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1.
Field surveys of a series of conjugated diunsaturated straight-chain primary alcohols, acetates, and aldehydes (dienes), including the 3,5-dode-cadienyl, 8,10-dodecadienyl, 3,5-tetradecadienyl, 8,10-tetradecadienyl, 9,11-tetradecadienyl, and 10,12-tetradecadienyl primary alcohols, acetates, and most aldehydes, and the related monounsaturated straight-chain primary alcohols, acetates, and aldehydes (monoenes), including the 3-dodecadienyl alcohol and acetates, attracted the following species from the title families. Diene attractants have been demonstrated for at least onePhyllonorycter sp.,Chionodes lugubrella (Fabr.),Leptostales ferruminaria (Zell.),Drepana bilineata (Pack.),Pyrausta fodinalis (Led.),Notocelia purpurissatana Heinr.,Phaneta alterana Heinr. Monoene attractants were demonstrated forHedya separatana (Kft.),Cydia fletcherana (Kft.),Barbara mappana Free.,Ancylis burgessiana (Zell.),Ancylis nubeculana Clem.,Evippe prunifoliella Cham.,Phlyctaenia coronata tertialis (Gn.), aChionodes sp., a Gelechiidae sp., and an unidentifiedPhyllonorycter sp. Replicated field experiments showed attraction-inhibition relationships for most species. Electroantennagram data are presented forLeptostales ferruminaria andDrepana bilineata. 相似文献
2.
The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v(C?C) = 2108–2128 cm?1 and v(C?C) = 1505–1532 cm?1 were calculated after extrapolation. Similarly sp-C13C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data. 相似文献
3.
A novel fully conjugated polymer containing 1,10‐phenanthroline (DAPcDOD) was first synthesized by the polycondensation of 2,7‐dimethyl‐2,4,6‐octatriene‐1,8‐dial with 5,6‐diamine‐1,10‐phenanthroline. Three polymeric complexes were first prepared by the reaction of DAPcDOD with NiSO4, CoCl2, and FeSO4, respectively. The structures of the polymer and the complexes were characterized by IR, 1H‐NMR, and elemental analysis. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 5 K and as a function of temperature (5–300 K) at a magnetic field strength of 30 kOe. The results show that DAPcDOD–Ni2+ and DAPcDOD–Co2+ were soft ferromagnets, whereas DAPcDOD–Fe2+ exhibited the features of an antiferromagnet. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
4.
Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
5.
离子液体催化C_5馏分中二烯烃的聚合反应 总被引:1,自引:0,他引:1
合成了多种基于1-丁基-3-甲基咪唑阳离子的离子液体,并作为裂解C5馏分中混合二烯烃聚合反应的介质。考察了离子液体种类、反应温度、反应时间和添加Lew is酸对混合二烯烃聚合反应的影响。实验结果表明,以硝酸根为阴离子的离子液体对混合二烯烃的聚合反应具有一定的阻聚作用;以六氟磷酸根为阴离子的离子液体能明显促进混合二烯烃的聚合反应,提高二聚物的含量;添加Lew is酸(质量分数为1%的ZnCl2)的离子液体对混合二烯烃的聚合反应具有更明显的促进作用,其效果仅次于酸性氯铝酸类离子液体,反应温度以30℃以下为宜,温度过高将促使二聚物进一步聚合,形成三聚物乃至多聚物,降低二聚物的含量。 相似文献
6.
共轭高分子三阶非线性光学材料 总被引:3,自引:0,他引:3
概述了n-共轭高分子材料的三阶非线性光学性质,着重讨论了化学结构对其光学非线性的影响,说明了n-共轭聚合物的三阶非线性极化率主要取决于共轭主链的结构,侧链取代基的变化对其非线性影响不大,文中展望了共轭高分子材料在集成光学中的应用前景。 相似文献
7.
Zhiqiang Wu Qiang Guo Yang Liu Huihui Zhou Hua Zheng Xingfeng Lei Lei Gong Yanhui Chen Zhenguo Liu Qiuyu Zhang 《大分子材料与工程》2021,306(11):2100456
In order to meet the requirements of polymer dielectric materials for high thermal stability and excellent dielectric properties in the application of high-temperature film capacitors, a series of polyimide (PI) films are fabricated by introducing a self-synthesized aniline trimer (ACAT) with a conjugated structure in this work. Since the conjugated ACAT in the main chains of PI improves the electron polarization and carrier mobility of the PI molecular chains, the dielectric constant of the ACAT-PI films is greatly enhanced (4.4–7.4). Meanwhile, the dissipation factor does not increase apparently (0.002–0.013). The dielectric properties are stable even when the temperature is up to 200 °C, the thermal degradation temperature is as high as 450 °C, and the mechanical properties are also excellent (70–105 MPa). Among all the films, the PI film with 5 mol% ACAT exhibits the maximal energy density of 3.6 J cm−3 under the field of 426 kV mm−1, the high tensile strength (90 MPa) and the excellent thermal stability (Td5 = 515 °C). The work paves the way to prepare high-temperature polymer dielectric film materials with high energy storage density. 相似文献
8.
Metal-containing conjugated oligomers and polymers are reviewed, focusing on the work carried out by the author and coworkers since 1995. The synthesis of model systems, electropolymerizable monomers and polymer films are discussed, along with the electronic and spectroscopic properties of these systems. The application of phosphino-oligothiophene ligands as an entry to conjugated metallopolymers is described. 相似文献
9.
共轭聚合物/C60复合体系及其在光伏打电池中的应用 总被引:3,自引:0,他引:3
共轭聚合物/C60复合体系在有机太阳能电池中的应用引起了化学工作者的广泛兴趣。本文介绍了共轭聚合物/C60复合体系的光诱导电子转移,以及近年来该体系在光伏打电池中的研究进展。 相似文献
10.
New organodilithium initiators were prepared in a hydrocarbon solvent in the absence of any polar additive. Although these initiators are insoluble when they are synthesized, they may be easily purified and reacted with dienes to give perfectly telechelic polydienes having unimodal distributions and low dispersity. A good agreement between experimental and theoretical molecular weights was observed. The polymer microstructures were similar to those of polymers initiated by butyllithium in the same solvent. Triblock thermoplastic elastomers were also prepared, the characteristics of which are given. The mechanical properties of a S.B.S. sample support also the claim of a good initiating ability and difunctionality of these initiators. 相似文献