全文获取类型
收费全文 | 3550篇 |
免费 | 108篇 |
国内免费 | 168篇 |
专业分类
电工技术 | 45篇 |
综合类 | 123篇 |
化学工业 | 792篇 |
金属工艺 | 224篇 |
机械仪表 | 127篇 |
建筑科学 | 128篇 |
矿业工程 | 278篇 |
能源动力 | 184篇 |
轻工业 | 44篇 |
水利工程 | 46篇 |
石油天然气 | 1179篇 |
武器工业 | 7篇 |
无线电 | 162篇 |
一般工业技术 | 217篇 |
冶金工业 | 77篇 |
原子能技术 | 24篇 |
自动化技术 | 169篇 |
出版年
2024年 | 18篇 |
2023年 | 44篇 |
2022年 | 108篇 |
2021年 | 134篇 |
2020年 | 124篇 |
2019年 | 93篇 |
2018年 | 89篇 |
2017年 | 72篇 |
2016年 | 120篇 |
2015年 | 99篇 |
2014年 | 186篇 |
2013年 | 191篇 |
2012年 | 223篇 |
2011年 | 247篇 |
2010年 | 165篇 |
2009年 | 182篇 |
2008年 | 174篇 |
2007年 | 197篇 |
2006年 | 175篇 |
2005年 | 189篇 |
2004年 | 143篇 |
2003年 | 131篇 |
2002年 | 137篇 |
2001年 | 81篇 |
2000年 | 105篇 |
1999年 | 82篇 |
1998年 | 75篇 |
1997年 | 48篇 |
1996年 | 45篇 |
1995年 | 45篇 |
1994年 | 18篇 |
1993年 | 11篇 |
1992年 | 11篇 |
1991年 | 12篇 |
1990年 | 4篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 7篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
排序方式: 共有3826条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(79):33765-33780
This work investigates selective Ni locations over Ni/CeZrOx–Al2O3 catalysts at different Ni loading contents and their influences on reaction pathways in ethanol steam reforming (ESR). Depending on the Ni loading contents, the added Ni selectively interacts with CeZrOx–Al2O3, resulting in the stepwise locations of Ni over CeZrOx–Al2O3. This behavior induces a remarkable difference in hydrogen production and coke formation in ESR. The selective interaction between Ni and CeZrOx for 10-wt.% Ni generates more oxygen vacancies in the CeZrOx lattice. The Ni sites near the oxygen vacancies enhance reforming via steam activation, resulting in the highest hydrogen production rate of 1863.0 μmol/gcat·min. In contrast, for 15 and 20-wt.% Ni, excessive Ni is additionally deposited on Al2O3 after the saturation of Ni–CeZrOx interactions. These Ni sites on Al2O3 accelerate coking from the ethylene produced on the acidic sites, resulting in a high coke amount of 19.1 mgc/gcat·h (20Ni/CZ-Al). 相似文献
2.
《Ceramics International》2022,48(20):29892-29899
It is very challenging for 3D printing based on the selective laser melting (SLM) technology to obtain cermet bulk materials with high density and homogeneous microstructures. In this work, the SLM process of the cermet powders was studied by both simulations and experiments using the WC-Co cemented carbides as an example. The results indicated that the evolution of the ceramic and metallic phases in the cermet particle during the heating, melting and solidification processes were all significantly inhomogeneous from atomic scale to mesoscale microstructures. As a consequence, the microstructural defects were caused intrinsically in the printed bulk material. The formation and growth of the bonding necks between the particles were mainly completed at the later stage of laser heating and the early stage of solidification. Both simulations and experiments demonstrated that thin amorphous layers formed at the ceramics/metal interfaces. This work disclosed the mechanisms for the evolution from the atomic scale to microstructure during the SLM printing of cermet powders, and discovered the origin of the defects in the printed cermet bulk materials. 相似文献
3.
4.
Theoretical investigation of solvent effects on the selective hydrogenation of furfural over Pt(111)
Jian Wang Cun-Qin Lv Jian-Hong Liu Rong-Rong Ren Gui-Chang Wang 《International Journal of Hydrogen Energy》2021,46(2):1592-1604
It was well known that solvent effect plays a very important role in the catalytic reaction. There are many theoretical studies on the solvent effect in homogeneous catalysis while there are few theoretical studies on the solvent effect in the heterogeneous catalytic reaction and there has been no work to investigate the solvent effect on furfural transformation in heterogeneous catalysis. In the present work, both the density functional calculations and the microkinetic analysis were performed to study the selective hydrogenation of furfural over Pt(111) in the presence of methanol as well as toluene and compared with that in the gas condition. The present results indicated that the methanol can enhance the adsorption strength of furfural and other oxygen-containing reaction species due to its relatively strong polarity properties and this can be a main reason for solvent-induced high activity and selectivity. Another reason is that reaction paths study showed that the presence of methanol solvent makes the dehydrogenation of furfural less thermochemical due to the fact that furfural is more stabilized than that of dehydrogenation species, and methanol also has an inhibition effect on the dehydrogenation of furfural in the kinetic aspect, and further energetic span theory proves highest activity and selectivity for hydrogenation in methanol solvent of vapor, methanol and toluene. Moreover, microkinetic model simulation demonstrated that the activity and selectivity of hydrogenation in methanol is both higher than that in vapor and toluene. The much higher activity in methanol is due to the stabilized adsorbed reactants in the surface, which leads to a higher surface coverage of furfural. It might be proposed based on the present work that a solvent with relatively strong polarity may be favorable for the high selective hydrogenation of furfural. 相似文献
5.
Andrea Bedon Jean Paul Viricelle Mathilde Rieu Simone Mascotto Antonella Glisenti 《International Journal of Hydrogen Energy》2021,46(27):14735-14747
In this contribution brownmillerite-based nanocomposite cathode for Single-Chamber Solid Oxide Fuel Cells is developed. These cells can be very attractive especially for small and cheap devices because of the absence of seals. The efficiency of SC-SOFCs is strictly connected to the selectivity of anode and cathode, the bottleneck for this technology. The development of a cathode inert in fuel oxidation is particularly challenging. Our strategy is to start from a catalytically un-active support (CFA = Ca2FeAl0.95Mg0.05O5) and induce the formation of iron oxide based nanoparticles, expected to activate oxygen. Symmetric (CFA + FeOx/CGO/CFA + FeOx) and complete cells (CFA + FeOx/CGO/Ni-CGO) are studied in air and methane/oxygen 2:1 mixture. The Area Specific Resistance of CFA + FeOx is less than 1/3 that of CFA. The high selectivity allows to reach an efficiency of 25%; power still needs to be increased but we demonstrated the possibility to develop selective low cost electrodes. The effect of air, methane/oxygen exposure and the heat treatments were carefully investigated. 相似文献
6.
7.
Woo‐Seok Cheong 《ETRI Journal》2003,25(6):503-509
Selective epitaxial growth (SEG) of silicon has attracted considerable attention for its good electrical properties and advantages in building microstructures in high‐density devices. However, SEG problems, such as an unclear process window, selectivity loss, and nonuniformity have often made application difficult. In our study, we derived processing diagrams for SEG from thermodynamics on gas‐phase reactions so that we could predict the SEG process zone for low pressure chemical vapor deposition. In addition, with the help of both the concept of the effective supersaturation ratio and three kinds of E‐beam patterns, we evaluated and controlled selectivity loss and nonuniformity in SEG, which is affected by the loading effect. To optimize the SEG process, we propose two practical methods: One deals with cleaning the wafer, and the other involves inserting dummy active patterns into the wide insulator to prevent the silicon from nucleating. 相似文献
8.
9.
低温低渗透砂岩油藏窜流大孔道深部封堵技术研究 总被引:4,自引:0,他引:4
所用堵剂为高强度的淀粉接枝聚丙烯酰胺交联凝胶SAMG-1,由<6%淀粉、4.5%-5.5%丙烯酰胺、0.003%-0.006%交联剂组成,35℃成胶时间受淀粉和交联剂用量控制,为18-20小时以上,成胶前黏度-100 mPa.s。该堵剂具有长期稳定性,在储层岩心中注入深度15 cm的堵剂,在35℃候凝48小时后及老化90天后,封堵强度分别为0.61和0.59 MPa/cm,封堵率分别为98.6%和98.1%。该堵剂优先进入高渗层,注入0.5 PV并成胶后,2组双填砂管组成的模型低、高渗管渗透率保留率分别为68.4%、0.7%和69.4%、0.0%。吉林扶余油田西一区+15-8.2区块有水井6口,油井13口,含水率达91.5%,注入水最快在5天内到达油井。报道了该区块整体深部调剖封堵窜流通道的情况,详细叙述了+15-9.2井施工中通过注入压力和井底回压控制注入流量,使堵剂陆续进入原生和次生孔道的工艺作业,该井设计注入堵剂92 m3。6口水井整体调剖后,油井产液量差别减小,产油量增加,有效期已超过了9个月,共增油843 t,含水平均下降3.87%。图7表1参8。 相似文献
10.
屏蔽暂堵技术在青西地区的应用 总被引:3,自引:0,他引:3
对玉门油田青西地区裂缝性储层的保护方法 ,最有效的技术手段就是利用屏蔽暂堵技术。根据该地区储层岩性不同 ,分别选用聚磺、金属离子、阳离子钻井液体系 ,在原浆的基础上加入EP - 2、LF - 1和硅油消泡剂 ,配制成屏蔽暂堵钻井液体系。通过室内试验 :屏蔽暂堵钻井液体系API失水小于 5ml,HTHP失水小于 13ml,岩心渗透率恢复值大于 70 % ,起到了良好的屏蔽暂堵效果。经完井试油发现 ,储层污染明显减小 ,产量与邻井相比有大幅度提高 相似文献