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1.
《International Journal of Hydrogen Energy》2019,44(5):2905-2917
In this study, a multi-tubular thermally coupled packed bed reactor in which simultaneous production of ammonia and methyl ethyl ketone (MEK) takes place is simulated. The simulation results are presented in two co-current and counter-current flow modes. Based on this new configuration, the released heat from the ammonia synthesis reaction as an extremely exothermic reaction in the inner tube is employed to supply the required heat for the endothermic 2-butanol dehydrogenation reaction in the outer tube. On the other hand, MEK and hydrogen are produced by the dehydrogenation reaction of 2-butanol in the endothermic side, and the produced hydrogen is used to supply a part of the ammonia synthesis feed in the exothermic side. Thus, 30.72% and 31.88% of the required hydrogen for the ammonia synthesis are provided by the dehydrogenation reaction in the co-current and counter-current configurations, respectively. Also, according to the thermal coupling, the required cooler and furnace for the ammonia synthesis and 2-butanol dehydrogenation conventional plants are eliminated, respectively. As a result, operational costs, energy consumption and furnace emissions are considerably decreased. Finally, a sensitivity analysis and optimization are applied to study the effect of the main process parameters variation on the system performance and obtain the minimum hydrogen make-up flow rate, respectively. 相似文献
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Ivonne Sgura Amos S. Lawless Benedetto Bozzini 《Inverse Problems in Science & Engineering》2019,27(5):618-647
The process of electrodeposition can be described in terms of a reaction-diffusion partial differential equation (PDE) system that models the dynamics of the morphology profile and the chemical composition. Here we fit such a model to the different patterns present in a range of electrodeposited and electrochemically modified alloys using PDE constrained optimization. Experiments with simulated data show how the parameter space of the model can be divided into zones corresponding to the different physical patterns by examining the structure of an appropriate cost function. We then use real data to demonstrate how numerical optimization of the cost function can allow the model to fit the rich variety of patterns arising in experiments. The computational technique developed provides a potential tool for tuning experimental parameters to produce desired patterns. 相似文献
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《Oil and Energy Trends》2019,44(10):29-30
Current data on net electricity production, as well as a breakdown of production by country. Updated on a monthly basis. 相似文献
6.
《Oil and Energy Trends》2019,44(9):27-28
Current data on net electricity production, as well as a breakdown of production by country. Updated on a monthly basis. 相似文献
7.
《Oil and Energy Trends》2019,44(1):26-28
Current data on natural gas production, as well as a breakdown of production by country. Updated on a monthly basis. 相似文献
8.
This study explored adolescents’ opinions about how Internet use supports the achievement of their developmental tasks. Qualitative data were collected in focus groups interviews with 127 Italian Internet users (11–20) attending middle and high schools. Discussions were recorded, transcribed and analyzed using content analysis. Results showed that the Internet plays important functions in identity formation, personal autonomy, and relationships outside the family. It allows teens to develop their own interests, to identify with others and, at the same time, differentiate from others. The Internet is also an arena in which adolescents develop and practice autonomy. The Internet can be a source of conflict with parents, because of parents’ concerns about Internet use. However, the Internet can also be a meeting ground with parents. Finally, participants indicated the Internet is used to form close relationships with peers. Gender and age differences are discussed. Although the study is cross-sectional and relies only on adolescent report, findings illustrate how the conceptual framework of developmental goals may be helpful for understanding how the Internet can affect adolescents’ lives. 相似文献
9.
In the present work, inter-diffusion of nickel and titanium and formation of Ni-Ti intermetallic compounds on Ti-6Al-4V substrate have been studied. Initially, nickel was electrodeposited on the alloy using a modified Watts bath solution at a current density of 2 A dm?2 for 1?h. The coated specimens were then heat treated for different durations at 750, 800 and 850 °C under argon atmosphere. The effects of temperature and time on the characteristics, hardness and wear resistance of intermetallic phases were investigated. The results showed that a multilayer structure was formed after heat treatment, an outer layer of residual nickel, an area of intermetallic layers with different compositions followed by a solid solution of Ni-Ti. It was also observed that an increase in time or temperature at first led to the formation of thicker intermetallic layers; however, after passing a critical point, the intermetallic layers seem to dissolve into the substrate. Furthermore, the wear rates of the diffusion treated samples were four times lower compared to Ti-6Al-4V alloy when sliding against AISI 52100 hardened steel. 相似文献
10.
F. Schröder R. M. Ward A. R. Walpole R. P. Turner M. M. Attallah J.-C. Gebelin 《Materials Science & Technology》2015,31(3):372-384
Linear friction welding of the Ti6Al4V alloy is studied. A new definition of the energy input rate is proposed, based on an integration over time of the in-plane force and velocity; a strong correlation with the upset rate is then found. The effective friction coefficient is estimated to be 0·5±0·1 for varying frequencies and amplitudes, with only a weak dependence on the processing conditions displayed. A model is proposed that accounts for both the conditioning and equilibrium stages of the process, which is shown to be in good agreement with the experimental data. The model is used to study the mechanism by which the flash is formed. A criterion is proposed by which the rippled nature of its morphology can be predicted. 相似文献