梯恩梯-吉纳、地恩梯-太安装药体系自旋爆轰特性的研究

本文研究了梯恩梯-吉纳(TNT-DINA)和地恩梯-太安(DNT-PETN)体系的自旋爆轰现象,爆轰波是以低频脉冲方式传播.这些体系具有的爆速、爆热分别为DJ=7.3～7.4km/s和Qv=(5.40±0.01)MJ/kg.不同组成的爆速和爆压PJ通过SW程序计算.用扩散区的爆压P3和爆温T3来评估爆轰波的衰减和重新点火.敏化剂含量相同,梯恩梯-黑索金(TNT-RDX)体系的爆压PJ大于TNT-DINA的爆压,TNT-RDX体系的温度T3比TNT-DINA高60～100K.计算值与实验结果吻合较好.     

砖烟囱集团装药定向爆破拆除

对一座 40 m 高的砖烟囱,采用TNT集团装药实施定向倒塌拆除爆破.介绍了该烟囱拆除爆破工艺技术,爆破参数和施工方法.     

GPIB芯片TNT4882在多路程控电源中的应用

介绍一种GPIB总线接口芯片TNT4882及其在多路程控电源中的应用,包括TNT4882的引脚排列、内部结构、功能和通信方式、与微处理器的接口及与上位机的通信;同时给出在实际应用中的总体框图和各主要功能模块的软件流程及程控电源与上位机通信程序.     

TNT红水治理研究新动态

综述了国内外治理TNT红水的研究现状及发展趋势,阐明了生化治理TNT红水的难点,给出了采用经红水驯化后的白腐菌生化治理TNT红水的技术措施、脱色方法及分析方法,指出白腐菌与木质素载体能较有效地降解TNT红水,该方法具有广阔的应用前景,同时对白腐菌处理技术的发展和应用提出建议.     

TNT荧光偏振免疫检测方法研究

研究旨在利用新制备的多克隆抗体首次建立2,4,6-三硝基甲苯（TNT）的荧光偏振免疫分析方法．通过设计合成新的TNT半抗原TNT—BSA,偶联载体蛋白后免疫新西兰大白兔,制备亲和力高、特异性强的多克隆抗体．结合新设计合成的荧光示踪物TNT—PDAM建立了TNT的荧光偏振免疫分析方法．试验结果表明,TNT荧光偏振免疫分析方法检测限为7．5μg／L,检测范围为13．8~129．7μg／L,IC50为39．3μg／L．     

TNT 粉尘爆炸压力发展过程研究

在２０Ｌ球形粉尘爆炸装置中，对ＴＮＴ粉尘爆炸压力发展过程进行了研究，主要讨论了浓度、粒度对其最大爆炸压力（ｐｍ）及最大压力上升速率（（ｄｐ／ｄｔ）ｍ）的影响；同时，理论建模对不同粒度、浓度、湍流度等情况下压力发展进行了研究，发现与实验基本吻合．     

Desorption characteristics of uncoated silicon microcantilever surfaces for explosive and common nonexplosive vapors

We measured the desorption of explosive trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), and hexahydro-1,3,5-triazine (RDX) vapors from piezoresistive silicon microcantilevers under ambient air. Depending on the amount of vapor loaded on the cantilever, TNT desorption took a few minutes to tens of minutes (for nanogram quantities). On the other hand, no significant loss of PETN or RDX was observed after many hours. We also measured desorption of common “nonexplosive” compounds (water, acetone, and ethyl alcohol) and observed that desorption was too fast to be measured. There is a good correlation between the desorption time and the melting point (or the vapor pressure) of a particular substance. In principle, this method can be used to measure desorption rates of various substances from cantilever surfaces.     

Full-scale experimental investigation on the shock-wave characteristics of high-pressure natural gas pipeline physical explosions

In this study, a series of full-scale high-pressure natural gas pipeline physical explosion experiments were performed, in which the overpressure of the shock waves was measured and analyzed. The concept of “physical explosion linear energy (PEXLE)” was proposed and a “PEXLE model” was established to evaluate shock waves in a cylindrical pipeline with high length–diameter ratio. Equations were fitted to describe the characteristics of peak overpressure, positive pressure duration and specific impulse. Results showed that peak overpressure of shock waves is not influenced by the length of pipeline. With the increase of the propagation distance, specific impulse first increases and then decreases. This indicates that the position of the maximum value of overpressure does not correspond with that of the specific impulse.     

Photocatalytic degradation of RhB and TNT and photocatalytic water splitting with CZTS microparticles

Cu₂ZnSnS₄ (CZTS) is a main candidate material for solar energy conversion through both photovoltaics and photocatalysis based on environmentally friendly elements and with a direct band gap of 1.5 eV. We report the synthesis of quasi Cu₂ZnSnS₄ microparticles with unprecedented narrow size distributions. The structural, morphological and core level analysis has been carried out by XRD, SEM and XPS techniques. These microparticles have shown excellent photocatalytic activity toward degradation of Rhodamine B dye (RhB) and TNT under visible light. The extent of mineralization has been analyzed by COD and TOC values. Photocatalytic water splitting for H₂ generation has also been reported.     

超重力-臭氧法处理TNT红水的试验研究

为提高O3氧化处理TNT红水的功效和利用率,节约水处理成本,将具有高效传质特性的旋转填料床用于研究O3氧化处理TNT红水的特性规律。考察了超重力因子卢、红水初始pH值和气液比等因素对红水COD去除率的影响。结果表明,β对COD去除率有萌显的影响,随着pH值的增大卢对COD去除率的影响增大,卢大于100后对COD去除率的影响不明显;COD去除率随气液比的增加呈先减小后增大的趋势,COD去除率随pH值的增大而升高,当pH值超过11时,COD去除率有所下降。通过试验证明了该方法在技术上是可行的,具有良好的应用前景。