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排序方式: 共有8935条查询结果,搜索用时 15 毫秒
1.
Jieyun Tu Xinghui Shi Yuanrong Jing Huimin Zou Jakub Kadlcak Zhanfu Yong Susu Liu Guangyong Liu 《Polymer Engineering and Science》2021,61(8):2213-2221
Equilibrium swelling and rheological tests were adopted to systematically investigate the effects of softener type and dosage on the crosslink densities. The results turned out that the chemical crosslink density could be distinguished from the physical crosslink density by comparing the results of equilibrium swelling and rheological tests. The liquid butadiene (LB) as a softener leads to the greatest reduction in crosslink density, followed by polyethylene wax (PW) and paraffinic oil (PO). The tensile strength decreases with increasing PO content while shows peak values with increase of LB and PW contents. The dependencies of chemical crosslink density on the aging time under 150°C are quite different for the three softeners, which can be expected from the double crosslinking networks consisting of small softener and large main crosslinking networks. Further investigation has been performed to correlate the tensile strength with chemical crosslink density of ethylene propylene diene monomer elastomer vulcanizates. Three different linear relationships can be obtained for the softeners independent of the aging time. It can now be expected from this study that the role of some new softeners in rubber compounds is not only confined to plasticization but also forms crosslinking networks in the peroxide-cured rubbers. 相似文献
2.
Ewa Olewnik-Kruszkowska Magdalena Gierszewska Sylwia Grabska-Zieliska Joanna Skopiska-Winiewska Ewelina Jakubowska 《International journal of molecular sciences》2021,22(7)
Hydrogels based on chitosan are very versatile materials which can be used for tissue engineering as well as in controlled drug delivery systems. One of the methods for obtaining a chitosan-based hydrogel is crosslinking by applying different components. The objective of the present study was to obtain a series of new crosslinked chitosan-based films by means of solvent casting method. Squaric acid—3,4-dihydroxy-3-cyclobutene-1,2-dione—was used as a safe crosslinking agent. The effect of the squaric acid on the structural, mechanical, thermal, and swelling properties of the formed films was determined. It was established that the addition of the squaric acid significantly improved Young’s modulus, tensile strength, and thermal stability of the obtained materials. Moreover, it should be stressed that the samples consisting of chitosan and squaric acid were characterized by a higher swelling than pure chitosan. The detailed characterization proved that squaric acid could be used as a new effective crosslinking agent. 相似文献
3.
Marziyeh Hayati Ghasem Rezanejade Bardajee Majid Ramezani Samaneh Sadat Hosseini Farhang Mizani 《Polymer International》2020,69(2):156-164
Hydrogels, nanogels and nanocomposites show increasing potential for application in drug delivery systems due to their good chemical and physical properties. Therefore, we were encouraged to combine them to produce a new compound with unique properties for a long‐term drug release system. In this regard, the design and application of a nanocomposite hydrogel containing entrapped nanogel for drug delivery are demonstrated. To this aim, we first prepared an iron oxide nanocomposite nanogel based on poly(N‐isopropylacrylamide)‐co‐((2‐dimethylaminoethyl) methacrylate) (PNIPAM‐co‐PDMA) grafted onto sodium alginate (NaAlg) as a biocompatible polymer and iron oxide nanoparticles (ION) as nanometric base (PND/ION‐NG). This was then added into a solution of PDMA grafted onto NaAlg. Through dropwise addition of mixed aqueous solution of iron salts into the prepared polymeric solution, a novel hydrogel nanocomposite with excellent pH, thermal and magnetic responsivity was fabricated. The synthesized samples were fully characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy with energy‐dispersive X‐ray analysis, vibrating sample magnetometry and atomic force microscopy. A mechanism for the formation of PNIPAM‐co‐PDMA/NaAlg‐ION nanogel–PDMA/NaAlg‐ION hydrogel and PND/ION nanogel is suggested. Swelling capacity was measured at various temperatures (25 to 45 °C), pH values (from 2 to 11) and magnetic field and under load (0.3 psi) and the dependence of swelling properties of the nanogel–hydrogel nanocomposite on these factors was well demonstrated. The release rate of doxorubicin hydrochloride (DOX) as an anticancer drug was studied at different pH values and temperatures in the presence and absence of a magnetic field. The results showed that these factors have a high impact on drug release from this nanocomposite. The result showed that DOX release could be sustained for up to 12.5 days from these nanocomposite hydrogels, significantly longer than that achievable using the constituent hydrogel or nanogel alone (<1 day). The results indicated that the nanogel–hydrogel nanocomposite can serve as a novel nanocarrier for anticancer drug delivery. © 2019 Society of Chemical Industry 相似文献
4.
由丙烯酸(AA)、α-甲基丙烯酸(MAA)和丙烯酰胺(AM)合成了具有很好DH敏感性和一定温度敏感性的智能水凝胶,考察了合成温度、丙烯酰胺、交联剂和引发剂用量对制备的水凝胶溶胀性能的影响。结果表明,在60℃下,单体从和MAA用量分别为100mmol和75mmol时,单体AM、交联剂和引发剂用量分别为反应物总质量的32.8%、0.2%和0.4%时,制备的水凝胶溶胀性能最好。考察了介质的离子浓度、pH值和温度对水凝胶溶胀比的影响,结果表明,离子浓度越大,水凝胶的溶胀比越小;水凝胶具有一定的DH可逆性。 相似文献
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某些微分方程和相应的积分方程之间的关系被讨论;这些微分方程通过边境小波变换可被转换成相应的积分方程,它们不仅在弱收敛意义下而且在范围数收敛意义下是等价的;关于这些微分方程的讨论就与相应的积分方程的讨论联系起来。 相似文献
8.
通过对影响气化炉火层各因素的分析,理论与实际相结合,推导出现见性控制气化炉火层的经验式,应用于生产实际中,起到了指导生产的作用。 相似文献
9.
柔性桩沉降可靠性的简化分析公式 总被引:1,自引:1,他引:0
本文提出了结合分层的剪切位移法、摄动法和随机场理论来计算柔性桩沉降可靠度的简化方法,并用随机有限元和蒙特卡洛模拟法对此简化模型的精度进行了对比分析,分析结果表明该方法计算简便,精度较高。通过算例发现,在土的变形模量为小变异的情况下,其概率模型对桩的沉降可靠度影响不明显,因此其概率模型可近似采用正态分布;在土的变形模量为大变异的情况下,其概率模型对桩的沉降可靠度影响非常明显,在选择概率模型时要慎重。对于土的变形模量服从对数正态分布的情况,采用将其当量正态化后的中心点法即使在参数大变异的情况下也可以获得理想的计算精度。 相似文献
10.
从原料与生产工艺过程分析了瓷质势光砖批量色差产生的原因,并提出了相应对策,为生产质量佳化提供一定的参考。 相似文献