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排序方式: 共有104条查询结果,搜索用时 15 毫秒
1.
2.
Meso-porous Al2O3-supported Ni catalysts exhibited the highest activity, stability and excellent coke-resistance ability for CH4 reforming with CO2 among several oxide-supported Ni catalysts (meso-porous Al2O3 (Yas1-2, Yas3-8), -Al2O3, -Al2O3, SiO2, MgO, La2O3, CeO2 and ZrO2). The properties of deposited carbons depended on the properties of the supports, and on the meso-porous Al2O3-supported Ni catalyst, only the intermediate carbon of the reforming reaction formed. XRD and H2-TPR analysis found that mainly spinel NiAl2O4 formed in meso-porous Al2O3 and -Al2O3-supported catalysts, while only NiO was detected in -Al2O3, SiO2, CeO2, La2O3 and ZrO2 supports. The strong interaction between Ni and meso-porous Al2O3 improved the dispersion of Ni, retarded its sintering and improved the activated adsorption of CO2. The coking reaction via CH4 temperature-programed decomposition indicated that meso-porous Al2O3-supported Ni catalysts were less active for carbon formation by CH4 decomposition than Ni/-Al2O3 and Ni/-Al2O3. 相似文献
3.
Nianxue Song Colin Rhodes David W. Johnson Graham J. Hutchings 《Catalysis Letters》2005,102(3-4):271-279
Temperature programmed reduction (TPR) and oxidation (TPO) are used extensively in catalyst characterisation. In this paper, we examine the use of TPR/TPO cycles for the characterisation of a range of molybdates and single oxides. In particular we observe that the first cycle differs from that of subsequent analyses, even when the maximum temperature is limited to that used in the catalytic reaction. The effect is independent of heating rates and cooling atmospheres and has been demonstrated using different bed configurations. This observation has significance when these oxides are used in periodic flow reactors that involve many cyclical reduction/oxidation. 相似文献
4.
种植屋面技术难点在于屋面结构层与功能层的耐根系穿刺能力,而本文即对耐根穿刺型TPO防水卷材的施工技术作为研究对象,简要介绍了该材料在屋面应用中干铺法施工技术实施的方法,并结合施工质量得出相应的保证措施。 相似文献
5.
通过试验系统地研究了焊接参数特别是温度和速度对TPO自粘复合防水卷材中TPO层接缝剥离强度的影响,并确定了TPO的焊接窗口.结果表明,在较大范围的焊接温度和速度下,TPO的接缝剥离强度从9.10 N/mm变化到11.88N/mm,符合相关标准规范的要求.根据试验数据确定的焊接窗口较宽,表明TPO可焊性良好,焊接操作较易. 相似文献
6.
从介绍热塑性聚烯烃TPO及其在汽车工业中的应用出发,综述了近年来国内外在TPO组分的相容性、TPO的形态和性能、TPO/CPO(氯化聚烯烃)的界面形态和结构、TPO/CPO粘结性能和机理几个方面研究的最新进展,并提出了未来的发展趋势。 相似文献
7.
Yue Baohua Zhou Renxian Sha Feng Zheng Xiaoming 《中国稀土学报(英文版)》2006,24(1):28-28
Methane Combustion and TPR/TPO Properties of Pd/Ce_xZr_ 1-xO_2/Al_2O_3 Catalysts 相似文献
8.
Praharso Adesoji?A.?Adesina David?L.?TrimmEmail author Noel?W.?Cant 《Korean Journal of Chemical Engineering》2003,20(3):468-470
The production of hydrogen from isooctane over three rhodium-based catalysts has been examined. The reaction entailed total
oxidation of a proportion of the fuel followed by reforming of isooctane to produce hydrogen. Rhodium (1% wt) was impregnated
on three different supports: alumina, ceria-alumina, and ceria-zirconia. No differences in catalytic activity were observed,
but reaction yield changed with the support. Ceria-zirconia was found to be the preferred support since methanation did not
occur over the catalyst. 相似文献
9.
High-resolution scanning transmission electron microscope (HR STEM) measurements were performed on a thermoplastic polyolefin (TPO) substrate coated with chlorinated polyolefin (CPO). This CPO was a maleated chlorinated polypropylene containing 21.8 wt% Cl. The TPO investigated was a blend of high-modulus isotactic polypropylene (iPP) with a crystalline ethylene-butene copolymer (EB9) containing 9 wt% butene. For these injection-molded samples, examined ca. 10 mm from the mold gate, a stratified morphology found at TPO surface consisting of thin fibers of EB9 trapped in a transcrystalline iPP matrix, with crystalline lamellae propagating from the matrix across the EB9 domains. This structure was unperturbed when the plaques were coated (from tetrahydrofuran solution) with a 5 μm layer of CPO, but underwent changes of increasing severity when subjected either to a dry bake at 120 °C or annealing at 120 °C in the presence of xylene vapor. The interfacial structure between the CPO and the TPO was probed by TEM with energy dispersive X-ray imaging (EDX). The elemental chlorine across the interface gave good fits to a tan h function, and the interface thickness increased from 23 ± 2 nm to 28 ± 1 nm upon annealing at 120 °C for 30 min. After annealing in the presence of xylene vapor, this value increased to 50 ± 4 nm. As reference points, we determined an interface thickness of 29 ± 3 nm for the CPO-EB interface and 15 ± 2 nm for the interface between CPO and iPP. 相似文献
10.
Heng-Yu Li Yun Luo Christophe Ballif 《Polymer-Plastics Technology and Engineering》2015,54(4):416-424
In certain laminators for poly (ethylene-co-vinyl acetate) (EVA) encapsulation process of photovoltaic modules, cooling press (CP) is applied to the module after encapsulation. Here, the effect of CP on the optical transmission through common PV encapsulants is studied. Interestingly, CP is shown to reduce drastically the scattering of the light between 400 and 700 nm traveling through the thermoplastic polyolefin (TPO)-based encapsulant. Post-annealing tests prove this effect to be stable at the temperature up to 85°C. This work has discovered a simple solution to mitigate the milky appearance of the TPO encapsulant and hence greatly enhanced its competitiveness against EVA. 相似文献