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1.
我国的丙醛系列产品急待开发 总被引:1,自引:0,他引:1
丙醛系列产品属精细化工产品,其中丙醛、丙醇和丙酸在我国的生产基本是空白。介绍了世界丙醛系列产品的生产与应用。建议我国开发丙醛系列产品生产技术,组建万吨级生产装置。 相似文献
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《分离科学与技术》2012,47(16):3876-3887
Abstract In this work, polyethersulfone (PES) asymmetric nanofiltration (NF) membranes were prepared by immersion precipitation phase inversion process. The casting solution contained N-methyl-2-pyrrolidone (NMP) as solvent, 1-propanol and 2-propanol as nonsolvent additives, and polyvinylpyrrolidone (PVP) as pore former additive. Water was used as a coagulant. The effects of the PVP content in the casting solution and the exposed time on the performances of the NF membranes were investigated. It was found that with the increase of PVP content, the pure water flux (PWF) increased to the largest value and then decreased. The rejection to PEG 1000 always decreased. The largest value (1281.40 kg · m?2 · h?1 · MPa?1) of PWF appeared when the content of 1-propanol was 9 wt.%. However, when 2-propanol was added in the casting solution, the largest value of PWF was only 678.37 kg · m?2 · h?1 · MPa?1 (the content of 2-propanol was 7 wt.% and other preparing conditions were unchanged). The results meant that both PWF and rejection of the membranes with 1-propanol as additive were higher than that of 2-propanol as additive. The possible reason was discussed from the viewpoint of the difference of solubility of propanols to PES and PVP. 相似文献
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The chemical capture of CO2 by either aqueous Na2CO3 and K2CO3 or nonaqueous solutions of the amines 2‐amino‐2‐methyl‐1‐propanol (AMP) or piperazine (PZ) is described. The captured CO2 is stored as solid NaHCO3, KHCO3, and AMP or PZ carbamates. Solid NaHCO3 and KHCO3 are decomposed at 200 °C and 250 °C, respectively, to regenerate the carbonates for their reuse. In the experiments with AMP or PZ, the solid carbamates are decomposed at 80 °C–110 °C to regenerate the free amines. The absence of water in the desorption‐regeneration step is intriguing and could have the potential of reducing one of the major disadvantages of aqueous absorbents, namely the energy cost of the regeneration step and amine degradation, yet preserving the efficiency of the absorption in the liquid phase. 相似文献
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Viscosity of (water + alcohol) mixtures under high pressure 总被引:1,自引:0,他引:1
Y. Tanaka Y. Matsuda H. Fujiwara H. Kubota T. Makita 《International Journal of Thermophysics》1987,8(2):147-163
New experimental viscosity data are presented for aqueous solutions of methanol, ethanol, 1-propanol, 2-propanol, and 2-methyl-2-propanol (t-butyl alcohol) in the temperature range from 283 to 348 K and pressures up to 120 MPa. The viscosity measurements were performed using a falling-cylinder viscometer on a relative basis with an uncertainty of less than 2%. The viscosity of pure alcohols and aqueous solutions is found to increase almost linearly with increasing pressure, whereas that of water decreases slightly with pressure at temperatures below 298 K. As for the composition dependence of the viscosity, a distinct maximum appears near 0.3–0.4 mole fraction of alcohol on all isobars at each temperature. The viscosity maximum shifts gradually to a higher alcohol concentration with increasing temperature and pressure. The isobars of aqueous 2-propanol and 2-methyl-2-propanol solutions have another shallow minimum near 0.9 mole fraction of alcohol below 323 K. The experimental results were analized empirically by a Tait-type equation and a free-volume theory. It was found that the isothermal viscosity data were satisfactorily correlated by these equations as functions of pressure and composition or of density and composition. 相似文献
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Gity Mir Mohamad Sadeghi Jalil Morshedian Mehdi Barikani 《Polymer International》2003,52(7):1083-1087
Polybutadiene‐ol was synthesized by solution radical polymerization of 1,3‐butadiene in the presence of hydrogen peroxide as initiator and 2‐propanol as solvent. The ratio of initiator to monomer molar concentration, [I0]/[M0], was varied while temperature, reaction time and the type and amount of solvent were kept constant. The effects on the Mn; Mw; Mv; PDI, OH‐number and functionality of the synthesized polyols were studied. By taking several samples during a polymerization batch and analyzing them, the time of reaction was chosen as 100 min, after which the PDI changed dramatically. Mn decreased exponentially with increasing [I0]/[M0] according to the relationship Mn = 565.55 ([I0]/[M0])?0.7553. The decrease observed in Mw gradually levelled off with increasing [I0]/[M0] and molecular weight distribution broadened at larger values of [I0]/[M0]. The OH‐number increases with [I0]/[M0]. In addition to the number‐average molecular weight, functionality is dependent on the number of hydroxyl‐terminated chain radicals in the reaction medium. Copyright © 2003 Society of Chemical Industry 相似文献
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Enantioselective membrane was prepared using ethyl cellulose (EC) as membrane material. The flux and permselective properties of membrane using aqueous solution of (R,S)‐2‐phenyl‐1‐propanol as feed solution was studied. The employed membrane process was a pressure driven process. All kinds of important conditions including preparation and operation of membranes were investigated in this experimentation. When the membrane was prepared with 18 wt % EC, 20 wt % N,N‐dimethylformamide in casting solution, 13 min evaporation time and 0°C temperature of water bath for the gelation of the membrane, and the operating pressure and feed solution of (R,S)‐2‐phenyl‐1‐propanol were 0.2 MPa and 1.5 mg/mL, respectively, over 90% of enantiomeric excess (e.e.) and 44.2 (mg/m2 h) of flux were obtained. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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采用停流光谱仪研究了异丙醇在T=298K和pH=3~11范围内O3 / H2O2复合氧化的反应动力学.结果表明异丙醇的O3 / H2O2复合氧化反应动力学随反应体系的pH值不同而不同.在酸性和中性条件下,反应相对于O3浓度、异丙醇浓度都为1级;在碱性条件下,异丙醇较容易被O3/H2O2复合氧化降解,总反应级数为2级,相对于O3浓度、异丙醇浓度和H2O2浓度分别为1级、0级和1级,可见异丙醇的降解速率与它的浓度无关.在T=298K,当pH值从9增大到11, 反应速率常数从3486.1(mol·L-1)-1·s-1增大到38239.2(mol·L-1)-1·s-1. 表明在酸性条件下,异丙醇的O3/H2O2复合氧化是O3分子直接攻击异丙醇的反应占主导;在碱性条件下,自由基型反应占主导. 相似文献
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以甲醇和环氧丙烷为反应物,采用均相连续反应精馏法合成了2-羟丙基甲醚。对三乙胺、氢氧化钠、氢氧化钾、碳酸钠和碳酸钾五种催化剂的催化活性和选择性进行了研究。考察了以三乙胺为催化剂时进料摩尔比和环氧丙烷进料速率对环氧丙烷转化率、2-羟丙基甲醚选择性及收率的影响,并对反应精馏塔的温度分布进行了讨论 相似文献