大跨度无粘结预应力梁楼盖结构施工技术

分析、介绍石家庄第二长途电信枢纽工程大跨度无粘结预应力梁楼盖结构的施工方法、张拉工艺及质量控制。     

Functionalization of Polymer Surfaces Using Excimer VUV Systems and Silent Discharges. Application to Electroless Metallization

New approaches for electroless plating of nonconductive polymers or polymer-based materials are described. In this work, polyimide substrates were surface-functionalized (i) in nitrogenated (ammonia at reduced pressure) and oxygenated (air at atmospheric pressure) atmospheres under assistance of vacuum-ultraviolet (VUV) irradiation (use of a xenon silent discharge excimer source) or (ii) directly in air at atmospheric pressure using a dielectric-barrier discharge (DBD) device. After functionalization, the substrates were “activated” by dipping in a dilute acidic PdCl₂ solution or by spin-coating of a thin metal-organic film (from a solution of palladium acetate (PdAc) in chloroform). The catalytic activity of the so-deposited palladium species toward the electroless deposition of nickel was studied before and after a VUV post-irradiation (in air at atmospheric or reduced pressure) with a view to understanding better the role of the reducer (sodium hypophosphite) within the electroless bath.

This work confirms the specific interest of grafting nitrogenated functionalities onto polymer surfaces for attaching covalently the palladium-based catalyst (in particular in the case of the PdCl₂ route), forming thus strong Pd - N - C bonds at the metal/polymer interface. This results from the strong chemical affinity of palladium toward nitrogen. On the other hand, when oxygenated functionalities are surface-grafted, the conventional two-step procedure using SnCl₂ and PdCl₂ solutions can be proposed due to the strong chemical affinity of tin toward oxygen. The Ni deposits obtained under these different conditions pass the standard Scotch^®-tape test and, therefore, exhibit a good practical adhesion. For this same purpose, it is interesting to note that the DBD treatment operating in air at atmospheric pressure causes an increase of the surface roughness and, therefore, an improvement in adhesion of metallic films when their initiation is catalyzed through the PdAc route. In addition, this work demonstrates that extensive research still has to be performed to understand and improve the Ni/polymer adhesion when the PdAc route associated with a VUV irradiation is considered.     

New formulation and plots for error probability in the pulse position modulation (PPM) photon counting satellite-to-earth channel

In digital satellite-to-earth transmission the entry of substantial undesired solar radiation into the receiver antenna is sometimes unavoidable. When the signal transmission takes the form of incoherent optical pulse position modulation (PPM) the parameters of signal and consequent intense noise can fall outside the range of routinely available classical numerical results on symbol error probability. This paper presents an alternative system for parametrization of signal and noise in the classical PPM channel, i.e. that characterized by Poisson photon arrival statistics for signal itself, the noise itself, and the signal plus noise. The resulting formulation for error probability, the scheme for probability calculation, and the simple, compact plots of error probability versus newly conceived parameters cover the entire range of signal and noise intensities, from weakest to strongest. Of course, when properly interpreted the new results agree entirely with classically available numerical results within the parametric range of the former.     

On Detecting White Space Spectra for Spectral Scavenging in Cognitive Radios

A primary task performed by a Cognitive Radio is that of spectral estimation to locate the segments in a spectral span that contain white zones, spans that contains noise only, or grey zones, spans that contain signals with significant intervals of off-time. The identification of spectral regions containing noise only spectra, as opposed to regions containing signals with low spectral density, is surprising difficult. The estimator must deal with questions of transform length, window selection, window length, window overlap, and ensemble averaging options. This paper describes the impact of each selection option and presents the architecture of the optimal spectral estimator.

用点扩展函数确定卫星反射后的脉冲强度

卫星激光测距系统是一个非相干成象光学系统。卫星形状效应是由于卫得上不同位置的反射器对光子反射的时间不同而引起的脉冲强度重新分布的现象。非相干成象系统在等晕区内是空间不变性的光强线性系统。成象光学系统中象强度等于输入物强度与光瞳点扩展函数的卷积。用卫星的点扩展函数描述卫星形状效应,能非常简便地计算出被卫星反射后的脉冲强度分布。讨论了激光测距卫星的点扩展函数的求解方法和表达形式,并分别推导和计算了Lageos卫星和自行设计卫星的点扩展函数以及点扩展函数作用后的脉冲强度分布。     

感应式LED观片灯的研究

分析了目前工业射线底片观片灯的现状,给出一种新型观片灯的设计方案.采用高亮度发光二极管(LED)作光源观片灯具有亮度高、寿命长、节能和环保的特点.可用于射线检测底片的观察和评定.     

Investigation of defects in a mesophase pitch-based graphite at the atomic scale北大核心CSCD

A C/C composite as a thermal conducting material was prepared by the impregnation of unidirectional mesophase pitch based carbon fibers with mesophase pitch and graphitization at 3 000 degrees C. It was thinned to around 10 nm in the direction parallel to the fiber axis by cutting, grinding and ion beam bombardment. Results indicate that mesophase pitch is transformed into hexagonal graphite (HG). However, there is rhombohedral graphite (RG) tens of nanometer thick mingled with the HG. Defects include the glide and rotation structures and grain boundaries.     

udkm1Dsim—A simulation toolkit for 1D ultrafast dynamics in condensed matter

The udkm1Dsim  toolbox is a collection of matlab (MathWorks Inc.) classes and routines to simulate the structural dynamics and the according X-ray diffraction response in one-dimensional crystalline sample structures upon an arbitrary time-dependent external stimulus, e.g. an ultrashort laser pulse. The toolbox provides the capabilities to define arbitrary layered structures on the atomic level including a rich database of corresponding element-specific physical properties. The excitation of ultrafast dynamics is represented by an N$N$-temperature model which is commonly applied for ultrafast optical excitations. Structural dynamics due to thermal stress are calculated by a linear-chain model of masses and springs. The resulting X-ray diffraction response is computed by dynamical X-ray theory. The udkm1Dsim  toolbox is highly modular and allows for introducing user-defined results at any step in the simulation procedure.     

Functionalization of Polymer Surfaces Using Excimer VUV Systems and Silent Discharges. Application to Electroless Metallization

New approaches for electroless plating of nonconductive polymers or polymer-based materials are described. In this work, polyimide substrates were surface-functionalized (i) in nitrogenated (ammonia at reduced pressure) and oxygenated (air at atmospheric pressure) atmospheres under assistance of vacuum-ultraviolet (VUV) irradiation (use of a xenon silent discharge excimer source) or (ii) directly in air at atmospheric pressure using a dielectric-barrier discharge (DBD) device. After functionalization, the substrates were “activated” by dipping in a dilute acidic PdCl₂ solution or by spin-coating of a thin metal-organic film (from a solution of palladium acetate (PdAc) in chloroform). The catalytic activity of the so-deposited palladium species toward the electroless deposition of nickel was studied before and after a VUV post-irradiation (in air at atmospheric or reduced pressure) with a view to understanding better the role of the reducer (sodium hypophosphite) within the electroless bath.

This work confirms the specific interest of grafting nitrogenated functionalities onto polymer surfaces for attaching covalently the palladium-based catalyst (in particular in the case of the PdCl₂ route), forming thus strong Pd - N - C bonds at the metal/polymer interface. This results from the strong chemical affinity of palladium toward nitrogen. On the other hand, when oxygenated functionalities are surface-grafted, the conventional two-step procedure using SnCl₂ and PdCl₂ solutions can be proposed due to the strong chemical affinity of tin toward oxygen. The Ni deposits obtained under these different conditions pass the standard Scotch^®-tape test and, therefore, exhibit a good practical adhesion. For this same purpose, it is interesting to note that the DBD treatment operating in air at atmospheric pressure causes an increase of the surface roughness and, therefore, an improvement in adhesion of metallic films when their initiation is catalyzed through the PdAc route. In addition, this work demonstrates that extensive research still has to be performed to understand and improve the Ni/polymer adhesion when the PdAc route associated with a VUV irradiation is considered.