装置锅炉用水对含油量的要求。HOL-100树脂具有在高温状态下(120℃)除油的特点。通过标定考核,萃取除油技术是一项节能、节水、环保措施,可在中石油和中石化企业推广应用。     

Failure Analysis of Fuel System Assemblies

Fuel system assemblies used on recreational watercraft failed after a short time in service in a seawater environment. Examination of the assemblies revealed significant degradation of the polyacetal connectors of the wire subassemblies. Optical and microscopic evaluations indicated the complete loss of connector material implying decomposition of the resin, along with mud-cracking and a rough surface morphology signifying chemical attack. An elemental analysis performed on both an intact connector and degraded connector suggested a potential chemical agent in the form of zinc chloride. At elevated temperatures, concentrated zinc chloride solutions are known to decompose polyacetal resins. The source of the zinc chloride was established as corrosion products that resulted during the dezincification of the internal brass connector through exposure to saltwater in the application.