Single‐Source Precursors For Synthesizing Bifunctional Periodic Mesoporous Organosilicas

A new class of bifunctional periodic mesoporous organosilicas (PMOs) composed of organosilicate building blocks with two different silicon sites have been synthesized from the single‐source bifunctional organosilica precursors tris(triethoxysilylethyl)ethoxysilane and bis(triethoxysilylethyl)diethoxysilane, respectively denoted MT³‐PMO and DT²‐PMO. The synthesis of these PMOs is achieved by the co‐assembly of a triblock‐copolymer Pluronic P123 template with the bifunctional organosilica precursor under acid‐catalyzed and inorganic‐salt‐assisted conditions. After template removal through solvent extraction, the MT³‐PMO and DT²‐PMO so obtained show well‐ordered mesopores and display large pore diameters (6–7 nm) and pore volumes (0.6–0.8 cm³ g^–1) with a narrow pore‐size distribution and high surface areas (700–800 m³ g^–1).     

国际函件处理信息系统设计

本文试图从系统整体及行业MIS建模方法出发，对国际函件处理信息系统进行了系统设计．在设计中，遵循了对象模板法的开发思想，采用了FoxPro与Excel相结合的技术．所开发出的系统功能较齐全，人权界面友好，具有一定的推广应用价值．     

Rational Synthesis of Metal Nanotubes and Nanowires from Lamellar Structures

A generic method has been developed for the synthesis of crystalline metal nanowires or nanotubes (such as bismuth nanotubes, tungsten nanowires) from lamellar structures. In a typical process, lamellar surfactant/inorganic composite precursors are first prepared by reacting cationic or anionic surfactants with inorganic species under appropriate conditions. After treating these precursors by hydrothermal pyrolysis, or other processes, crystalline metallic nanotubes or nanowires are obtained.     

Block Copolymer Surface Reconstuction: A Reversible Route to Nanoporous Films

Thin films of block copolymers have been used as templates and scaffolds for the fabrication of arrays of nanostructured materials. In general, a chemical modification of the film or the removal of one of the components by photodegradative methods is required to produce a nanoporous film that serves as a template or scaffold. Here, however, the preferential interaction of one of the components with a solvent is shown to produce a reconstruction of the block copolymer film that, upon drying, leads to the generation of a nanoporous template. The area density of the pores is identical to that of the original copolymer thin film. Since no chemical reactions occurr, the process is fully reversible. Upon heating the copolymer film above its glass‐transition temperature, mobility is imparted to the copolymer and the original copolymer film with oriented domains is recovered. The film reconstruction significantly simplifies the generation of nanoporous templates.     

Nodally exact Ritz discretizations of 1D diffusion–absorption and Helmholtz equations by variational FIC and modified equation methods

This article presents the first application of the Finite Calculus (FIC) in a Ritz-FEM variational framework. FIC provides a steplength parametrization of mesh dimensions, which is used to modify the shape functions. This approach is applied to the FEM discretization of the steady-state, one-dimensional, diffusion–absorption and Helmholtz equations. Parametrized linear shape functions are directly inserted into a FIC functional. The resulting Ritz-FIC equations are symmetric and carry a element-level free parameter coming from the function modification process. Both constant- and variable-coefficient cases are studied. It is shown that the parameter can be used to produce nodally exact solutions for the constant coefficient case. The optimal value is found by matching the finite-order modified differential equation (FOMoDE) of the Ritz-FIC equations with the original field equation. The inclusion of the Ritz-FIC models in the context of templates is examined. This inclusion shows that there is an infinite number of nodally exact models for the constant coefficient case. The ingredients of these methods (FIC, Ritz, MoDE and templates) can be extended to multiple dimensions     

一种新的累加自动地形生成方法*

提出了一种新的基于分形的累加自动地形生成方法,首先引入断裂形成算法作为地形高度生成器的初始模型,通过控制幅度和迭代次数,生成形态各异的地形轮廓,然后从分形理论fBM数学模型出发,使用中点位移法对初始模型进行迭代处理,生成丰富的地形细节。该方法的主要优点是自动性和可控性的结合,一方面通过设置断裂形成算法的参数可以自动生成特征模板,另一方面通过控制分形参数,生成任意层次的地形细节。实验表明,使用该方法可以生成真实感较强的地形,该方法是可行且有效的。     

基于多模板匹配和可信度分析的中文文档图像关键词过滤方法*

针对互联网中文文档图像非法信息过滤提出了一种多模板匹配结合可信度分析的方法。该方法克服了传统OCR速度慢的缺点,同时改善了基于图像特征匹配方法对字体和噪音敏感的特性。通过改变关键词搜索方式有效地减小了计算量,提高了识别速度。实验结果表明了该方法的有效性。     

Forum The role of CIB: some reflections

An explanation for the low innovation activity in construction is put forward. The central argument is that the current theory of construction is one root cause for low innovation activity. Instead, an explicit and more powerful theory of construction is needed for further innovation, which is ‘to manage new ideas into good currency’. There are three main mechanisms in the current theory of construction which are identified as causing this hindrance. Firstly, production theories in general, as well as construction theories specifically, have been implicit. Therefore, it has not been possible to transfer radical managerial innovations, such as lean production, from manufacturing to construction at a theoretical level. Direct application of this production template to construction has been limited due to the different context of construction in comparison with manufacturing. Secondly, the current theoretical model of construction is based on the transformation model of production. It is argued that the principles of this model are counterproductive, because uncertainty and interdependence are abstracted away. This leads to fragmented and myopic management and inflated variability. Practical examples show that these deficiencies and related practical constraints hinder the implementation of top-down innovations. Thirdly, empirical research shows that also bottom-up innovations - systematic learning and problem solving - are being hindered by the current theory. Thus, the advancement of innovations in construction requires that a new, explicit and valid theory of construction is created, and business models and control methods are developed on the basis of that new theory. Cet article propose une explication concernant le taux bas de l'activité d'innovation dans la secteur du bâtiment. L'argument central étant que la théorie actuelle de la construction est une des raisons fondamentales de cette activité basse d'innover. Au lieu de cela, on a besoin d'une théorie de la construction explicite et plus efficace afin d'innover. Dans la théorie actuelle du bâtiment, il y a trois mécanismes fondamentaux qui sont identifiés comme causes gênant cette innovation. Premièrement, les théories de production en général, ainsi que les théories de la construction en particulier, ont été implicites. Ainsi, il était impossible de transférer des innovations gestionnaires radicales, comme la production allégée (lean production), à partir du domaine de la fabrication à celui du bâtiment à un niveau théorique. L'application directe de ce modèle de production au secteur bâtiment a été limitée à cause du contexte différent de celui-ci en comparaison de celui de la fabrication. Deuxièmement, le modèle théorique actuel de la construction bâtiment est basé sur le modèle de la transformation de production. On avance que les principes de ce modèle agissent négativement sur la productivité parce que l'incertitude et l'interdépendance en sont exclues. Ceci mène à une gestion fragmentée et myope ainsi qu'à une inflation de la variabilité. Des exemples pratiques montrent que ces déficiences et les contraintes pratiques qui leur sont liées, gênent les implémentations des innovations de haut en bas. Troisièmement, une étude empirique montre que les innovations de bas en haut - c'est-à-dire l'apprentissage systématique et la résolution de problèmes - sont gênés par la théorie actuelle. Ainsi, le progrès dan les innovations du secteur bâtiment exige qu'une nouvelle théorie explicite et valide soit créée, et que des modèles d'affaires et des méthodes de contrôle soient développés sur la base de cette nouvelle théorie.     

Fabrication and characterization of hierarchical porous Ni2+ doped hydroxyapatite microspheres and their enhanced protein adsorption capacity

Hydroxyapatite (HAP) is a common bio-adsorbent, which performance depends heavily upon its morphology and microporous structure. In this study, a novel synthesis strategy was proposed for hierarchical porous HAP microspheres by a simple “one-pot” hydrothermal reaction. In the strategy, L-glutamic acid serves as soft template to modulate the morphology and inner crystalline of HAP. To evaluate the application potential, doping Ni²⁺ on hierarchical porous HAP microspheres gives metal chelated affinity adsorbents. The prepared adsorbents show a perfect spherical shape, particles size of 96.6 μm, relatively specific surface area of 48.5 m²·g^-1 and hierarchical pores (mesopores: 4 nm and macropores: 53 nm). By the adsorption evaluation, it reveals that the Ni²⁺-HAP adsorbents have high adsorption capacities of 275.11 and 97.55 m²·g^-1 for hemoglobin and bovine serum albumin, respectively, which is comparable to other similar adsorbent. Therefore, this work provides a promising method for high-efficiency hydroxyapatite microspheres for proteins purification.     

Study on manufacturing information sharing and tracking for extended enterprises

To solve manufacturing information sharing and tracking problems, three key issues are discussed. Firstly, templates are used to host manufacturing information, though they differ in their content and capacity. Secondly, the manufacturing information sharing and controlling method (MISCM) locates every information item at a discrete point on the manufacturing information plane according to its invisibility and unusability. And each user has several various privilege areas in the plane. According to the mapping relationship between the information set and the discrete point set, every user is entitled to access some information items. A template that contains these privileges is activated. Thirdly, when the manufacturing process is in progress, templates are instantiated. Then, a time-dependent instantiated template net (TIT-net) emerges. Based on its searching algorithm, information tracking is achieved through the history view and the in-time view. Finally, some examples show how these issues work together to implement a fluent, controllable and dynamic manufacturing information tracking mechanism.