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1.
简要介绍世界几种主要薄板坯连铸工艺。着重叙述应用大型通用商业软件MSC.MARC。模拟液芯压下时铸坯的变形,确定最佳压下方案的有限元分析,液芯压下应该在结晶器出口处及二冷区扇形段开始部分进行,这样能减小铸坯的应变。 相似文献
2.
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
3.
针对UO_3的N_2还原反应建立了多孔挡板流化床反应器模型。将多孔挡板床的每一级视为具有相似的流动状态,每一级的上、下段称为稀、密相段,分别用鼓泡床和活塞流模型描述。该模型的计算值与¢63mm的多孔挡板床H_2还原UO_3的热态实验值能较好的吻合。还预计了还原温度、操作气速和挡板结构参数对固相转化率的影响,为该类反应器的工业设计、放大和优化提供了依据。 相似文献
4.
Two different generators for ozone were tested, a traditional electrical discharge generator and a generator based upon UV–irradiation of air at 150–180 nm. It was demonstrated that the traditional generator gave slightly higher reductions in levels of color for equivalent ozone dosages. Both gases affected the molecular weight distribution in the way that the bigger molecules were broken down to smaller ones. No significant difference between the molecular weight reduction efficiency of the gases was found. 相似文献
5.
6.
The effect of gas-liquid contacting conditions in a static mixer on ozone transfer efficiency and reduction of Bacillus subtilis spores was studied in an experimental ozone contactor. An empirical mathematical model was developed that related the transfer efficiency in the experimental system to the superficial liquid velocity in the mixer, the gas-liquid flow rate ratio and the height of the down-stream bubble column. Spore reduction was determined primarily by the dissolved ozone concentration-time (Cavgtm) product in the reactive flow segment and was independent of the gas-liquid contacting conditions in the static mixer. In an integrated ozone contacting system, the static mixer should be designed to maximize ozone mass transfer while the reactive flow segment should be designed for efficient microorganism reduction. 相似文献
7.
In this paper, the microstructure of a 1 wt.% Cu/γ-Al2O3 catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts. 相似文献
8.
D. Bergmann U. KaiserS. Wagner 《Journal of Wind Engineering & Industrial Aerodynamics》2003,91(4):543-550
The determination of dynamic wind loads on buildings, i.e. pressure and deflection, has gained increasing interest (European Prestandard ENV 1991-2-4, Eurocode 1: basis of design and actions on structures—Part 2-4: actions on structures—wind actions, European Committe for Standardization, Brussels, 1995; DIN 1055 Teil 4 Lastannahmen für Bauten, Verkehrslasten, Windlasten bei nicht schwingungsanfälligen Bauwerken, 1991; N. Hölscher, M. Hortmanns, J. Sahlem, Praxisnahe Erfassung von Windwirkung an Industrie- und Hochbauten, Windwirkung im Bauwesen, Braunschweig, 7, Dreiländertagung D-A-CH 2001, Windtechnologische Gesselschaft, 2001 [1], [2] and [3]). Therefore, the spectral distributions of velocity and pressure fluctuations in wind tunnels are an important quality aspect. While velocity fluctuations can be manipulated by the obstacles used to create the turbulence, pressure fluctuations are influenced by acoustic noise as well. Especially, the first eigenfrequency of the longitudinal mode of the wind tunnel tends to disturb the pressure spectrum.In this paper, a solution for the reduction of low-frequency acoustic pressure fluctuation is presented and its application in the atmospheric boundary layer wind tunnel at the IAG is shown. 相似文献
9.
Cathodic processes in the leaching and electrochemistry of covellite in mixed sulfate–chloride media
The cathodic processes that occur on a covellite (CuS) surface in mixed sulfate–chloride solutions in the absence and presence
of copper(II) ions have been studied using potentiostatic transients and cyclic voltammetry at rotating disk electrodes in
the potential range 0.3–0.7 V (versus SHE). This range is relevant to the oxidative leaching of this copper mineral in sulfate
and chloride lixiviants. Variations in the concentrations of sulfate and chloride ions had a small effect on the cathodic
reduction of covellite in the potential range of 0.5–0.3 V, although the presence of chloride ion resulted in a significant
increase in the anodic current on the reverse sweep. On the other hand, addition of copper(II) ions resulted in enhanced cathodic
currents and subsequent anodic currents in both sulfate and chloride solutions due to reduction of covellite to an undefined
reduced copper sulfide species. Reduction of copper(II) to copper(I) ions becomes the preferred cathodic reaction as the concentration
of chloride ions increases, becoming mass transport controlled at a rotating disc electrode at potentials below about 0.4 V.
Potentiostatic measurements at potentials negative to the mixed potential in acidic chloride solutions have shown that reduction
of copper(II) ions is reversible and have been used to estimate the rate of oxidative dissolution of the mineral which value
agrees reasonably well with previously reported leaching rates under similar conditions. Reduction of dissolved oxygen has
been found to be very much slower that that of copper(II) ions under ambient conditions. 相似文献
10.
The reduction and subsequent reoxidation of isolated vanadate species supported on silica was investigated using temperature-programmed reduction and oxidation, along with in-situ XANES and Raman spectroscopy. Approximately 70–80% of the vanadium was reduced to V3+ after reduction in H2 at temperatures up to 923 K. Upon reduction, the vanadyl oxygen was removed and the three remaining V–O bonds are lengthened by 0.2 Å. The vanadate species are rapidly reoxidized when exposed to O2, with the amount of oxygen uptake matching well with the amount removed during reduction. In-situ Raman spectroscopy during reoxidation in 18O2 showed that significant scrambling occurs between gas phase oxygen and surface oxygen species during the reoxidation of the vanadate species. 相似文献