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排序方式: 共有1207条查询结果,搜索用时 31 毫秒
1.
氮杂冠醚合成中的双功能基试剂 总被引:1,自引:0,他引:1
综述了氮杂冠醚合成中的双功能基试剂的进展。着重讨论了典型的双功能基试剂,如取代多甘醇、二胺、氨基二醇、二卤代物、二醛和二酮以及3-烷氧丙烯醛等的制备方法。 相似文献
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对快速击实试验研究成果进行了总结,并介绍了应用快速击实试验研究成果的经验.不论是重型击实还是轻型击实,也不论击实试验所给定的击实功能多大,应用"一点法"或"快速法"击实试验原理,对土料都有一定要求."一点法"击实试验与快速击实试验所用土体的比重在2.67~2.73之间,当被测土样的比重超越此范围时,在绘制击实曲线时可适当偏离ρdmax计算值的点,但这个误差是很小的,通常ρdmax的影响在±0.01 g/cm3以内,而对ωop的影响在±0.5%以内.结合工程实例,对击实试验成果的简化校正作了详细介绍. 相似文献
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Dario Pasini Luigi Garlaschelli Elza Bontempi Laura E. Depero 《Fullerenes, Nanotubes and Carbon Nanostructures》2007,15(5):367-378
The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C60 compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films. 相似文献
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Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
8.
N. Ilayaraja A. Manivel D. Velayutham M. Noel 《Journal of Applied Electrochemistry》2008,38(2):175-186
Electrochemical perfluorination (ECPF) of n-hexanoyl, n-heptanoyl, n-octanoyl, n-nonanoyl and n-decanoyl chlorides was carried out under identical experimental conditions in liquid HF. The product distribution among perfluorinated
carboxylic acids, perfluoro ethers, perfluoroalkanes, isomerised and fragmented products containing less number of carbon
atoms was identified using 19F NMR. The selectivity of C6–C10 perfluoro carboxylic acid varied between 29 and 36%. The alkali insoluble perfluoro cyclic ether and perfluoro alkane fractions
increased with increasing chain length. The increase of perfluoroalkane fractions is mainly due to decarboxylation. Cyclic
ether fractions also decreased slightly with increase in chain length. Among the cyclic ethers α substituted oxolanes were
the predominant products. Six membered cyclic ethers were always found to contain β substitution. The possible pathways for
these products are also indicated.
An erratum to this article can be found at 相似文献
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在金属板带的轧制中,不同品种和宽度的板带需要不同的轧辊原始凸度。在实际工程中,靠人为摸索和经验积累来估计凸度,不仅效率低、成本高,而且误差大。通过数学推导建立起适合不同品种、不同宽度的板带轧制的轧辊原始凸度抛物线曲线预测模型;经过优化和实际应用,采用正弦曲线来预测轧辊原始凸度可以明显减轻二肋浪,提高板带平直度。 相似文献