Excited-state absorption of meso-tetrasulfonatophenyl porphyrin: Effects of pH and micelles

The influence of the environment on the excited state transitions of meso-tetrakis(p-sulfonatophenyl) porphyrin (TPPS) is reported. TPPS was investigated in protonated and non-protonated forms, and in the presence of the cationic cetyltrimethylammonium bromide (CTAB) micelles. The singlet excited-state absorption spectra were measured by using the white-light continuum Z-scan technique and the triplet–triplet absorption spectra were acquired employing an association of laser flash photolysis and Z-scan techniques. Our results show that the perseveration of the molecular symmetry, upon excitation, depends on the state of multiplicity of the molecules, as well as on the environment and structural characteristics of the porphyrin. Additionally, it was observed that for excited molecules, the ring distortion caused by the protonation of porphyrin ring has great influence on the changes observed for the symmetry and vibronic structure. The results clearly show that the porphyrin investigated is a promising candidate for optical limiting applications for all investigated environments.     

Study on the relationship between the particle size distribution and the effectiveness of the K‐powder fire extinguishing agent

The relationship between the particle size distribution and the extinguishing effectiveness of the new K‐powder fire extinguishing agent has been studied experimentally, to explore the reason of the great extinguishing efficiency exhibited by the new K‐powder fire extinguishing agent on Class B fire (liquid fuel fire). The results of the experiment showed that the extinguishing effectiveness increased along with the decrease of the particle size distribution. In addition, a sharp discontinuity appeared around the limiting size, about 40 μm. The powder with the particle size below 40 μm exhibited highly effective extinguishing with the minimum effective extinguishing concentration C_xr = 23 g·m^?3, while the powder with the particle size above 40 μm exhibited little fire extinguishing efficiency. Compared with other fire extinguishing agents produced by different substances, the new K‐powder fire extinguishing has the bigger limiting size. That means, in the same particle size distribution, the new K‐powder fire extinguishing agent contains more highly effective powder than others contain, and is more effective.     

Transparent niobate glass-ceramics for optical limiting

The construction of nonlinear optical materials featuring asymmetric transmission of light is of great technological importance for various applications, including optical switching and optical power limiting. A significant challenge is the scalable fabrication of material candidates with good photochemical stability, high optical transmittance, and excellent optical limiting performance. Here, we present a nanocrystallization avenue for constructing hybrid optical limiting materials that exhibit ultrafast and robust optical limiting performance. The experimental results show that the controllable relaxation of a niobate glass may lead to the clustering of Nb-O units and contracting of the bandgap. It results in the notable improvement in nonlinear optical properties, including the enhanced saturation irradiance (380 GW/cm²), doubly increased nonlinear coefficient, and decreased limiting threshold (200 GW/cm²). Our results suggest a promising material that exhibits promising applications for protecting eyes and sensitive components from laser-induced damage.     

5Gb/s 0.25μm CMOS限幅放大器

采用TSMC 0.25μm CMOS技术设计实现了高速低功耗光纤通信用限幅放大器.该放大器采用有源电感负载技术和放大器直接耦合技术以提高增益,拓展带宽,降低功耗并保持了良好的噪声性能.电路采用3.3V单电源供电,电路增益可达50dB,输入动态范围小于5mVpp,最高工作速率可达7Gb/s,均方根抖动小于0.03UI.此外核心电路功耗小于40mW,芯片面积仅为0.70mm×0.70mm.可满足2.5,3.125和5Gb/s三个速率级的光纤通信系统的要求.     

Overlapping Schwarz and Spectral Element Methods for Linear Elasticity and Elastic Waves

The classical overlapping Schwarz algorithm is here extended to the spectral element discretization of linear elastic problems, for both homogeneous and heterogeneous compressible materials. The algorithm solves iteratively the resulting preconditioned system of linear equations by the conjugate gradient or GMRES methods. The overlapping Schwarz preconditioned technique is then applied to the numerical approximation of elastic waves with spectral elements methods in space and implicit Newmark time advancing schemes. The results of several numerical experiments, for both elastostatic and elastodynamic problems, show that the convergence rate of the proposed preconditioning algorithm is independent of the number of spectral elements (scalability), is independent of the spectral degree in case of generous overlap, otherwise it depends inversely on the overlap size. Some results on the convergence properties of the spectral element approximation combined with Newmark schemes for elastic waves are also presented.     

The Application of the Theory of the Price Elasticity of Demand to the EMS Management

1　Introduction　ExpressMailService (EMS )wasopenedupbyChinaPostintheearly 80stomeettheneedsofeco nomicdevelopment.It sthemostcompetitiveoneofthepostservices.There recivilaviation ,Chinarail wayandotherprivateexpressdeliverycompaniesdomesticallyandUPS ,TNT ,DHLandTEDEXcompetingwithEMSintheinternationalmarket.OneofthemostpowerfulcompeteweaponofthesecompaniesisthelowerpricethanEMS[1 ] .BecauseofthefiercecompetitionEMSdeclinedfromthemo nopolistindomesticandinternationalmarketoftheear…     

Network topology and the theory of rubber elasticity

The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters.     

Disorder effects on the strain response of model polymer networks

Molecular dynamics simulations are used to investigate polymer networks made by either end-linking or randomly crosslinking a melt of linear precursor chains. The resulting network structures are very different, since end-linking leads to nearly ideal monodisperse networks, while random crosslinking leads to polydisperse networks, characterized by an exponential strand length distribution. Networks with average strand length 20 and 100 were generated. These networks were used to study the effects of disorder in the network connectivity on observables averaged either over the entire network or selected sub-structures. Heterogeneities in the randomly crosslinked networks cause significant differences in the localization of monomers, however, neither the localization of crosslinks nor the microscopic strain response are significantly affected. Compared to end-linked networks, randomly crosslinked networks have a slightly increased tube diameter, and as a result a slightly decreased shear modulus, but otherwise identical stress-strain behavior. For the investigated systems, we conclude that the microscopic strain response, tube diameter, and stress-strain relation are all insensitive to the heterogeneities due to the linking process by which the network were made.     

On a three-dimensional axisymmetric boundary-value problem of nonlinear elastic deformation: Asymptotic solution and exponentially small error

In this paper, we study a three-dimensional axisymmetric boundary-value problem of a slender cylinder composed of a nonlinearly elastic material subjected to an axial force. Starting from the field equations, after a transformation and proper scalings, we identify a small variable and two small parameters, which characterize the present problem. Then, by an approach involving compound series-asymptotic expansions, a nonlinear ODE is derived, which governs the axial strain (the first-term in the series expansion). By imposing the zero radial displacement conditions at two ends, we manage to get the analytical solution of the axial strain, from which all other physical quantities can be deduced and thus the three-dimensional displacement field can be determined. Graphical results are presented, which show that there are two boundary layers near the two ends while the middle part is in a state of almost uniform extension. The asymptotic structure of the analytical solution is derived, which offers clear explanations to the structure of the deformed configuration and shows that the thickness of both boundary layers is of the order of the radius. We also point out the relevance of the present results to the St. Venant’s problem. In particular, we obtain the explicit uniformly-valid exponentially small error term, when the obtained deformed configuration is compared to the configuration of a uniform extension.