Microstructure of Nano-Y203／Cobalt Based ,Alloy Composite Coating byLaser Cladding

Composite coatings made of nano-Y203/cobalt-based alloy and produced by crosscurrent CO2 laser on Ni-based superalloy are introduced. Cross-section or surface of the coatings was examined to reveal their microstructure using optical microscope, SEM, including EDS microanalysis, TEM and XRD. The results show that some equilibrium or non-equilibrium phases, such as γ-C0, Cr23C6, Y203 and ε-Co exist in the coatings. Fine and short dendritic microstructure andcolumnar to equiaxed transition (CET) occurred by adding nano-Y203 particles. With the increasing amount of nano-Y203(1%, mass fraction), fully equiaxed crystallization appeared. These are caused by nano-Y203 particles acting as new nucleation site and rapid solidification of the melt. The results also show that inhomogeneous dispersion of nano-Y203 resultsin the formation of ε-Co phase in the coatings. The sub-microstructure of the clad is stacking fault. The mechanism of theformation of equiaxed grains is also analyzed.     

WC对铜基和镍基喷焊覆层材料耐气蚀性能的影响

在CuNiSiB,NiCrSiB自熔合金粉末中添加WC陶瓷颗粒，利用氧乙炔焰粉末喷焊工艺制备覆层材料，用超声波振动气蚀仪对覆层材料进行耐气蚀性能研究，用扫描电子显微镜对覆层材料表面气蚀破坏形貌进行观察，结果表明：复合覆层材料的耐气蚀能力比基体强；提高CuNiSiB覆层材料耐气蚀能力的途径是强化晶界，还探讨了覆层材料的气蚀破坏机理。     

铝多孔质阳极氧化膜扩孔行为的电镜研究

铝多孔质阳极氧化膜扩孔行为的电镜研究徐洮，赵家政，陈建敏（中科院兰州化物所固体润滑开放实验室，兰州７３００００）利用铝质材料阳极氧化层均匀、规则的多孔质结构，制备各种功能型阳极氧化铝材料是近年来铝质材料表面改性研究的热点之一￣［１］。所谓自润滑阳极氧...     

不锈钢表面热喷涂陶瓷层经激光处理的显微结构研究

不锈钢表面热喷涂陶瓷层经激光处理的显微结构研究吴秋红，贺连龙，李斗星，陶曾义，崔嵬，叶恒强（中国科学院金属研究所固体原子像实验室，沈阳１１００１５）（华中理工大学机械二系）材料表面陶瓷涂层被广泛地用于提高耐磨和开成热阻挡层。等离子喷涂和热喷涂是获得材...     

LASER CLADDED TiCN COATINGS ON THE SURFACE OF TTTANIUM

Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs （OM）. The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm/s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm^-2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2 and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80μm, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.     

德国开发出了不锈钢覆层表面抛光新技术

德国蒂森克虏伯尼罗斯塔公司（ThyssenKruppNirosta）开发出两种不锈钢覆层表面抛光新技术。尼罗斯塔公司与汉高集团（Henkel）合作开发出一种新的透明涂层Silverlee。可用于家用电器、厨房设备、家具、镶板、电梯和自动扶梯。工艺采用紫外线辐射和纳米粒子方法，产生薄的无色透明涂层。     

等离子喷涂技术的现状与展望

综合分析了国内外等离子喷涂技术的现状，着重阐述了今后的发展趋势，并希望这一技术在我国的工业生产中发挥更大的作用。     

镁合金表面激光电弧复合熔覆 5556 铝合金工艺研究

铝合金熔覆是轻量化镁合金表面涂层防护的重要方法。 本研究使用 AZ80A 镁合金作为基材, 使用 5556 铝 合金作为熔覆合金, 并使用激光电弧复合熔覆进行了铝合金熔覆层制备。 对熔覆层组织进行了分析, 重点研究了 激光摆动对熔覆层品质的影响。 结果表明, 当激光无摆动时, 熔覆层宽度有限, 无法正常形成各道次熔覆层的有 效搭接, 且缺陷较多。 在增加激光摆幅的情况下, 激光加热能量会更均匀地在镁合金基材表面分散, 有效增加了 熔宽, 提升了各道次熔覆层的搭接率, 促进内部缺陷更少、 品质更高的连续熔覆层的形成。     

不锈钢表面超薄铜层的激光熔覆

采用ＣＯ２激光器在３１６Ｌ不锈钢表面获得了超薄的铜熔覆层,文中分析和讨论了激光熔覆工艺参数加激光功率,熔覆速度,离焦量以及送粉率等对熔覆层质量的影响,提出了熔覆工艺的优化方法,使铜层的熔覆厚度可控制在１００μｍ之内,稀释率小于１０％以及很小的热变形。