Nanoraspberry-like palladium/spongy nickel oxide for electrooxidation of five light fuels

The spongy nickel oxide (SNO) was synthesized the solution combustion method. The SNO was selected as a promoter to boost the catalytic activity of nanoraspberry-like palladium (NRPd) toward electrooxidation of five light fuels (LFs): methanol, ethanol, formaldehyde, formic acid, and ethylene glycol. The X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy, and field emission scanning electron microscope techniques were used for the materials characterization. In comparison with nonpromoted Pd, the NRPd-SNO electrocatalyst shown an excellent efficiency in parameters like the electrochemical active surface area and anti-CO poisoning behavior. The turnover data and the parameters, including reaction order, activation energy, and the coefficients of electron transfer and diffusion, were evaluated for the each process of LFs electrooxidation. The outcome for NRPd-SNO activity toward LFs electrooxidation was compared to some reported electrodes. The SNO increases the removal of intermediates created in the oxidation of LFs that can poison the surface of palladium catalyst. This is due to the presence of the lattice oxygens in SNO structure and Ni switching between its high and low valances. The compatibility of the adsorption process of LFs on the surface of the NRPd-SNO catalyst with different isotherms was determined by studying the Tafel polarization and calculating the surface coverage.     

Exploring the feasibility of green hydrogen production using excess energy from a country-scale 100% solar-wind renewable energy system

When planning large-scale 100% renewable energy systems (RES) for the year 2050, the system capacity is usually oversized for better supply-demand matching of electrical energy since solar and wind resources are highly intermittent. This causes excessive excess energy that is typically dissipated, curtailed, or sold directly. The public literature shows a lack of studies on the feasibility of using this excess for country-scale co-generation. This study presents the first investigation of utilizing this excess to generate green hydrogen gas. The concept is demonstrated for Jordan using three solar photovoltaic (PV), wind, and hybrid PV-wind RESs, all equipped with Lithium-Ion battery energy storage systems (ESSs), for hydrogen production using a polymer electrolyte membrane (PEM) system. The results show that the PV-based system has the highest demand-supply fraction (>99%). However, the wind-based system is more favorable economically, with installed RES, ESS, and PEM capacities of only 23.88 GW, 2542 GWh, and 20.66 GW. It also shows the highest hydrogen annual production rate (172.1 × 10³ tons) and the lowest hydrogen cost (1.082 USD/kg). The three systems were a better option than selling excess energy directly, where they ensure annual incomes up to 2.68 billion USD while having payback periods of as low as 1.78 years. Furthermore, the hydrogen cost does not exceed 2.03 USD/kg, which is significantly lower than the expected cost of hydrogen (3 USD/kg) produced using energy from fossil fuel-based systems in 2050.     

基于桥连接的词典学习方法的语义解析

现阶段的语义解析方法大部分都基于组合语义,这类方法的核心就是词典。词典是词汇的集合,词汇定义了自然语言句子中词语到知识库本体中谓词的映射。语义解析一直面临着词典中词汇覆盖度不够的问题。针对此问题,该文在现有工作的基础上,提出了基于桥连接的词典学习方法,该方法能够在训练中自动引入新的词汇并加以学习,为了进一步提高新学习到的词汇的准确度,该文设计了新的词语—二元谓词的特征模板,并使用基于投票机制的核心词典获取方法。该文在两个公开数据集(WebQuestions和Free917)上进行了对比实验,实验结果表明,该文方法能够学习到新的词汇,提高词汇的覆盖度,进而提升语义解析系统的性能,特别是召回率。     

织金县HFC双向网络设计方案

织金电视台通过对有线电视网络进行双向改造，为Internet宽带接入、数字电视、VOD等多媒体应用提供了运行平台，介绍织金县城区HFC双向网络设计方案。     

双转向垂向控缝技术实验研究及现场应用

针对压裂过程中缝高较难控制的问题，研制开发出新型的油溶性垂向双转向剂，并开展了室内实验研究。首次验证了转向剂对裂缝延伸的控制机理，确定了转向剂的适用浓度及控缝能力。实验表明，转向剂可以增加隔层应力3～4MPa左右。在此基础上研究了控制裂缝高度施工方案的设计方法，并利用全三维软件结合垂向应力剖面对控缝技术进行了优化。现场推广应用30井次，取得了较好的控缝效果。     

中国未来电力需求与核能

本文介绍了我国未来电力需求和能源结构，阐述了核能是我国满足经济发达地区电力需求的合理选择，并提出了我国“九五”核电计划和中期目标，以及发展核电中面临的问题和基本对策。     

实施油气回收的必要性和技术方案的探讨

简要介绍油气回收技术;从环保和增加经济效益的角度,以福建炼化公司的实际情况为例提出了油气回收的方案,并对实行该方案的必要性和经济效益做了分析;希望增强炼化企业对油气回收问题的重视,达到安全生产、改善环境和节约能源的目的。     

黄河下游游荡性河道整治方案研究

小浪底水库投入运用后，黄河下游水沙条件的变化，使游荡性河道整治出现了新情况，新问题。下一步治理应注意积极修建新布点工程，完成具有关键性导流作用的续建工程，确定适应新情况的设计治导线，积极开展新结构试验和观测研究。     

海河流域河道外生态需水研究

水土流失是海河流域较为突出的生态环境问题之一。经对比研究发现，植被覆盖度的变化会通过影响洪充量，土壤侵蚀量等因子，进而改变水土流失的状况。从提高植被覆盖度尤其是低覆盖度草地植被的角度出发，定量研究了为改善流域水土流失状况河道外生态需水的具体数额，得出海河流域现状年河道外生态耗水（降水）385亿m^3。另外，为改善河道外生态环境状况将低覆盖度草地提高地提高至中等覆盖度水平，则需要增加生态需水12．5亿m^3。     

根据人工裂缝特征优化油井压裂地质方案

近年来大庆油田外围地区地质储量得到动用，每年依靠压裂投产的井逐渐增多，由达西定律可知，在油层厚度一定的情况下，措施井的渗透率是影响产量的关键参数，油井压裂可以改善油井周围地层渗透性，消除近井地带油层污染，从而提高油井产能，而人工压裂的成功与否主要取决于裂缝的导流能力和裂缝的几何形态，为此，根据台105地区地质特征，结合低渗透油田开发实际，本着经济有效的开发原则，从人工裂缝特征，方位对开发效果的影响等方面，论述了优化油井压裂地质方案技术的方法，改善了低渗透油田的开发效果。