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排序方式: 共有104条查询结果,搜索用时 15 毫秒
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Taeko Izumi Yoshihiro Yagimuma Masanori Haga 《Journal of the American Oil Chemists' Society》1997,74(7):875-878
Enyzmatic amidation of the primary amines β-alanine ethyl ester and 3-aminopropionitrile with methyl laurate by means of immobilized
lipase (Candida antarctica lipase, CAL) resulted in the formation in good yield of N-lauroyl-β-alanine ethyl ester and 3-(N-lauroylamino)-propionitrile, respectively. When 3-amino-propionitrile was used as substrate, diisopropyl ether was a suitable
solvent. Changing the reaction temperature (12–80°C) did not affect the yields, and room temperature was a suitable temperature
for this reaction. In the investigation of reaction conditions, the use of equimolar amounts (5 mmol) of substrate and ester,
along with 0.5 g of CAL, in diisopropyl ether gave the best yield (99.3%) after 24 h of incubation at 24°C. The enzyme activity
in the amidation reaction did not decrease even after six uses. With β-alanine ethyl ester hydrochloride as substrate, diisopropyl
ether was unsuited as a solvent owing to the low solubility of the substrate in this solvent.
In this reaction, the best yield (82.0%) was attained by using dioxane as solvent. CAL achieved higher extents of amide synthesis
with long-chain than with short-chain ester substrates. The enzyme accepted only nonbulky primary amines as substrates. 相似文献
3.
The effects of functionalized multi‐walled carbon nanotubes (MWCNTs) on thermal and chemorheological behaviors of an epoxy‐based nanocomposite system were investigated. Chemical functionalization of MWCNTs by acid modification (A‐MWCNTs) and chemical amidation (D‐MWCNTs) was confirmed using Fourier transform infrared spectroscopy and thermogravimetric analysis. It was found that the D‐MWCNTs had a significant effect on the chemorheological behaviors of the epoxy‐based nanocomposite. Compared to the epoxy/A‐MWCNT nanocomposite, the epoxy/D‐MWCNTs nanocomposite showed a significant increase in gel time, as obtained from isothermal rheology measurements. Also, the storage modulus of the diglycidylether of bisphenol F (DGEBF)/D‐MWCNTs nanocomposite was higher than that of the DGEBF/D‐MWCNTs nanocomposite and gradually increased with an increase of frequency. This could be interpreted by the relatively strongly interconnected structure of the D‐MWCNTs in the DGEBF epoxy resin, which arises from the functionalized alkyl groups of the D‐MWCNTs in dispersion phases with the DGEBF epoxy resin. Copyright © 2012 Society of Chemical Industry 相似文献
4.
由3-氨基丙基三甲氧基硅烷(NH2-propyl-silane)出发,在碱催化条件下采用水解缩合一锅法合成了笼形氨丙基硅倍半氧烷(NH2-propyl-POSS)。红外光谱、核磁共振、电喷雾飞行质谱(ESI-TOF)表征结果表明,合成产物NH2-propyl-POSS是不同大小笼形结构的混合物,其中T8、T9、T10笼形结构含量较高。由NH2-propyl-POSS分别与乙酸和丙炔酸进行酰胺化反应,进一步合成了乙酰基丙基POSS(CH3-CONH-POSS)和丙炔酰基丙基POSS(CH≡C—CONH-POSS),并通过红外光谱、氢谱、碳谱分析表征了其结构。X射线衍射分析结果表明,3种POSS均为非晶态结构。通过热重分析可知,NH2-propyl-POSS具有较高的热稳定性。将NH2-propyl-POSS用于提高环氧树脂(EP)的热稳定性,添加量为5 %(质量分数,下同)时,EP/NH2-propyl-POSS共混物的玻璃化转变温度(Tg)提高至180.7 ℃,极限氧指数(LOI)为25.2 %。 相似文献
5.
研究了对苯二甲酸法合成对苯二甲酰胺的反应过程,考察了溶剂、温度、时间等反应条件对目的产物收率的影响。结果表明合成对苯二甲酰胺的优化条件为:用适当量的乙二醇溶解对苯二甲酸二甲酯,60℃常压通氨气反应8h,对苯二甲酰胺收率可达94%。 相似文献
6.
Y. Pan B. Shiell J. Wan M.J. Coventry W.P. Michalski A. Lee H. Roginski 《International Dairy Journal》2007,17(12):1450-1459
Amidation of bovine β-lactoglobulin (β-Lg) imparted antimicrobial properties to this protein. Amidated β-Lg was strongly bactericidal against resting cells of Pseudomonas fluorescens, Pseudomonas fragi and Bacillus subtilis, but had a much weaker effect against Escherichia coli, Enterococcus faecalis, Salmonella typhimurium and Listeria monocytogenes. Neither native nor amidated β-Lg was effective against the yeast Saccharomyces cerevisiae and the mould Penicillium candidum. Mass spectrometric analysis demonstrated that amidation of β-Lg converted aspartyl and glutamyl residues to asparaginyl and glutaminyl residues, respectively, and that the amidation reaction did not occur to the same extent on every β-Lg molecule. The charge change was also confirmed by SDS–PAGE, ion exchange chromatography and the change in isoionic point of β-Lg. Reverse-phase chromatography showed that amidation also led to alterations in hydrophobicity of the β-Lg molecule. The antibacterial properties of the amidated β-Lg appear to be dependent on the net positive charge and charge distribution on the molecule. 相似文献
7.
Qi Shuai Guojun Deng Zhijie Chua D. Scott Bohle Chao‐Jun Li 《Advanced Synthesis \u0026amp; Catalysis》2010,352(4):632-636
Copper(I) bromide‐catalyzed amidation of 2‐arylpyridine derivatives and 1‐methylindoles with a variety of amides was achieved by employing tert‐butyl peroxide (TBP) as oxidant. Aryl halides could be tolerated under the reaction conditions. Neither a special ligand nor a base was required for this amidation process. 相似文献
8.
A novel and highly efficient copper‐catalyzed tandem synthesis of triazoloquinazolinones is explored. The synthetic strategy involves a sequential one‐pot click reaction followed by aerobic intramolecular C H amidation. Two distinct and important transformations were carried out in one‐pot by employing a single cost‐effective copper catalyst. The milder, rapid and ligand‐free reaction conditions as well as a broader substrate scope are the salient features of this novel protocol.
9.
红色基KD合成新工艺以氯苯甲酸为原料,经硝化、醚化、酰胺化、还原4步反应制得。该工艺缩短了反应步骤,提高了收率,降低了成本。其中酰胺化反应是关键步骤,文章分析了该反应的亲核取代机理及催化剂种类、催化剂用量、溶剂、温度等条件对反应的影响。 相似文献
10.
Preparation of laurel oil alkanolamide from laurel oil 总被引:1,自引:1,他引:1
Hakan Kolancilar 《Journal of the American Oil Chemists' Society》2004,81(6):597-598
A low-temperature synthesis of laurel oil alkanolamides directly from laurel oil and ethanolamine was carried out in essentially
quantitative yields. The ethanolamine/laurel oil molar ratio used was 10∶1. Even though amine served as a catalyst in the
reaction, we used sodium methoxide at a ratio of 0.2–2% as a second catalyst. The reaction was complete in 1–9 h at room temperature.
The identity of the amide was confirmed by IR and 13C NMR spectroscopy. 相似文献