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1.
Anton Apriyantono Jennifer M Ames 《Journal of the science of food and agriculture》1993,61(4):477-484
Aqueous molal solutions of xylose and lysine (initial pH 4–9) were refluxed either with control of the pH at 5–0 or without pH control (final pH 2–6). Analysis by gas chromatography (GC) and GC-mass spectrometry resulted in the identification of 58 and 28 compounds, respectively, from the two systems. Furans were the main reaction products in both systems and 2-furfural alone comprised 522 and 999 g kg?1 of the volatiles, respectively, from the systems with final pH values of 5–0 and 2–6. Maintaining the pH at 5–0 resulted in a higher yield and greater numbers of nitrogen-containing compounds, and monocyclic pyrroles, pyridines and 2,3-dihydro-l H-pyrrolizines were identified only in that system. Aliphatic compounds, alicyclic compounds, benzene derivatives. l-(2–furfuryl)pyrroles and pyrazines were also identified. This investigation is the first report of the formation of 2.3-dihydro-l H-pyrrolizines in a model system containing lysine as the amino compound; a possible mechanism is proposed. 相似文献
2.
嗜单宁管囊酵母木糖酒精发酵的研究 总被引:3,自引:0,他引:3
综合利用丰富、廉价且可再生的农作物秸秆资源生产酒精的研究已经渐渐成为全球范围的热点之一。文章研究了嗜单宁管囊酵母木糖酒精发酵的发酵性能,分离、筛选、驯化培养出一株高效木糖酒精发酵菌株 g-13,在最适条件下其木糖酒精发酵的转化率为 0.446 g/g(酒精/消耗的糖),为发酵秸秆纤维水解液中的戊糖生产燃料酒精提供菌种支持。 相似文献
3.
强碱树脂在木糖应用中存在的问题及解决方法 总被引:1,自引:0,他引:1
木糖是一种在化工、食品等领域有着广泛用途的五碳糖,工业生产是用稀强酸将玉米芯中含有的大量多缩戊糖分解为单个的木糖分子,然后通过离子交换除盐、脱色,精制提取,但在强碱离子交换柱中,木糖分子容易被部分催化异构转化为阿拉伯糖,使得木糖纯度下降,结晶困难。考察了强碱树脂再生浓度、淋洗终点pH值、交换温度以及流速对木糖分子异构的影响,得出最佳的交换工艺条件:再生剂浓度为2%、淋洗终点pH值为7.5、交换温度20℃,流速为1BV/h。 相似文献
4.
Xylose fermentation by Pichia stipitis was examined using a two-stage batch process. The cells were first grown aerobically on D-xylose (5 g/L), whereafter additional xylose (10 g/L) was added and fermented during anaerobic conditions (T=30°C). The optimum pH value for a fermentation with constant pH was found to be 4.5 (maximum specific ethanol production rate 0.21 g/(g h). Forced square wave cycling of the pH between 4 and 5, and 3.5 and 5.5 (cycle time 30 min) during the fermentation stage resulted in a fermentation rate lower than the maximum rate, but with unchanged ethanol yields. 相似文献
5.
Zheng Ya-Jun; Merz Kenneth M. Jr; Farber Gregory K. 《Protein engineering, design & selection : PEDS》1993,6(5):479-484
Two mechanisms for an aldoseketose isomerization havebeen examined using high level ab initio and semiempirical molecularorbital methods. The proton transfer pathway via an enediolintermediate is shown to be favored in the absence of a metalion, while the hydride transfer pathway becomes favored in thepresence of a metal ion. Our calculations explain why the protontransfer pathway is operative in most aldoseketose isomerizationreactions. These calculations also provide further support forthe previously proposed metal ion-mediated hydride transfermechanism for xylose isomerase. 相似文献
6.
7.
通过美拉德反应对荞麦蛋白进行改性,对荞麦蛋白-木糖接枝物的制备及其性质进行研究。在湿热条件下,利用美拉德反应制备荞麦蛋白-木糖接枝物。通过正交试验优化接枝物的制备条件,荞麦蛋白与木糖按1∶5的质量比、在50℃下反应120min,接枝度可达到49.24%。性质测定表明,接枝物的溶解度较荞麦蛋白提高了约25%,乳化性提高了约30%,乳化稳定性提高了约11%。 相似文献
8.
从5种土壤和植物叶片上分离到24株酵母菌株。分别对它们的耐高温、木糖利用和产酒精能力进行了测定。从中筛选到4株能在45℃下生长良好,能够利用木糖的产酒精酵母菌株。 相似文献
9.
Beatriz Gutiérrez‐Rivera Krzysztof Waliszewski‐Kubiak Octavio Carvajal‐Zarrabal Maria Guadalupe Aguilar‐Uscanga 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(2):263-270
BACKGROUND: Efficient conversion of glucose/xylose mixtures from lignocellulose is necessary for commercially viable ethanol production. Oxygen and carbon sources are of paramount importance for ethanol yield. The aim of this work was to evaluate different glucose/xylose mixtures for ethanol production using S. cerevisiae ITV‐01 (wild type yeast) and P. stipitis NRRL Y‐7124 and the effect of supplying oxygen in separate and co‐culture processes. RESULTS: The complete conversion of a glucose/xylose mixture (75/30 g L?1) was obtained using P. stipitis NRRL Y‐7124 under aerobic conditions (0.6 vvm), the highest yield production being Yp/s = 0.46 g g?1, volumetric ethanol productivity Qpmax = 0.24 g L?1 h?1 and maximum ethanol concentration Pmax = 34.5 g L?1. In the co‐culture process and under aerobic conditions, incomplete conversion of glucose/xylose mixture was observed (20.4% residual xylose), with a maximum ethanol production of 30.3 g L?1, ethanol yield of 0.4 g g?1 and Qpmax = 1.26 g L?1 h?1. CONCLUSIONS: The oxygen present in the glucose/xylose mixture promotes complete sugar consumption by P. stipitis NRRL Y‐7124 resulting in ethanol production. However, in co‐culture with S. cerevisiae ITV‐01 under aerobic conditions, incomplete fermentation occurs that could be caused by oxygen limitation and ethanol inhibition by P. stipitis NRRL Y‐7124; nevertheless the volumetric ethanol productivity increases fivefold compared with separate culture. Copyright © 2011 Society of Chemical Industry 相似文献
10.