Corrosion behaviors of Cr2AlC/α-Al2O3 composites in 3.5 wt. % NaCl aqueous solution

Cr₂AlC and its composites containing α-Al₂O₃ (6.1 and 15.2 wt %) were prepared by hot pressing and their corrosion behaviors in air-saturated 3.5 wt % NaCl aqueous solution were investigated by electrochemical testing methods. It was revealed that the secondary phase of Al₂O₃ particles mainly distributed along grain boundaries of Cr₂AlC matrix. The potentiodynamic polarization measurements showed that the corrosion current densities of these Cr₂AlC composites were lower than that of the pure Cr₂AlC. The Aluminum in Cr₂AlC was prone to be attacked more easily. When immersed at open circuit potential (OCP), Al readily slipped out from Cr₂AlC matrix into NaCl solution in the form of dissoluble species. But in the case of polarization, regardless of potentiostatic polarization or potentiodynamic polarization, more de-intercalated Al, reacted with the electrolyte to form corrosion products of Al₂O₃ and/or AlOOH and deposited on the sample surface. For Cr₂AlC/α-Al₂O₃ composites, the presence of Al₂O₃ weakened the corrosion along grain boundaries by partly blocking the permeation of electrolyte and inhibiting the anodic dissolution process.     

Molten salt synthesis of MAX phases in the Ti-Al-C system

The molten salt method was used to synthesise the MAX phase compounds Ti₂AlC and Ti₃AlC₂ from elemental powders. Between 900–1000?°C, Ti₂AlC was formed alongside ancillary phases TiC and TiAl, which decreased in abundance with increasing synthesis temperature. Changing the stoichiometry and increasing the synthesis temperature to 1300?°C resulted in formation of Ti₃AlC₂ alongside Ti₂AlC and TiC. The type of salt flux used had little effect on the product formation. The reaction pathway for Ti₂AlC was determined to be the initial formation of TiC_1-x templating on the graphite and titanium aluminides.     

双膦胺镍-甲基铝氧烷体系催化苯乙烯聚合

研究了具有新型结构的双膦胺镍配合物N,N-双(二苯膦基)-对甲氧基苯胺二氯化镍-甲基铝氧烷(PNP-N i-MAO)催化体系对苯乙烯聚合的催化性能,考察了聚合温度、n(A l)∶n(PNP-N i)、PNP-N i的浓度和苯乙烯的浓度对催化活性、苯乙烯转化率、聚苯乙烯相对分子质量及其分布的影响,并用核磁共振和凝胶色谱对聚苯乙烯的结构进行了表征。实验结果表明,在聚合温度25℃、聚合时间1h、n(A l)∶n(PNP-N i)=300、c(苯乙烯)=2.3m ol/L、c(PNP-N i)=0.4mm ol/L、甲苯为溶剂的适宜条件下,苯乙烯的转化率可达95%以上,催化活性达到5×105g/(m ol.h)左右。核磁共振和凝胶色谱表征结果显示,所得聚苯乙烯为无规结构,重均相对分子质量约为1×104,相对分子质量分布Mw/Mn约为2。     

MAX3100在80C196串口扩展中的应用

介绍采用新型的UART器件MAX3100为Intel单片机80C196扩展串口，给出了硬件设计和软件编程，并对关键技术进行了说明。     

双电池系统电源选择器MAX1773/1773A

MAX1773／MAX1773A是用于双电池系统的电源选择器，它允许外部控制器去管理双电池组、适配器输入、电池充电器和系统负载所需的电源连接。文中介绍了MAX1773／1773A的特点、引脚功能、内部结构和工作原理，给出了MAX1773/MAX1773A的典型工作电路。     

16位A/D转换器MAX1166的原理及应用

MAX1166是美国MAXIM公司生产的逐次逼近型16位低功耗模数转换器 ,该转换器内带4.096V精密参考源 ,同时具有并行数据输出接口。文章介绍了该模数转换器的特性、功能及实际应用电路。     

高性能∑-△A/D转换器MAX1403在微功耗旋涡流量计中的应用

本文在旋涡流量计中采用MAX1403芯片进行温度、压力传感器的激励、信号放大和16位A/D转换,缩小了体积,提高了可靠性,满足了该流量计研制中低功耗、高精度的苛刻要求.     

16位串行模数转换器MAX1132的特性及应用

MAX1132是美国MAXIM公司生产的16位串行模数转换器，文章介绍了MAX1132的工作原理、接口特点及使用方法，给出了它在数据采集系统中的硬件电路和软件程序。     

MAX+Plus与数字电路教学

MAX PlusⅡ是美国Altera公司为开发其编程逻辑器件而推出的工具软件,可以完成从门级到系统级的逻辑芯片的设计,是典型的逻辑设计与综合工具.将MAX PlusⅡ用于课堂教学中,可以起到事半功倍的效果,作图快捷,修改方便,仿真结果直观具体,提高课堂讲授效率,将抽象的逻辑教学形象化和直观化.简要介绍了电子设计自动化(EDA)的理念和工具MAX Plus及其在普通数字电路教学中的应用,并以设计一个有使能控制端的半加器为例,说明MAX PlusⅡ的设计、仿真过程,以期得到融传统教学方式和现代化设计理念为一体的教学效果.     

闭路电视监控系统中矩阵控制器的设计

以 6 4× 16矩阵控制器为例 ,介绍了闭路电视监控系统中矩阵控制器的设计方法 ,矩阵控制器的主要功能 ,以及视频矩阵切换芯片MAX4 35 8的性能特点及使用方法 ,概括提出了在软、硬件设计时应注意的几个问题