排序方式: 共有41条查询结果,搜索用时 13 毫秒
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OU Yang-jun LI Hong-jian DAI Xiao-yu 《半导体光子学与技术》2006,12(4):245-249,261
Based on the charge injection and recombination processes and the triplet-triplet annihilation process, a model to calculate the electro.luminescent(EL) efficiency is presented. The influences of the applied electric field on the injection efficiency, recombination efficiency and electroluminescent efficiency are discussed. It is found that: (1) The injection efficiency is increasing while the recombination efficiency is decreasing with the applied electric field increasing. (2) The EL efficiency is enhanced at low electric field slowly but is decreasing at high electric field with the increase of applied voltage. (3) The EL efficiency is decreasing with the increase of the host-guest molecular distance (R). So, it is concluded that the EL efficiency in single-layer organic electrophosphorescent devices is dominated by injection efficiency at lower electric field and recombination efficiency at higher electric field. 相似文献
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The preparation and characterization of a new cyclometalated iridium complex with 2-(1-naphthalene) pyridine ligand were reported. An electrophosphorescent device was fabricated by using this new iridium complex as guest and poly-(cyano-paraphenylene) as host. Red electrophosphorescence was observed with an emission peak at approximately 600 nm. An external quantum efficiency of 1.3% was achieved in this electrophosphorescent polymer light-emitting devices. 相似文献
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PVK-based phosphorescent FIrpic-doped devices have been fabricated and the effect of carrier transporting materials on the device performance has been investigated. We have fabricated the single-layer and double-layer devices to investigate the role of electron- and hole-transporting materials both when they are mixed in the single- and separated from the emissive layer. We have studied NPB as a hole-transporting material, OXD-7 and PBD as electron-transporting materials. Even though PBD had been well known to be unsuitable as an electron-transporting material for FIrpic-doped PVK devices, it was found in this study that the separate utilization of PBD from PVK:FIrpic layer instead of mixing it with the emissive layer could enhance the device performance significantly. Nevertheless, the OXD-7 was found not only superior to PBD as the electron-transporting material for FIrpic-doped PVK devices but also suitable as an electron-transporting material for the single-layer devices. 相似文献
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Keqi He Xiangdong Wang Junting Yu Haigang Jiang Guangshan Xie Hua Tan Yu Liu Dongge Ma Yafei Wang Weiguo Zhu 《Organic Electronics》2014,15(11):2942-2949
To explore the influence of push–pull chromophores on properties of emitter in organic light-emitting devices (OLEDs), an acceptor–donor–acceptor (A–D–A)-based dinuclear iridium (III) complex of (dfppy)4Ir2(dipic-FL) was synthesized via Suzuki coupling reaction, in which dfppy is 2-(2,4-difluorophenyl)pyridine and dipic-FL is 2,7-di(5-pyridyl-2-carboxyl)-9,9-dioctyl-9H-fluorene. An intense emission peak at about 480 nm resulting from the (dfppy)2Ir(pic) chromophore and a weak long-wavelength emission band at 580–660 nm attributed to intramolecular charge transfer transition were exhibited for (dfppy)4Ir2(dipic-FL) in dichloromethane solution. But a remarkably hypsochromic photoluminescence profile with an intense characteristical emission peak at 422 nm was observed, which is attributed to the intraligand (IL) π–π∗ excited states in its thin film. White emission with a maximum luminance of 1040 cd/m2 and current efficiency of 1.2 cd/A was obtained in its single-emissive-layer (SEL) OLEDs with a configuration of ITO/PEDOT:PSS/(dfppy)4Ir2(dipic-FL) (10 wt%):TCTA/TPBi/LiF/Al. To our knowledge, this is one of the best examples in term of dinuclear iridium complex as single dopant in the high-performance white-emitting SEL-OLEDs. 相似文献
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R. N. Bera N. Cumpstey P. L. Burn I. D. W. Samuel 《Advanced functional materials》2007,17(7):1149-1152
Intermolecular interactions play a crucial role in the performance of organic light‐emitting diodes (OLEDs). Here we report the photophysical and electroluminescence properties of a fac‐tris(2‐phenylpyridyl)iridium(III ) cored dendrimer in which highly branched biphenyl dendrons are used to control the intermolecular interactions. The presence of fluorene surface groups improves the solubility and enhances the efficiency of photoluminescence, especially in the solid state. The emission peak of the dendrimer is around 530 nm with a PL quantum yield of 76 % in solution and 25 % in a film. The photophysical properties of this dendrimer are compared with a similar dendrimer with the same structure but without the fluorene surface groups. Dendrimer LEDs (DLEDs) are prepared using each dendrimer as a phosphorescent emitter blended in a 4,4′‐bis(N‐carbazolyl)biphenyl host. Device performance is improved significantly by the incorporation of an electron‐transporting layer of 1,3,5‐tris(2‐N‐phenylbenzimidazolyl)benzene. A peak external quantum efficiency of 10 % (38 Cd A–1) for the dendrimer without surface groups and 13 % (49.8 Cd A–1) for the dendrimer with fluorene surface groups is achieved in the bilayer LEDs. 相似文献