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Hari B. Goyal M. O. Garg K. R. Rao R. D. Srivastava 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(2):49-56
The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid. 相似文献
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在上海石油化工研究院开发的分子筛催化剂和联合化学反应工程研究所华东化工学院分所小试过程开发的基础上,建立了年产300t乙苯的中试装置,进行了由乙烯、苯气相烷基化合成乙苯的中试研究,为工业生产提供了设计依据。 相似文献
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Daizo Kunii 《Chemical engineering science》1980,35(9):1887-1911
A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy. 相似文献
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The process of grinding soybeans to a fine flour and extracting the flour with hexane was studied on a pilot plant scale.
The crude oil from the pilot plant study had 15 ppm phosphorus and was suitable for physical refining after a light acid pretreatment
and bleaching. The refined oil showed a Lovibond color of 1.4 yellow and 0.3 red. The pilot plant study also showed that grinding
of the soybeans and the separation of solid from miscella were the most difficult steps in solvent extraction with fine flour.
A laboratory study on separation of miscella from meal by aqueous ethanol reduced the hold-up volume, but it did not remove
all the miscella. A test with betacarotene showed that only the miscella outside the flour particles was displaced.
Aqueous ethanol solutions used as a second solvent extracted additional nontriglyceride materials (primarily phospholipids)
from the meal. Also, the free fatty acid content of the oil was increased with aqueous ethanol solution wash. The quality
of the extracted crude oil was lowered by using a second solvent, but it had the advantage of needing only one centrifugation
to separate miscella from meal. 相似文献
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朱鸿德 《昆明冶金高等专科学校学报》2010,26(5):14-17
说明了鹅头厂铁矿露天采场延深采用硐室爆破的理由,分析了爆破参数选择、硐室爆破参数计算、边坡安全的要求、导硐及药室布置、药室堵塞及起爆网路等,并对爆破效果进行了评价。 相似文献
10.
目前几乎所有最先进的目标检测方法都依赖于预先定义的anchor,但是由于anchor的存在,网络会增加与anchor相关的计算开销,而且在现实世界中,目标尺度多种多样,比如地对空拍摄的无人机目标,预先定义的anchor不可能穷举所有的无人机尺度。因此,该文抛弃预先定义的anchor,采用anchor free的方法来检测无人机。该anchor free方法以目标中心区域的像素为训练样本来逐像素预测边界框的偏移量。针对地对空拍摄的无人机目标大部分都是小尺度的情况,采用高分辨率网络HRNet作为主干网络来提取小目标细粒度的特征,从而提高小目标检测的精度。相对于基于anchor的目标检测方法,该网络框架简单、灵活,并且可以自适应地预测无人机目标的边界框。在自己设计的无人机数据集上,该方法获得了更高的召回率和精确率。 相似文献