全文获取类型
收费全文 | 7220篇 |
免费 | 1328篇 |
国内免费 | 178篇 |
专业分类
电工技术 | 1599篇 |
综合类 | 195篇 |
化学工业 | 1499篇 |
金属工艺 | 325篇 |
机械仪表 | 32篇 |
建筑科学 | 11篇 |
矿业工程 | 88篇 |
能源动力 | 1083篇 |
轻工业 | 14篇 |
水利工程 | 1篇 |
石油天然气 | 7篇 |
武器工业 | 12篇 |
无线电 | 1422篇 |
一般工业技术 | 2229篇 |
冶金工业 | 147篇 |
原子能技术 | 3篇 |
自动化技术 | 59篇 |
出版年
2024年 | 58篇 |
2023年 | 767篇 |
2022年 | 228篇 |
2021年 | 509篇 |
2020年 | 638篇 |
2019年 | 522篇 |
2018年 | 456篇 |
2017年 | 470篇 |
2016年 | 419篇 |
2015年 | 337篇 |
2014年 | 358篇 |
2013年 | 276篇 |
2012年 | 251篇 |
2011年 | 571篇 |
2010年 | 416篇 |
2009年 | 325篇 |
2008年 | 344篇 |
2007年 | 433篇 |
2006年 | 285篇 |
2005年 | 235篇 |
2004年 | 214篇 |
2003年 | 158篇 |
2002年 | 135篇 |
2001年 | 63篇 |
2000年 | 45篇 |
1999年 | 66篇 |
1998年 | 33篇 |
1997年 | 32篇 |
1996年 | 32篇 |
1995年 | 18篇 |
1994年 | 10篇 |
1992年 | 4篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1954年 | 1篇 |
1951年 | 7篇 |
排序方式: 共有8726条查询结果,搜索用时 0 毫秒
1.
由于干态聚合物电解质目前还不能满足聚合物锂离子电池的应用要求,人们致力于开发含液体增塑剂的聚合物电解质,包括凝胶型和微孔型两类体系。本文综述了含液聚合物电解质的最新进展,重点论述了各种新体系和新方法。 相似文献
2.
A quantum chemical study of the binding of Li+ cation to polyalkyloxides has been carried out. The lithium cation interaction with three polyalkyloxides (polyethylene oxide (PEO), polytrimethylene oxide (PTMO), and polypropylene oxide (PPO)) has been investigated using ab initio molecular orbital theory at the HF/6-31G* level with molecular models for the polymers. Coordination by one to six oxygens was considered. In addition, higher level calculations were carried out using G3(MP2) theory for coordination of Li+ by one oxygen. For coordination of lithium by one oxygen, the binding energy ordering is PTMO>PPO>PEO, with PTMO having the largest lithium cation affinity. The same ordering is found for larger coordination numbers with the exception of coordination by six oxygens, where the ordering changes due to the steric interactions. 相似文献
3.
4.
5.
超动型长寿命铅蓄电池池的几点建议 总被引:1,自引:1,他引:0
报导了国内外起动用长寿命铅酸蓄电池的概况,根据笔多年积累的经验并针对这类电池的应用特点,具体介绍了起动型铅酸蓄电池在原辅材料,零部件,生产设备和制造工艺等方面如何采取有效措施以提高这类电池的使用寿命。 相似文献
6.
Ying Bai Yanfeng Yin Na Liu Bingkun Guo Hongjun Shi Jianyong Liu Zhaoxiang Wang Liquan Chen 《Journal of power sources》2007
As the continuance of our series study on LiCoO2 surface modification, the complicated traditional surface coating method is replaced with simple addition of amorphous YPO4 and Al2O3 in commercial LiCoO2 or in commercial electrolyte based on our understanding to the improvement mechanism of surface modification. Comprehensive studies by X-ray photoelectron spectroscopy (XPS), gas chromatography and mass spectroscopy (GC–MS), inductively coupled plasma (ICP) and Fourier transformed infrared (FTIR) indicate that the products of spontaneous reaction between the additive and the LiPF6 based electrolyte are responsible for the performance improvements. 相似文献
7.
Co^3+—modified Surface of LiMn2O4 Spinel for its Improvementof Electrochemical Properties 总被引:3,自引:0,他引:3
ZishanZHENG ZilongTANG ZhongtaiZHANG JunbiaoLU WanciSHEN 《材料科学技术学报》2003,19(4):359-362
Cobalt was used to modify the surface of spinel LiMn2O4 by a solution technique to produce Co^3 -modified surface material (COMSM). Cobalt was only doped into the surface of LiMn2O4 spinel. XPS(X-ray photoelectron spectroscopy) analysis confirms the valence state of Co^3 . COMSM has stable spinel structure and can prevent active materials from the corrosion of electrolyte. The ICP(inductively coupled plasma) determination of the spinel dissolution in electrolyte showed the content of Mn dissolved from COMSM was smaller than that from the pure spinel. AC impedance patterns show that the charge-transfer resistance (Rct) for COMSM is smaller than that for pure spinel. The particles of COMSM are bigger in size than those of pure spinel according to the micrographs of SEM(scanning electron microscopy). The determinations of the electrochemical characterization show that COMSM has both good cycling performance and high initial capacity of 124.1 mA/h at an average capacity loss of 0.19 mAh/g per cycle. 相似文献
8.
电解铜箔产业发展趋势 总被引:4,自引:0,他引:4
随着技术的进步,电解铜箔在厚度上迅速向薄、超薄方向发展,THE、RCC、CAC等特殊性能铜箔需求比例快速 增加,以锂离子电池为代表的新应用领域正在形成。 相似文献
9.
B. A. Trofimov G. F. Myachina I. V. Rodionova A. G. Mal'kina I. A. Dorofeev T. I. Vakul'skaya L. M. Sinegovskaya T. A. Skotheim 《应用聚合物科学杂志》2008,107(2):784-787
Ethynedithiol‐based polyeneoligosulfides have been synthesized in 96% yield by the reaction of sodium acetylides (HC?CNa, NaC?CSNa) and elemental sulfur through the Na? Csp bond in liquid ammonia with the following spontaneous polymerization of ethynedithiols (HSC?CSH) formed by the hydrolysis. The polyeneoligosulfides synthesized are brown powders (up to 77% sulfur content, mp 128–184°C), partially soluble in organic solvents. They are high‐resistance semiconductors (10?13 to 10?14 S cm?1), possess paramagnetic (1017 to 1018 spin g?1) and redox properties. The oligosulfides obtained, being redox systems capable of reversible redox processes, provide high values of discharge capacity (345–720 mA h g?1) of rechargeable lithium‐sulfur batteries. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
10.
A novel current source inverter system interconnected to the single‐phase grid is proposed. It has the same construction as the conventional three‐phase current source inverter that is interconnected to the single‐phase three‐wire distribution system. Though the proposed circuit has no output transformer, it can be equivalently performed as the single‐phase double cascade inverter by diverting the pole transformer in the utility system. By controlling the appropriate scheme, the output currents can be obtained as the five‐level waveforms and their distortions can be decreased sufficiently. It is applied to the interactive electric energy storage system with batteries and the basic discharging characteristics are discussed experimentally. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 50–61, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10380 相似文献