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排序方式: 共有442条查询结果,搜索用时 140 毫秒
1.
本文用ASAP2000吸附仪测定了吸附性能优异的沥青基高比表面积新型活性碳(PHAC)的BET比表面积、用BJH和DRS法分析了其孔隙结构参数,用XPS测定了PHAC的表面元素组成及含氧官能团,对PHAC的表面形态结构进行了SEM和TEM观察。研究表明:PHAC具有高度发达且均匀的微孔结构,其表面含有一定量的C-O-C、C-OH、C=O、O=C-O等多种类型的含氧官能团。 相似文献
2.
R.H. Laskar D. Chakrabarty F.A. Talukdar K. Sreenivasa Rao K. Banerjee 《Applied Soft Computing》2012,12(11):3332-3342
In this paper, we present a comparative analysis of artificial neural networks (ANNs) and Gaussian mixture models (GMMs) for design of voice conversion system using line spectral frequencies (LSFs) as feature vectors. Both the ANN and GMM based models are explored to capture nonlinear mapping functions for modifying the vocal tract characteristics of a source speaker according to a desired target speaker. The LSFs are used to represent the vocal tract transfer function of a particular speaker. Mapping of the intonation patterns (pitch contour) is carried out using a codebook based model at segmental level. The energy profile of the signal is modified using a fixed scaling factor defined between the source and target speakers at the segmental level. Two different methods for residual modification such as residual copying and residual selection methods are used to generate the target residual signal. The performance of ANN and GMM based voice conversion (VC) system are conducted using subjective and objective measures. The results indicate that the proposed ANN-based model using LSFs feature set may be used as an alternative to state-of-the-art GMM-based models used to design a voice conversion system. 相似文献
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Kinetic and thermodynamic analyses of catalytic hydrodechlorinations in supercritical carbon dioxide (SC-CO2) were performed using 5% Pd supported on γ-Al2O3. The selected standard compounds used for the study represented chlorinated wood resins commonly found in pitch deposits; 1-chlorooctadecane (C18-Cl), 9,10-dichlorostearic acid (Stearic-Cl2), and 12,14-dichlorodehydroabietic acid (DHA-Cl2). The reaction utilized isopropanol as a hydrogen donor. Pressure, temperature, and the concentrations of isopropanol and palladium were varied to study the effect of each parameter and to optimize the dechlorination yield. The reaction in SC-CO2 was compared to the one in liquid solvents at atmospheric pressure. By applying a Langmuir–Hinshelwood kinetic model, the rate-determining step of the reaction was deduced to be adsorption of the chlorinated molecules on the palladium surface. The apparent activation energies of the reactions for C18-Cl, Stearic-Cl2, DHA-Cl2 were 43±5, 40±7, and 135±7 kJ mol−1, respectively, in SC-CO2. The relatively high activation energy for DHA-Cl2 was apparently due to structural differences from the other two compounds. The apparent activation energy of dechlorination of C18-Cl in liquid isopropanol at atmospheric pressure was determined to be 35±3 kJ mol−1, leading to the conclusion that the rate-determining step is the same for this compound in both fluid systems. The enthalpies of desorption of stearic acid and dehydroabietic acid were determined to be 18±2 and 12±2 kJ mol−1, respectively. These values being less than half of the apparent activation energies of dechlorination of their corresponding chlorinated compounds indicates that desorption of the dechlorinated products is not the rate-determining step of the reaction. This was consistent with the conclusion that the rate-determining step is adsorption, on the understanding that the reaction mechanism is same in both fluid systems. 相似文献
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现有的基音周期提取方法在准确度和稳健性上存在一定的局限性,很难准确地提取出信噪比较低的语音信号的周期.针对这一问题,提出一种基于小波变换的基音周期提取改进算法,将TEO(Teager Energy Operator)算子与二进小波变换结合起来,首先进行清浊判定,然后只对浊音帧采取多尺度小波分析提取周期,提出用幅度信息和出现概率信息校正二进小波模极大值间距,从而得到准确的周期.计算机仿真结果表明,与传统方法相比,不仅提高了处理效率,而且具有更高的精确度和稳定性. 相似文献
7.
基音周期估计中倍数检验算法的研究 总被引:2,自引:0,他引:2
讨论了基于自相关函数法基音周期估计过程中的倍数检验和校正问题。自相关函数法是语音信号处理中的一种重要方法,但往往会把真实基音周期的倍数误判为真实的基音周期。为了防止误判,提出了倍数检验算法。实验表明:使用该算法,提高了基音周期估计的准确性,改善了基音周期轨迹的平滑度。 相似文献
8.
This paper proposes a novel signal transformation and interpolation approach based on the modification of DCT (Discrete Cosine Transform). The proposed algorithm can be applied to any periodic or quasi periodic waveform for time scale and/or pitch modification purposes in addition to signal reconstruction, compression, coding and packet lost concealment. The proposed algorithm has two advantages:
(i)
Since DCT does not have the explicit phase information, one does not need the cubic spline interpolation of the phase component of the sinusoidal model. (ii)
The parameters to be interpolated can be reduced because of the energy packing efficiency of the DCT. This is particularly important if signal synthesis is carried out on a remote location from the transmitted parameters.
9.
目前音频数据库的研究相对于图象处于滞后,文中侧重音乐角度,结合MPEG标准和基于内容检索的应用,综述了音频检索的研究现状,分析了音频方面研究的特殊性和相关应用中的问题;并提出基于独立分量分析(ICA)的按调查询(QBH)的系统,较好地解决了特征提取中的鸡尾酒会效应问题。系统的查询结果置于三维声效环境中加速了查询。 相似文献
10.
基于多相滤波器组的语音基频检测方法 总被引:1,自引:0,他引:1
基于多相滤波器组的语音基频检测方法,运用多相滤波器组分解语音信号频谱,然后利用声带震动的能量准周期性在各子带进行峰值搜索,并综合这些子带的搜索结果计算基音周期,最后根据先验知识以及一种新的清浊音判定方法对结果进行校正。基于标准TIMIT语料库子集的实验结果证明了此方法的有效性。 相似文献