An adaptive sliding mode observer based near-optimal OER tracking control approach for PEMFC under dynamic operation condition

Tracking control of oxygen excess ratio (OER) is crucial for dynamic performance and operating efficiency of the proton exchange membrane fuel cell (PEMFC). OER tracking errors and overshoots under dynamic load limit the PEMFC output power performance, and also could lead oxygen starvation which seriously affect the life of PEMFC. To solve this problem, an adaptive sliding mode observer based near-optimal OER tracking control approach is proposed in this paper. According to real time load demand, a dynamic OER optimization strategy is designed to obtain an optimal OER. A nonlinear system model based near-optimal controller is designed to minimize the OER tracking error under variable operation condition of PEMFC. An adaptive sliding mode observer is utilized to estimate the uncertain parameters of the PEMFC air supply system and update parameters in near-optimal controller. The proposed control approach is implemented in OER tracking experiments based on air supply system of a 5 kW PEMFC test platform. The experiment results are analyzed and demonstrate the efficacy of the proposed control approach under load changes, external disturbances and parameter uncertainties of PEFMC system.     

Structural and optical properties of CdTe-nanocrystals thin films grown by chemical synthesis

By mans of a chemical synthesis technique stoichiometric CdTe-nanocrystals thin films were prepared on glass substrates at 70 °C. First, Cd(OH)₂ films were deposited on glass substrates, then these films were immersed in a growing solution prepared by dissolution of Te in hydroxymethane sulfinic acid to obtain CdTe. The structural analysis indicates that CdTe thin films have a zinc-blende structure. The average nanocrystal size was 19.4 nm and the thickness of the films 170 nm. The Raman characterization shows the presence of the longitudinal optical mode and their second order mode, which indicates a good crystalline quality. The optical transmittance was less than 5% in the visible region (400–700 nm). The compositional characterization indicates that CdTe films grew with Te excess.     

燃气红外线辐射器的节能与环保特性分析

论述了燃气红外线辐射器的基本原理 ,对其节能与环保特性的分析表明 :与大气式燃烧器相比 ,红外线辐射器的燃料节约率为 15 %～ 45 % ,CO2 排放量减少率为 15 %～ 48% ,CO排放量减少率为 96.2 %～ 97.7% ,NOx 减少率为 94.9%～ 96.9% ,具有显著的节能与环保效果     

初论带状光纤缆结构设计

推导出了成叠带状光纤在松套管中余长的两个计算公式，此两公式是带状光纤缆结构设计需要用到的基本公式。此外，还对带状光纤缆结构设计作了初步讨论。     

合理选用过剩空气系数的重要性分析

通过分析过剩空气系数过大或过小时加热炉多方面的影响,强调了合理选用过剩空气系数的重要性,并提出了控制措施。     

Thermophysical Properties of Binary Mixtures of Methyl Methacrylate+Di-Ethers (Ethyl, Isopropyl, and Butyl) at 298.15 and 308.15 K

Experimental data for the densities, dynamic viscosities, sound speeds, and relative permittivities and for three binary systems of methyl methacrylate (MMA)+di-ethers (ethyl, isopropyl, and butyl) at 298.15 and 308.15 K and at atmospheric pressure are reported. The mixture viscosities are correlated by Grunberg–Nissan, McAllister, and Auslander equations over the complete composition range. The sound speeds for the mixtures are also calculated by using free length and collision factor theories, and Nomoto and Junjie equations. From the measured primary properties, deviation functions such as deviations in viscosities, sound speeds, relative permittivities, molar polarizations, excess isentropic compressibilities, and molar electrical susceptibilities were calculated, and the compositional dependence of each of the functions was expressed with a Redlich–Kister type equation. The variation of the Kirkwood correlation factor was determined over the complete composition range.     

Synthesis and properties of monodisperse hydroxy-terminated oligomers of 1,4-butanediol and 2,4-toluene diisocyanate

The synthesis of monodisperse hard segments containg 2,4-TDI and 1,4-butanediol by a simple technique is described. High purity material is obtained in good yield. The structures of these hard segments are confirmed by proton n.m.r., ¹³Cn.m.r., and i.r. Glass transition temperatures and melting temperatures are reported. The T_g′s of the hard segments are inversely proportional to the reciprocal of their molecular weights. The T_m′s show an odd-even effect relative to the number of 2,4-TDI units in the hard segment.     

生烧石灰对氧化铝生产过程的影响及石灰炉热工现状分析

由于反苛化作用，生烧石灰对氧化铝生产的循环效率、溶出和蒸发工序有很大的影响。本文对石灰生烧的热工现状进行了热平衡验算，从热工的角度分析了石灰烧制中存在的缺陷，通过热工计算，提出了改善石灰烧制质量的建议，以消除其在生产过程的危害及实现增效的目的。     

剩余污泥资源化提取蛋白质方法的优选

剩余污泥中蛋白质的资源化利用是目前研究的热点,污泥预处理则是实现污泥中蛋白质释放的重要途径。为了进一步提高剩余污泥中蛋白质的溶出效果,选取热碱预处理、超声碱联合预处理、溶菌酶预处理对污泥进行溶胞,以蛋白质提取浓度为主要指标进行参数优化,并利用等电点法对粗提取蛋白进行纯化回收。结果表明：溶胞效果热碱预处理（pH值13、温度140℃、时间1.5 h,2 062.98 mg/L）>超声碱联合预处理（497.76 mg/L）>溶菌酶预处理（269.95 mg/L）,且在pH值为3时热碱预处理蛋白质纯化回收率可达62.42%。试验结果表明：热碱预处理在提取效果方面较另外两种方法优势明显,具有良好的利用前景。     

浅谈一次盐水的工艺指标控制

介绍了一次盐水的各项工艺指标对生产的影响以及稳定控制这些指标的方法，强调了在生产中控制好一次盐水的工艺指标是影响产品质量及离子交换膜使用寿命的关键。