氧化钒制取碳化钒的热力学分析

采用热力学的方法对以五氧化二钒为原料制取碳化钒的工艺过程进行了分析,分析表明:钒氧化物的转化过程中遵守逐级还原理论。钒氧化物碳化过程中,不转化为金属钒,直接转化为碳化钒。在钒氧化物的转化过程中,应尽可能使其转化为二氧化钒。若采用气相还原碳化的方法,可通过调节气体的流量、配比、还原与碳化工艺参数进行质量控制。     

A molecular level mechanism ofn-butane oxidation to maleic anhydride over vanadyl pyrophosphate

A molecular level mechanism is proposed for the highly selective 14-e^– oxidative transformation ofn-butane to maleic anhydride on the surface of vanadyl pyrophosphate. The mechanism suggests that the dimeric active sites assume at any given time, one of four possible interconvertible states which differ from each other in the number of available oxygen atoms and the formal oxidation states of the individual vanadium atoms. The relative ratios of active sites in each of the four possible states are dictated by the reaction conditions, the redox properties of the reacting gases and the structure of the vanadyl pyrophosphate active surface. A crucial feature of the mechanism is a pseudo-ozonide surface species formed by the interaction of a chemisorbed dioxygen molecule and an adjacent metal-oxo group. This unusual species is responsible for the initial activation of then-butane, which occurs when the chemisorbed dioxygen abstracts an H-atom from the alkane and the adjacent metal-oxo group reacts with the incipient alkyl radical to form an alkoxy group. The proposed mechanism is entirely consistent with literature reports describing the behaviour of (VO)₂P₂O₇ in flow, pulse and TAP reactors.     

DaWson型磷钨钒杂多酸催化合成苹果酯的研究

制备了Dawson型磷钨钒杂多酸催化剂，用Fr—IR分析方法对催化剂进行了结构表征，并以乙酰乙酸乙酯与乙二醇为原料催化合成了苹果酯。实验结果表明，磷钨钒杂多酸是合成苹果酯的理想催化剂，其较优反应条件为：乙酰乙酸乙酯0．1 mol，n（乙酰乙酸乙酯）：n（乙二醇）=1．0：1．5，催化剂的用量为反应物总质量的1．5％，12mL甲苯，回流反应3．0h，苹果酯的收率可达83．0％以上。     

镉掺杂Bi2VO5.5的结构、相变、电导性能的研究

通过X射线衍射,DSC和交流阻抗等测试方法研究了镉掺杂Bi2VO5.5的结构,相变和电性能.由于Cd2+的半径与V5+和Bi3+的半径都比较接近,所以在合成BICDVOX体系时假设了两种模型:Bi2V1-xCdxO5.5-3/2x(x=0.05,0.075,0.10,0.125,0.15)和Bi2-xVCdxO5.5-1/2x (x=0.10,0.20).XRD和DSC分析表明了这两种模型可能同时存在.根据交流阻抗谱的结果,当x=0.10时,具有较高的电导率,这归因于此成分使高电导的四方相可以稳定到室温.     

虚拟天文台技术在HXMT卫星任务中应用的设想

随着国际上天文项目的发展与推进,天文数据呈爆炸式增长。如何从浩瀚如海的大数据集中快速检索所需信息,已成为各国科研人员共同面对的问题。虚拟天文台（Virtual Observatory,VO）为满足对大规模天文数据进行处理分析、检索访问和共享发布等需求,提供了一系列 VO 标准协议和集成化服务。开发符合 VO 标准协议的天文数据发布与检索系统、集成数据访问发布和可视化分析服务,符合当前的发展趋势。本文在回顾 VO发展历程的基础上,对 VO 体系结构、VO 标准协议等若干关键技术进行概括阐述。同时,基于 VO的技术框架,提出硬 X 射线调制望远镜（Hard X-ray ModulationTelescope,HXMT）卫星数据发布与检索系统的初步设想,设计符合卫星任务需求的体系结构,并选取相关的 VO 标准协议加以实现。     

Construction of VS2/VOx Heterostructure via Hydrolysis-Oxidation Coupling Reaction with Superior Sodium Storage Properties

Heterostructure engineering is one of the most promising modification strategies for reinforcing Na⁺ storage of transition metal sulfides. Herein, based on the spontaneous hydrolysis-oxidation coupling reaction of transition metal sulfides in aqueous media, a VO_x layer is induced and formed on the surface of VS₂, realizing tight combination of VS₂ and VO_x at the nanoscale and constructing homologous VS₂/VO_x heterostructure. Benefiting from the built-in electric field at the heterointerfaces, high chemical stability of VO_x, and high electrical conductivity of VS₂, the obtained VS₂/VO_x electrode exhibits superior cycling stability and rate properties. In particular, the VS₂/VO_x anode shows a high capacity of 878.2 mAh g⁻¹ after 200 cycles at 0.2 A g⁻¹. It also exhibits long cycling life (721.6 mAh g⁻¹ capacity retained after 1000 cycles at 2 A g⁻¹) and ultrahigh rate property (up to 654.8 mAh g⁻¹ at 10 A g⁻¹). Density functional theory calculations show that the formation of heterostructures reduces the activation energy for Na⁺ migration and increases the electrical conductivity of the material, which accelerates the ion/electron transfer and improves the reaction kinetics of the VS₂/VO_x electrode.     

基于虚拟组织的校园网格服务发现机制

为了有效定位校园网格中大量不同属性的动态服务,提出一种校园网格服务发现机制。以小世界模型为理论依据组建虚拟组织(VO),构建普通节点-域-VO的3层体系结构模型,基于该模型提出IS-Gossip算法。最上层在VO之间、中间层在VO内各域间分别用IS-Gossip算法进行分布式查找,最下层在域内进行集中式查找。算法分析表明,该机制提高了服务发现的可扩展性和查询效率。     

网格技术框架的探讨和研究

介绍了网格计算的概念，描述了在虚拟组织环境中的网格技术的层次框架，重点探讨了每一层的作用和功能，最后通过实例进行了具体的阐述。     

基于MPEG－4的视频检索技术研究

1 引言今天,人类的科学文明发展到了很高的水平。人们足不出户,就可在家里欣赏到声形并茂的视听内容。我们可以根据需要去选择视听材料。拿电影来举例,如果我们知道所要查找的影片名字时,这很好办;但如果我们仅凭童年的记忆依稀记得某个场景的一个细节,这仍然是一个未解决的问题。当人们可以哼着旋律找到心目中的歌曲时,视频检索就成了一个亟待     

Spectrally selective and adaptive surfaces for protection against radiative heating: ITO and VO2

Two surface materials for reducing absorptivity of heat radiation from fires have been investigated. The first is VO₂, which is a thermochromic material. When the temperature of a VO₂ surface increases over a certain temperature, it switches, ideally, from infrared (IR)‐absorbing to IR‐reflecting. VO₂ window coatings are still on a research level, yet to be commercialized. In this study, VO₂ powder available on the market was investigated. The thermochromic effect could be identified but was not large enough to significantly improve the fire properties of treated surfaces. Some thoughts concerning how to improve the performance of VO₂ are discussed. The second investigated material is indium tin oxide (ITO), which is a so called low‐e coating, which means that it has low emissivity and absorptivity in the IR part of the spectrum. ITO is spectrally selective in the sense that it transmits visible light while reflecting a large fraction of the IR radiation, which is a rare property for surfaces in general but a typical property of thin electrically conducting non‐metallic films. It is shown that the application of ITO to poly(methyl methacrylate) (PMMA) significantly improves its fire properties. ITO coating is a mature technology already in widespread use today in the electronics industry. Copyright © 2012 John Wiley & Sons, Ltd.