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Wladek T. Sobol L.John SchreinerLjubis̆a Miljković Maria E. Marcondes-HeleneLeonard W. Reeves M.Mik Pintar 《Fuel》1985
The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent. 相似文献
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Hussain Sheikha Anil K. Mehrotra Mehran Pooladi-Darvish 《Journal of Petroleum Science and Engineering》2006,53(3-4):189-202
An inverse solution methodology is developed for the estimation of diffusion coefficient of gases in highly viscous, oil-sands bitumens from isothermal, pressure-decay measurements. The approach involves modeling the rate of change in pressure using the diffusion equation for the liquid phase coupled with a mass balance equation for the gas phase. The inverse solution framework is utilized to arrive at two graphical techniques for estimating the diffusion coefficient. Both techniques involve the determination of the slope of a straight line resulting from plotting the experimental data in accordance with the developed model. An advantage of the proposed techniques is that the diffusion coefficient is estimated directly, i.e. without making it an adjustable parameter. The novelty of the proposed method is in its simplicity as well as its ability to isolate portions of the pressure-decay data affected by experimental fluctuations. The effect of the initial pressure on the predicted diffusion coefficient and pressure-decay profile was also investigated. The diffusion coefficients of CO2, CH4, C2H6 and N2 in Athabasca bitumen at 50–90 °C and about 8 MPa were estimated and compared with literature values. 相似文献
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Ronak A. Kapadia Simant R. Upreti Ali Lohi Ioannis Chatzis 《Journal of Petroleum Science and Engineering》2006,51(3-4):214-222
In this work, a mathematical model is developed and simulated to determine gas dispersion along with solubility during the vapor extraction (Vapex) of live oil from a laboratory scale physical model. The physical model is a rectangular block of homogenous porous medium saturated with heavy oil and bitumen. At a given temperature and pressure, the block is initially exposed on its side to a solvent gas, which diffuses into the medium and gets absorbed. The absorption of gas reduces the viscosity of heavy oil and bitumen causing it to drain under gravity. The low-viscosity “live oil” is produced at the bottom of the porous block. The production of live oil with time is accompanied by the shrinkage of oil in the block as well as its increased exposure to gas from top. These phenomena of Vapex are described by the mathematical model, which is used to calculate live oil production with various values of gas solubility and dispersion. Their optimal values are determined for the vapor extraction of Cold Lake bitumen with butane by matching calculated live oil production with its experimental values published earlier. 相似文献
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遵义后坝奥陶系红花园组生物碎屑灰岩中发现油苗和沥青,经过气/源岩、沥青/源岩对比,震旦、寒武及奥陶系产层轻烃C6+7结构组成基本一致,奥陶系含油苗灰岩轻烃星图与震旦系泥岩、寒武系沥青砂岩星图较为相似,显示红花园组油苗主要来源于震旦系和下古生界过成熟或高成熟海相烃源岩,油气经历了较长距离的运移,得以在奥陶系中保存下来。这对评价该地区油气前景有重要意义,预示着可能存在一套特殊的含油气组合,存在以O1h古风化壳储集层为目的层的勘探领域。在兴文—叙永一线以西地区现今下古生界储盖组合保存良好,在适当的构造圈闭中可形成油气藏。志留系和二叠系产层轻烃C6+7与震旦系、寒武系及奥陶系等产层轻烃C6+7明显有别,星图对比性差,表征它们之间成烃母质或沉积环境均有不同。 相似文献
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Viscosity data over a temperature range of 37-115°C and a pressure range of 0-10 MPa gauge are presented for a Cold Lake bitumen sample. These data show that the compression of Cold Lake bitumen results in a significant increase in its viscosity. Results are compared with those from a similar study on an Athabasca bitumen sample. Also presented are two correlations for the effects of pressure and temperature on the viscosity of Cold Lake bitumen. 相似文献
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