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1.
Xue‐Yong Liu Xiao‐Bin Ding Zhao‐Hui Zheng Yu‐Xing Peng Albert S
C Chan C
W Yip Xin‐Ping Long 《Polymer International》2003,52(2):235-240
Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe3O4 magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g?1. © 2003 Society of Chemical Industry 相似文献
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Conducting poly(aniline‐co‐o‐anisidine) (PAS) films with different ratios of aniline units in the polymer chain were prepared by oxidative polymerization of different molar ratios of aniline and o‐anisidine in 1 M HCl using cyclic voltammetry. Due to the much higher reactivity of o‐anisidine, the structure and properties of PASs were found to be dominated by the o‐anisidine units. The polymerization of poly‐o‐anisidine and PASs followed zero‐order kinetics with respect to formation of the polymer (film thickness) and the autocatalytic polymerization of aniline was completely inhibited. In contrast to polyaniline, a decrease in the polymerization temperature was found to increase the amount of copolymer formed and its redox charge. The presence of aniline units in PASs led to a pronounced increase in the molecular weight and conductivity, and a decrease in the solubility in organic solvents. Repetitive charging/discharging cycles showed that PASs resist degradation more than polyaniline. Copyright © 2003 Society of Chemical Industry 相似文献
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高透明耐冲击聚氯乙烯接枝聚合研究 总被引:1,自引:0,他引:1
研究高透明耐冲击聚氯乙烯接枝聚合工艺,讨论了加料顺序、复合分散体系以及采用聚集粒子乳液、并用碱性物质调节其pH值等对接枝聚合物性能的影响,确定了接枝聚合最佳工艺条件。 相似文献
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苯乙烯与1-(2-叔丁基过氧异丙基)-3-异丙烯基苯(D120)能进行自由基共聚合反应,聚合后过氧基团以侧基的形成被保留在共聚物大分子链上,凝胶色谱分析发现,随原料单体中D120比例增加,共聚物的分子量减小,分子量分布变窄,DSC分析发现共聚物中过氧基团的分解温度随D120结构单元含量的增加而下降,但仍高于D120单体过氧基团的分解温度,苯乙烯与D120的竞聚率为:rD120=0.700,rSt=0.714。 相似文献
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N‐p‐Bromophenylmaleimide (BrPMI) does not polymerize in solution by conventional free radical mechanism. However, it readily polymerized in bulk when mixed with a free radical initiator and heated in a microwave oven for 7–8 min. Copolymerization of ethyl methacrylate or butyl methacrylate with BrPMI was conducted in dioxane. The copolymers were characterized by IR and 1H NMR spectroscopy and gel permeation chromatography. The monomer reactivity ratios were calculated by a non‐linear least‐square analysis. Thermal analysis indicated a great improvement in thermal stability of the copolymers compared with the methacrylate homopolymers. BrPMI was also polymerized in bulk in the DSC pan, which allowed the calculation of the activation energy of its polymerization. Copyright © 2003 Society of Chemical Industry 相似文献
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Anionic copolymerizations of styrene (M1) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M2) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;n = 16.1 × 103 g/mol (M?w/M?n = 1.04) and 38.2 × 103g/mol (M?w/M?n = 1.05), and 24 and 38 moles of M2 per macromolecule, respectively, were characterized by size exclusion chromatography, 1H NMR spectroscopy and DSC. The monomer reactivity ratio, r1 = 5.6, was obtained from the copolymer composition at complete consumption of M1, assuming that the rate constant k22 =0,i.e. r2 =0. The polymers exhibited Tg values of 128 and 119°C, respectively, which correspond to an estimated Tg = 217°C for the hypothetical homopolymer of M2. 相似文献
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