Host/guest complex of Me-β-CD/2,2-dimethoxy-2-phenyl acetophenone for initiation of aqueous photopolymerization: Kinetics and mechanism

Methylated-β-cyclodextrin (Me-β-CD) was used to complex the photoinitiator, 2,2-dimethoxy-2-phenyl acetophenone (DMPA), yielding a water-soluble host/guest complex. The comparative studies demonstrated that the Me-β-CD complexed DMPA exhibited a high photoreactivity identical to the uncomplexed DMPA, while the CD complex obviously influenced the products of primary photolysis of DMPA and the photopolymerization kinetics due to the steric effect of CD on the subsequent initiation reactions. The photopolymerization rate of acrylamide can be described by the equation: R_p=K[2a]^0.62[M]^1.37[I]^0.5[Me-β-CD]⁰. The mechanism of polymerization was also discussed.     

Drag coefficient of flow around a sphere: Matching asymptotically the wide trend

An empirical relationship of drag coefficient of flow around a sphere is developed for the entire range of Particle Reynolds numbers reported in the literature from Stokes regime to the condition when turbulent boundary layer prevails. The relationship is obtained using an approach to match asymptotically the wide trend of drag coefficient. The matching approach, which relies on dividing the wide trend into smaller segments that can be combined into an overall relationship, employs regression techniques and thus warrants the best-fit accuracy results. The relationship is calibrated with experimental data available in the literature covering the entire range for Reynolds numbers up to ~ 10⁶. For Reynolds values greater than 10⁶, the relationship renders a drag coefficient of 0.2. The performance of the relationship is tested and compared with other suitable models found in the literature. This relationship is also transformed into an explicit expression for settling velocity calculations.     

Posttraumatic stress in children and adolescents exposed to family violence: I. Overview and issues.

Exposure to child physical abuse and parents' domestic violence can subject youth to pervasive traumatic stress and can lead to posttraumatic stress disorder (PTSD). This article presents evolving conceptualizations in the burgeoning field of trauma related to family violence exposure and describes how the often repeating and ongoing nature of family violence exposure can complicate a PTSD diagnosis. In addition, recent literature indicates that children exposed to family violence may experience problems in multiple domains of functioning and may meet criteria for multiple disorders in addition to PTSD. Considerations salient to the recognition of traumatic stress in this population and that inform assessment and treatment planning are presented. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Exact integration in the boundary element method for two-dimensional elastostatic problems

This paper derives the exact integrations for the integrals in the boundary element analysis of two-dimensional elastostatics. For facilitation, the derivation is based on the simple forms of the fundamental functions by taking constant, discontinuous linear and discontinuous quadratic elements as examples. The efficiency and accuracy of the derived exact integrations are verified against five benchmark problems; the results indicate that the derived exact integrations significantly reduces the CPU time for forming the matrices of the boundary element analysis and solving the internal displacements.     

地震复合波地质属性的研究方法

在地震资料解释中,地震复合波的地质属性问题一直没有得到很好地解决。本文针对松辽盆地砂泥岩薄互层的地质特点,提出了用波形合成追踪法研究地震复合波地质属性的方法。该方法在地震复合波正演合成过程中有五个可以识别的特征界面,其中 C 界面是地震复合波形成的主导界面;C 至 D 界面间的地层为形成地震复合波的主要地层。因此,找准 C 界面深度是建立地震复合波与钻孔地层间有机联系的关键,对地震地质层位准确标定和利用地震剖面复合波波形信息进行岩性预测极为重要。文中的应用实例表明,用该方法在松辽盆地较好地建立了地震信息与地质信息间的对应关系,解决了一些疑难地质问题,取得了较好的勘探效果。     

“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。     

A BOUNDARY INTEGRAL EQUATION AND ITS NUMERICAL SOLUTION OF POTENTIAL FLOW AROUND SURFACE-IRREGULA-RITIES

In this paper,using complex functional theory,the authors turn the potentialflow around the surface irregularities in a pressure conduit and semi-infinite platforms intoDirichlet problem.Based on Schwarz formula and by the application of Plemelj's formula,theauthors change the problem into the integration of a Cauchy boundary integral equation in theflow plane through the substitution of variables.Using numerical integration,the authors obtainthe velocity distribution and pressure coefficient along surface irregularities and platforms.Thephysical concept of this method is clear,the convergent speed is rapid and the computative effi-ciency is high.The calculated values agree well with the measured results.It is an effective andsimple method in solving potential flow.     

A review of error estimation and adaptivity in the boundary element method

When using the boundary element method, the accuracy of the numerical solution depends critically on the discretization of the boundary into elements (panels). The distribution of the panels is one of the most important decisions taken when analyzing a problem, but still the vast majority of users employ empirical guidelines to distribute the panels. This paper reviews the various adaptive schemes that have been proposed for boundary elements. Numerical results are obtained for infinite fluid flow problems and free surface problems and are used to assess the reliability and effectiveness of each method.     

Non‐reflecting artificial boundaries for transient scalar wave propagation in a two‐dimensional infinite homogeneous layer

This paper presents an exact non‐reflecting boundary condition for dealing with transient scalar wave propagation problems in a two‐dimensional infinite homogeneous layer. In order to model the complicated geometry and material properties in the near field, two vertical artificial boundaries are considered in the infinite layer so as to truncate the infinite domain into a finite domain. This treatment requires the appropriate boundary conditions, which are often referred to as the artificial boundary conditions, to be applied on the truncated boundaries. Since the infinite extension direction is different for these two truncated vertical boundaries, namely one extends toward x →∞ and another extends toward x→‐ ∞, the non‐reflecting boundary condition needs to be derived on these two boundaries. Applying the variable separation method to the wave equation results in a reduction in spatial variables by one. The reduced wave equation, which is a time‐dependent partial differential equation with only one spatial variable, can be further changed into a linear first‐order ordinary differential equation by using both the operator splitting method and the modal radiation function concept simultaneously. As a result, the non‐reflecting artificial boundary condition can be obtained by solving the ordinary differential equation whose stability is ensured. Some numerical examples have demonstrated that the non‐reflecting boundary condition is of high accuracy in dealing with scalar wave propagation problems in infinite and semi‐infinite media. Copyright © 2003 John Wiley & Sons, Ltd.     

Optical data storage by novel photoelectrochromic polymer

A novel elastic polymer containing 4,4′-bipyridinium salts with tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as part of the main chain was synthesized. The cast film showed persistent and reversible colour changes due to photoinduced electron transfer upon excitation of an ion-pair charge-transfer band (_ex >365 nm) in vacuo. The lifetime of the coloured state markedly depended on temperature. The optically written data were stored without decay below 0°C and were erased thermally at elevated temperatures. The colour changes were reversibly repeatable for many times.