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Alena Yarysheva Dmitry Strel'tsov Sergey Malakhov Olga Arzhakova Larisa Yarysheva Alexandr Volynskii 《Polymer International》2020,69(7):627-634
This work addresses the phenomenon of the development of a patterned surface relief on polymer films via different modes of environmental crazing. Commercial films of semicrystalline poly(tetrafluoroethylene) (PTFE) and amorphous glassy poly(ethylene terephthalate) (PET) were subjected to tensile drawing in the presence of physically active liquid environments (carbon tetrachloride or aliphatic alcohols). The structure parameters and wettability of the modified films were studied by AFM, SEM, profilometer measurements and contact angle measurements. Environmental intercrystallite crazing of PTFE is accompanied by the development of an unstable structure with a high free surface, which experiences marked strain recovery upon unloading. As a result of the relief formation, PTFE hydrophobicity is enhanced (the water contact angle increases by 25°). Classical environmental crazing of PET films is accompanied by the formation of an anisotropic surface relief which is an assembly of crazes oriented perpendicular to the direction of tensile drawing, thus leading to the phenomenon of anisotropic wetting. The proposed approach for structural surface modification makes it possible to use the advantages of surface instability and spontaneous self‐organization of the polymer towards the development of a unique surface microrelief. © 2020 Society of Chemical Industry 相似文献
3.
The fourth-order partial differential equations have good performance on noise smoothing and edge preservation without creating blocky effects on smooth regions. However, for low signal-to-noise ratio images, the discrimination between edges and noise is a challenging problem. A novel kernel-based fourth-order diffusion is proposed in this paper. It introduces a kernelized gradient operator in the fourth-order diffusion process, which leads to more effective noise removal capability. Experiment results show that this method outperforms several previous anisotropic diffusion methods for noise removal and edge preservation. 相似文献
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The copreheat-treatment of non-fusible and slightly fusible coals with A240 and hydrogenated A240 under high temperature-short contact-time conditions around 500 °C has been examined in an attempt to produce a formed coke with better anisotropic development. These conditions shortened the copreheat-treatment time and provided better anisotropic development in the resultant coke after carbonization. Effectiveness of short contact-time has been discussed in terms of the extent of depolymerization of coal molecules suitable for anisotropic development, this being related to coal liquefaction under similar conditions. 相似文献
6.
We describe a Gauss–Seidel algorithm for optimizing a three‐dimensional unstructured grid so as to conform to a given metric. The objective function for the optimization process is based on the maximum value of an elemental residual measuring the distance of any simplex in the grid to the local target metric. We analyse different possible choices for the objective function, and we highlight their relative merits and deficiencies. Alternative strategies for conducting the optimization are compared and contrasted in terms of resulting grid quality and computational costs. Numerical simulations are used for demonstrating the features of the proposed methodology, and for studying some of its characteristics. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
7.
高性能各向异性Sm2Fe17Nx磁粉的制备 总被引:5,自引:0,他引:5
本文研究了高性能各向异性Sm2Fe17Nx磁粉的制备工艺路线与工艺参数。优化了制备与工艺参数。已制备出磁性能达到:Br=1.39T,Hci=850KA/m和(BH)m=236KJ/m^3的各向异性Sm2Fe17N2.88磁粉,该磁粉的各向异性场HA达到20T。 相似文献
8.
The influence of the substrate nature on the structure and morphology of ITO thin films grown by thermal evaporation in vacuum is investigated. The as-prepared metal films with Sn/In molar ratio of 0.1 were subsequently annealed for 2 h at 723 K in air (to obtain tin doped indium oxide), then annealed in vacuum at 523 K, followed by UV irradiation (to reduce the electrical resistivity). Irrespective of substrate nature, XRD data evidence a (222) preferential orientation in films. Substrate nature, annealing in vacuum and UV irradiation influence the structure, morphology, optical, electrical and surface wetting properties of the films' surface. 相似文献
9.
二维金属凹槽填充各向异性介质时散射的边界元方法:TE情形 总被引:2,自引:0,他引:2
由各向异性介质无界空间Green函数和Green恒等式出发,推导了TE波入射时二维任意截面金属凹槽填充各向异性介质时所满足的边界积分方程,并用边界元法和广义网络原理计算了金属凹槽填充各向异性介质时的散射。用文中方法退化计算了凹槽填充各向同性介质时的散射,计算结果与解析结果一致。并给出了凹槽填充各向异性介质时的散射算例。 相似文献
10.
朱衍镛 《石油地球物理勘探》1991,(3)
本文对Byun(1990)的横向各向同性介质的旅行时反演方法作了两点改进:其一是根据优化后的V_r值计算一个初始的F值,然后再根据这个初始值进行最小均方误差分析;其二是对初始值进行优化分析时,提出用测量值(或由式(4)和式(10)计算的理论值)作为实际值进行拟合,而Byun的方法是用式(11)的计算来得到一个实际值。理论模型证明:本文所述方法有一个比较宽的适应性,而Byun方法只在弱各向异性时才可以得到较精确的结果。 相似文献