超声波强化原油破乳电脱盐技术的工业实践

报道了采用超声波强化原油破乳电脱盐技术的开发与工业应用.经过实验室开发确定的超声波强化原油破乳电脱盐专利技术--超声波-电场联合破乳脱盐组合技术采用顺逆流方式.该技术于2003年9月在齐鲁分公司完成工业应用试验后,超声波强化原油破乳设备直接投入生产运行,在不加入化学破乳剂的情况下,可使胜利混输原油(平均盐浓度为50 mg/L,平均水质量分数为0.5%～1.0%)脱后盐浓度低于3 mg/L,水质量分数小于0.3%.     

销售企业客户服务体系建设的几点建议

在阐述客户服务意义的基础上，提出对中国石化成品油销售企业客户服务体系建设的建议，即建立以客户为尊的服务理念；建设特色企业文化；完善员工服务体系；注重细节，提高服务质量；整合现有客户体系资源，拓展服务功能。     

降低成品油二次物流运输成本的思考

介绍了传统成品油进货和管理模式存在的诸如成品油物流以行政区划、中问环节多、信息化程度不高、运输路线未优化造成物流成本提高等问题。提出要降低成品油二次物流运输成本，当务之急是加强成品油物流的信息化建设；调整管理模式，打破行政区域界限，开展经济辐射半径内的库站物流配送；引进竞争机制，打破运输垄断，一、二次物流结合，大、小车型搭配，提高运营效率；做好运杂费全面预算、核算及运行费用的过程控制。     

加油站油品防盗的措施

为防止加油站油品被盗，应采取加强夜间值班管理、加强油品的计量管理和加强安全管理的高科技建设三项措施。     

TUD-DNS3脱硝助剂在催化裂化装置的工业应用

TUD-DNS3脱硝助剂在中韩（武汉）石油化工有限公司1号催化裂化装置上进行了工业应用。结果表明：针对两段再生工艺，当系统中助剂占总催化剂藏量的质量分数为2.6%时，烟气脱硫装置外排污水中的氨氮质量浓度由加剂前的100 mg/L下降至40 mg/L以内；助剂的加入降低了CO焚烧炉的炉膛温度，有利于烟气的合格排放，并对装置操作、产品分布及汽油、柴油产品质量无不良影响。     

MPTA型原油脱金属剂的工业应用

在对高金属含量原油进行初步评价的基础上，利用SH—Ⅰ型电脱盐试验仪对自主开发的MPTA型原油脱金属剂进行了原油脱金属的实验室研究。结果表明，当MPTA型脱金属剂加入量为250μg／g时，钙的脱除率可达97．4％，并且对其它金属元素，如镍、铁、钠、锰、铝和钒也有明显的脱除效果。该剂在山东恒源石油化工股份有限公司重交沥青车间500kt／a的电脱盐装置上进行原油脱金属工业试验的结果表明，经过二级电脱盐处理后，钙的脱除率达到99．1％，钠的脱除率为94．6％，铁的脱除率为82．9％，并可在一定程度上降低原油中镍和铜的含量。使用MPTA型原油脱金属剂显著降低了一、二级电脱盐装置的电场电流，有利于炼油厂的节能降耗。     

高酸原油脱酸工艺技术研究

介绍了一种原油脱酸工艺方法。研究了温度、时间对高酸原油脱酸的影响,脱酸温度大于 260℃,脱酸反应较快。分析了高酸原油脱酸前后馏分酸值的变化,脱酸反应对130℃以上各馏分酸值降低都较多,180℃以上馏分脱酸率在80％以上。     

井下乳化/水热催化裂解复合降黏开采稠油技术研究

实验考察了胜利孤东稠油井下催化水热裂解和乳化/催化水热裂解降黏效果。所用催化剂为水溶性铁镍钒体系,Fe3+∶Ni2+∶VO4+=5∶1∶1,100 g稠油与30 g 0.5%催化剂水溶液在240℃反应24小时。原始黏度(50℃)11.0和8.36 Pa.s的两种稠油裂解并静置除水后,黏度降低76.2%和75.6%,室温放置60天后降黏率下降小于3个百分点,气相色谱显示裂解后轻组分明显增加,红外光谱显示稠油组分发生脱羧反应且芳环数减少。讨论了稠油催化水热裂解反应机理。所用化学助剂JN-A在油水中均可溶,耐温达250℃,耐矿化度达50 g/L,其水溶液以30∶100的质量比与稠油混合时形成低黏度的O/W乳状液。当水相含1.0%JN-A和0.5%催化剂时,两种稠油水热裂解后的反应混合物为O/W乳状液,黏度仅为319和309 mPa.s,静置除水后的稠油降黏率增加到86.5%和87.3%,其中的轻组分含量进一步增加。该井下乳化/催化水热裂解复合降黏法成功地用于孤东两口蒸汽吞吐井,稠油井作业后初期采出的原油黏度由~9 Pa.s降低到1 Pa.s左右,随采油时间延长而逐渐升高,约50天后超过4Pa.s。图2表6参5。     

Biochemical mechanisms conferring cross-resistance to fumigant toxicities of essential oils in a chlorpyrifos-methyl resistant strain of Oryzaephilus surinamensis L. (Coleoptera: Silvanidae)

The fumigant toxicities of lavender and ylang-ylang essential oils were tested against a chlorpyrifos-methyl resistant strain (QVOS102) and an insecticide-susceptible reference strain (VOS48) of the saw-toothed grain beetle, Oryzaephilus surinamensis L. (Coleoptera: Silvanidae). The resistant strain showed 1.3- and 1.6-fold higher tolerance against lavender and ylang-ylang fumigation toxicity, respectively, relative to the susceptible strain. LT₅₀ values calculated as the time to attain 50% mortality of tested insects during fumigation were determined at two different concentrations. At 15 μl/l of air, QVOS102 had 2.9- and 1.4-fold higher LT₅₀ values for lavender and ylang-ylang fumigation toxicity, respectively, than VOS48. At 200 μl/l air, QVOS102 had 6.4- and 2.9-fold higher LT₅₀ values for lavender and ylang-ylang fumigation toxicity, respectively, than VOS48. Piperonyl butoxide, a potential inhibitor of cytochrome P450-dependent monooxygenase, increased fumigant toxicities of the two essential oils against QVOS102. The enhanced tolerance for the essential oil may have resulted from the enhancement of detoxifying enzymes associated with insecticide resistance.     

Quality of Crude Fish Oil Extracted from Herring Byproducts of Varying States of Freshness

ABSTRACT: Herring byproducts were stored at 2 and 15 °C for up to 72 h. Over time, significant increases of total volatile bases (TVB), histamine, putrescine, cadaverine, and tyramine were detected. However, only tyramine and TVB levels were temperature-dependent. The level of total polyunsaturated fatty acids (PUFAs) was constant. Longer byproducts storage gave rise to an oil with higher levels of free fatty acids, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and total PUFAs, while fluorescent compounds were lower. A higher storage temperature led to oil higher in α-tocopherol and EPA levels and lower in anisidine value. Surprisingly, the oil with the highest content of PUFAs was not produced from the freshest byproducts, and oil with low oxidation products can be extracted from stored byproducts.