二次离子质谱无标样定量分析方法的探索

Conventional quantitative analysis of SIMS is based on the calibration with standards. In this paper, some impurities in Aluminum bulk material were quantitatively analyzed using natural abundance of the isotope and known relative secondary ion yield of the elements. The analysis results are compared with the results of other quantitative analysis techniques, such as atomic emission spectrometer and glow discharge mass spectrometer(GDMS).     

钚气溶胶直接进样ICP-MS快速分析技术-6级高效过滤器后钚气溶胶的定量

A technique for fast analysis of plutonium in airborne aerosol was developed with directly sampling ICP-MS in this laboratory. And the Pu-242 aerosol particle addition calibration method was established. The nebulized Pu-242 solution aerosol was quantitatively mixed with the airborne aerosol and then introduced into ICP-MS. The results show that the detection limit for Pu-239 concentration is down to 1.4×10^－6 Bq·L^－3. The airborne aerosol sample after through a high efficiency particulate air (HEPA) filter with six stages (efficiency per stage 99.95%) was analyzed using this technique, the plutonium concentration determined is 3×10^－4 Bq·L^－3. However plutonium could not be detected when sampling using HEPA filter at same situation, airborne aerosol also could not be detected at same situation with Condensation Particle Counter (CPC). This result shows there were some tiny plutonium particulates which passed through the six stages HEPA filter with airflow and could not be collected by the HEPA filter     

基于非均匀系数的水库移民收入恢复评价

水利水电工程征地移民搬迁后的生产生活恢复,不仅是实现移民规划目标的重点内容,也是保持安置区社会稳定的重要因素。水库移民搬迁后的收入恢复水平是评价移民工程搬迁安置效果的一个重要指标。移民收入的评价,除收入水平之外,还涉及到贫富差距等共同富裕问题。针对南水北调中线丹江口库区试点移民的收入恢复,在抽样与跟踪调查获取数据的基础上,分析了移民收入的整体恢复水平,并利用非均匀系数对收入的差距进行了研究。     

基于近红外光谱的梯恩梯凝固点温度检测方法研究

为实时检测梯恩梯(TNT)生产过程中的凝固点温度,结合化学计量学和光谱学,采用偏最小二乘法建立近红外光谱分析技术,实时检测TNT凝固点温度的定量模型。通过比较1阶导数+标准正态变量变换(SNV)、多元散射校正(MSC)、1阶导数、SNV、1阶导数+MSC、2阶导数6种原始光谱数据优化预处理方法,发现选择光谱建模区间为9 403. 8～4 597. 7 cm^-1、1阶导数(17点平滑)+SNV预处理方法建立的模型最佳,模型相关系数R²=0. 991,交互验证标准偏差为0. 178.主成分分析及模型验证结果表明:用最优模型预测不同机台的硝化物凝固点温度,近红外光谱分析预测值与人工测定值偏差最大为0. 950 4%;该模型有较好的稳定性、预测性,能够识别不同类型的样本,在短时间内用近红外光谱分析法可测定凝固点温度。     

基于正态分布的光功率状态分析研究与应用

为了形成全网的光功率运行状态分析，本文采用概率统计的基本方法，首先对光功率数值在频率上进行正太分布可视化，然后从理论上对其正态分布进行验证，最后构建基于正太分布的光功率概率统计数据分析模型，实现光功率定量化分析，并在某铁路传输网中部署应用测试，提高了光功率数据使用价值和智能管理水平，测试结果能够满足光功率实际应用需求。