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Non-pinched, minimum energy solutions are important class of distillation designs that offer the potential advantage of a better trade-off between capital investment and operating costs. In this paper, two important tasks associated with non-pinched distillation designs are studied. Thus the novel contributions of this work to the literature are
(1) A comprehensive methodology for finding non-pinched minimum energy designs.
(2) Understanding of the reasons for the existence of non-pinched distillation designs.
It is shown that the recent shortest stripping line distance approach of Lucia et al. [Lucia, A., Amale, A. and Taylor, R., 2007, Distillation pinch points and more. Comput Chem Eng, available on-line] is capable of systematically and reliably finding non-pinched, minimum energy distillation designs. In addition, we provide an understanding of the reasons behind the existence of non-pinched designs, which include trajectories that follow unstable branches of a pinch point curve in azeotropic systems, the inherent looping structure of trajectories in hydrocarbon separations, and the presence of ancillary constraints in multi-unit processes like extraction/distillation. Several distillation examples are studied and many numerical results and geometric illustrations are presented that show the shortest stripping line distance methodology is indeed a powerful and systematic tool for computing non-pinched, minimum energy designs and that support the underlying reason we provide for the existence of non-pinched designs.  相似文献   
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根据电磁场边界条件和色散关系,理论研究了电磁波从各向同性右手材料向各向异性特异材料入射时的反常折射与反射性质,结果表明,从各向同性右手材料向never cutoff型特异材料入射时,透射波的波矢和坡印廷矢量的反射角具有相反的符号,折射角的幅度随着入射角的增大而增大并趋于一定值;研究了磁导率张量参数对折射角的影响,对于anti-cutoff型特异材料界面,当入射角小于临界角θc时可以发生反常的全反射,而对于always cutoff型特异材料界面总会发生全向全反射。这些电磁性质将在部分聚焦与全向反射镜方面具有潜在的应用价值。  相似文献   
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This study investigates the application of a recently developed construct, the uniform trigonometrization method (UTM), to the singular control problems in chemical engineering. The UTM involves minimal modifications to the original problem, thereby generating near-singular control solutions that can be used for conceptual design and serve as an alternate to direct techniques like nested and simultaneous approaches. Eight classical singular control problems with known analytical solutions and three complex singular control problems from chemical engineering domain are solved in this study. The results obtained using the UTM for these problems are found to match well with the literature and are of higher resolution as compared to the results obtained using a direct pseudospectral-based solver. The ability of the UTM to handle complex chemical engineering problems with both singular controls and state path constraints has also been demonstrated in this study.  相似文献   
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In a series of rulings given in the last few years, the Court of Justice of the European Union (EU) has made use of the concept of targeting by a trader of a particular territorial market as a device for determining the scope of European legislation on private law. The concept is of particular importance in the context of trading activities conducted by means of the Internet, though its significance is not confined to such activities. In particular, the European Court has used the concept of targeting for the purpose of restricting the substantive ambit of intellectual property rights created or harmonised by EU legislation. On the other hand, it has avoided use of the concept of targeting in the context of EU legislation allocating jurisdiction between the courts of the Member States, even in respect of disputes involving intellectual property, except where a legislative text specifically invokes such a concept. The instant paper endeavours to review the position as currently established by the European case-law, and to predict the likely further developments.  相似文献   
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游戏编程是当今程序设计的一个热点,开发过程会遇到各种各样的问题。通过限制构造函数和拷贝函数,设计一个单体全局管理类,可以避免不合适的调用。采用分块技术加栽地图,可以在时空性能上优化游戏。阐述了D3D的空间坐标变换。分析了万向节死锁问题发生的原因,并提出了解决办法。  相似文献   
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