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1.
Cellulose dissolved in ionic liquid (1‐(carboxymethyl)pyridinium chloride)/water (60/40 w/w) mixture is regenerated in various non‐solvents, namely water, ethanol, methanol and acetone, to gain more insight into the contribution of non‐solvent medium to the morphology of regenerated cellulose. To this end, the initial and regenerated celluloses were characterized with respect to crystallinity, thermal stability, chemical structure and surface morphology using wide‐angle X‐ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. According to the results, regardless of non‐solvent type, all regenerated samples have the same chemical structure and lower crystallinity in comparison to the initial cellulose, making them a promising candidate for efficient biofuel production based on enzymatic hydrolysis of cellulose. The reduction in crystallinity of regenerated samples is explained based on the potential of the non‐solvent to break the hydrogen bonds between cellulose chains and ionic liquid molecules as well as the affinity of water and non‐solvent which can be evaluated based on Hansen solubility parameter. The latter also determines the phase‐separation mechanism during the regeneration process, which in turn affects surface morphology of the regenerated cellulose. The pivotal effect of regenerated cellulose crystallinity on its thermal stability is also demonstrated. Regenerated cellulose with lower crystallinity is more susceptible to molecular rearrangement during heating and hence exhibits enhanced thermal stability. © 2019 Society of Chemical Industry 相似文献
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无捻毛巾产品毛羽问题的分析与实践 总被引:1,自引:1,他引:0
对无捻毛巾产品毛羽问题进行了分析,对成因进行了初步探索.通过试验,制定了较为有效的改进措施和工艺.无捻毛巾制品的毛羽问题得到改善,并控制在一个较为合理的范围内. 相似文献
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Effect of Li+ ions on structure,properties, and actuation of cellulose electro‐active paper actuator
We have reported an electro‐active paper actuator from regenerated cellulose. After dissolving cellulose fibers with a solution of lithium chloride in N,N‐dimethylacetamide, cellulose was regenerated by combining distillation of cellulose solution along with washing with the mixture of deionized water, isopropyl alcohol, and running water. However, the effect of Li+ ions on structure, properties, and the actuation behavior of the actuator was not studied. This article describes the changes in these parameters when the Li+ ions are removed by subjecting it to different running water exposure time. The structure and properties of cellulose electro‐active paper and its actuation behavior were studied. As Li+ ions content reduced from 4354.17 to 10.26 ppm by increasing the exposure time of running water, crystallinity, Young's modulus, and bending displacement decreased. Details about the investigation have been explained. This elimination of ions is important to increase the piezoelectric effect in EAPap by decreasing the ion migration effect. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
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Dongmei Hu Jin Du Guosheng Su Zhenyun Lu Chongyan Zhang Xiangmin Kong Chonghai Xu 《International Journal of Applied Ceramic Technology》2021,18(4):1222-1234
The hardness and toughness of regenerated cemented carbides, in general, are contradictory. Therefore, it is critical to explore regenerated cemented carbides with both high hardness and high toughness. In this study, regenerated WC-8-wt% Co cemented carbide with SiC nanowhisker were prepared by low-pressure sintering. The influence of SiCw contents on the microstructure and mechanical properties of regenerated WC-8-wt% Co cemented carbide was investigated. The results indicated that the hardness, density, flexural strength, and fracture toughness of regenerated cemented carbide first increased and then decreased with the addition of SiCw. The Vickers hardness, density, flexural strength, and fracture toughness could reach 1575 HV, 14.6 g/cm3, 2204 MPa, 16.85 MPa·m1/2, respectively, with SiCw content 0.5 wt%, which were increased by 14.4%, 0.7%, 12.2%, and 17.3%, respectively, when compared with the regenerated cemented carbide without SiCw. The lowest friction coefficient and the best wear resistance could be also reached when 0.5-wt% SiCw was added. The fracture mechanism of the regenerated cemented carbide contained both transgranular and intergranular fracture through the microscopic observation of fracture surface via scanning electron microscope. 相似文献
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以高直链淀粉(HS)为原料,通过“还原胺化-点击化学法”在其还原性端的潜在醛基上进行磁化分子修饰,得到具有磁性的变性淀粉(MMS),并在外磁场作用下制备再生淀粉膜。具体包括在HS分子唯一的潜在醛基上引入炔基,对四氧化三铁粒子(MNP)进行硅烷包覆得到叠氮化磁体粒子(azide-MNPs),两者经点击化学反应得到分子链末端带磁的变性淀粉。借助XRD、FTIR、NMR和MALDI-TOF MS对产物进行结构表征,结果表明,磁体粒子精准接枝到高直链淀粉分子还原末端,得到目标产物MMS。再生淀粉膜性能测试结果表明,在外磁场诱导条件下MMS逐渐趋于分子有序排列,制得的再生淀粉膜较纯CMS淀粉膜断裂伸长提升49.5%,断裂强度提升88.3%,短程有序程度提高。该文为基于外加磁场下的淀粉再生膜结构设计和力学性能调控提供了新思路。 相似文献
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阐述了赛络纺纱技术的原理,探讨了F1510细纱机改造赛络纺的方法,优选了工艺参数.试验结果表明,在相同的配棉条件下,CJ18.2tex赛络纱的条干、粗细节、强力和毛羽均优于相同线密度的传统环锭纱. 相似文献
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探究了利用嵌入式复合纺纱技术纺制高支纯亚麻纱.通过改造多功能纺纱小样机以实现嵌入式复合纺纱技术并对雨露沤麻过后的亚麻纤维进行化学脱胶和剪切处理,以70/30的比例和水溶性维纶短纤维混合制条做成粗纱后,在细纱机上纺制了嵌入式亚麻水溶性维纶复合纱,通过对成纱的强伸性、毛羽、条干均匀度的测试与比较进行了纺纱工艺的优化.结果表明,纺制20.7 tex亚麻水溶性维纶嵌入式复合纱的工艺最佳值为捻系数420、长丝预加张力7.5 cN、长丝与长丝间距8 mm、长丝与粗纱间距1.5 mm;经优化工艺试纺的20.7 tex亚麻水溶性维纶嵌入式复合纱,经退维处理后的纱线细度为8.9 tex;亚麻水溶性维纶嵌入式复合纱结构稳定、强力较高、条干均匀、毛羽少,为开发高档亚麻类面料提供了新的途径. 相似文献
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采用纳滤法处理电厂离子交换树脂再生废水,试验结果表明:废水中绝大部分有机污染物的分子量小于1 000,且含有的大量C l-;以出水的TOC浓度来评价纳滤试验的处理效果比CODC r值更合理,采用纳滤法处理废水,出水的TOC浓度将稳定在14~18 mg/L范围内,达到废水的处理要求. 相似文献