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报道了基于聚(9,9 二辛基芴 4,7 二噻基苯并二唑)(PDOF DBT,m(DOF):m(DBT)=85:15)的双层聚合物发光二极管(PLEDs)在使用碱金属、碱土金属和绝缘材料为阴极时表现的各种特性.当以厚度为3nm左右的Ba作为阴极时,器件表现出较好的性能:外量子效率为1.6%,最大的发光亮度接近4000cd m2.结果表明PDOF DBT与这种阴极的交界面具有较好的能级匹配以及电荷注入平衡. 相似文献
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S. K. Heeks J. H. Burroughes C. Towns S. Cina N. Baynes N. Athanassopoulou J. C. Carter S. Miyashita 《Journal of the Society for Information Display》2002,10(2):139-143
The latest developments in light‐emitting‐polymer (LEP) technology at CDT continue to show steady progress. Device performance for blue, green, and red systems as well as a high‐performance yellow system in terms of device efficiency and stability will be described. Some of the issues associated with the commercialization of LEP technology including the development of direct‐patterning techniques enabling full‐color passive‐ and active‐matrix display will be discussed. 相似文献
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Distributed feedback organic semiconductor lasers based on polyfluorene are shown to be suitable for use as chemical sensors for the detection of nitroaromatic‐based explosive vapors. The laser threshold is increased by a factor of 1.8 and the slope efficiency is reduced by a factor of 3 after exposure to the vapor. The sensing efficiency depends strongly on the excitation energy with a maximum efficiency of 85%. The temporal dynamics of the laser response to the analyte have been investigated. The laser emission falls to 60% of its initial value in 46 s. A model is developed to offer some insight into the diffusion of the vapor molecules inside the polymer layer. 相似文献
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Peng Chen Gui‐Zhong Yang Chuan‐Ming Wang Weizhi Wang Min Wang Tianxi Liu 《Polymer International》2007,56(8):996-1005
Soluble fluorene‐based alternating copolymers containing benzene as the comonomer were synthesized and characterized, in which three different side chains (hydrogen atom, linear octyloxy and bulky benzyloxy groups) were attached to the phenylene ring. The effect of the side chains with different steric hindrances on the photophysical, thermal and electrochemical properties as well as the morphology were investigated. Moreover, the chain conformation and spectroscopic properties in dilute solution were studied to understand the solvent effect. Aliphatic and aromatic solvents were demonstrated to have different influences on the spectra of the polymers owing to various interaction mechanisms in the excited states. Also, a significant decrease of up to 80 °C in the thermal degradation temperature was observed as a result of the introduction of large benzyloxy units. The energy levels of the highest occupied molecular orbital and the lowest unoccupied molecular orbital of the polymers were estimated to be ? 5.76 to ? 5.82 eV and ? 2.19 to ? 2.27 eV, respectively, from cyclic voltammetry measurements. In addition, the electronic structures of the polymers were described via quantum chemical calculations. Copyright © 2007 Society of Chemical Industry 相似文献
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Baohua Zhang Chuanjiang Qin Junqiao Ding Lei Chen Zhiyuan Xie Yanxiang Cheng Lixiang Wang 《Advanced functional materials》2010,20(17):2951-2957
We report an efficient non‐doped all‐polymer polymer white‐light‐emitting diode (PWLED) with a fluorescent three‐color, white single polymer as an emissive layer, an ethanol‐soluble phosphonate‐functionalized polyfluorene (PF‐EP) as an electron‐injection/electron‐transport layer, and LiF/Al as a cathode, respectively. The all‐polymer PWLED achieves a peak external quantum efficiency of 6.7%, a forward viewing luminous efficiency of 15.4 cd A?1 and a power efficiency of 11.4 lm W?1, respectively, at a brightness of 347 cd m?2 with Commission Internationale d’Eclairage coordinates of (0.37, 0.42) and color rendering index of 85, which is the best results among the non‐doped PWLEDs. Moreover, this kind of PWLED not only shows excellent color stability, but also achieves high brightness at low voltages. The brightness reaches 1000, 10000, and 46830 cd m?2 at voltages of 4.5, 5.4, and 7.5 V, respectively. The significant enhancement of white‐single‐polymer‐based PWLEDs with PF‐EP/LiF/Al to replace for the commonly used Ca/Al cathode is attributed to the more efficient electron injection at PF‐EP/LiF/Al interfaces, and the coordinated protecting effect of PF‐EP from diffusion of Al atoms into the emissive layer and exciton‐quenching near cathode interfaces. The developed highly efficient non‐doped all‐polymer PWLEDs are well suitable for solution‐processing technology and provide a huge potential of low‐cost large‐area manufacturing for PWLEDs. 相似文献
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芴基荧光聚合物材料合成中间体的质谱分析 总被引:1,自引:0,他引:1
本文报导了新化合物 2 ,7-双 ( 4,4 ,5 ,5 -四甲基 -1 ,3 ,2二氧杂硼烷 -二基 ) -9,9-二辛基芴的 EI和 ESI的质谱 ,利用质谱 -质谱 ( MS/ MS)分析 ,确认了该谱图中母离子和子离子的关系 ,讨论了其碎裂途径 ,为其结构鉴定提供了依据 相似文献
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A novel series of soluble conjugated random and alternating copolymers derived from 9,9-dioctylfluorene (FO) and 1,1-dimethyl-2,3,4,5-tetraphenylsilole (PSP) were synthesized by Suzuki coupling reactions. The feed ratios of FO to PSP were 95:5, 90:10, 85:15, 70:30, and 50:50. Chemical structures and optoelectronic properties of the copolymers were characterized by elemental analysis, NMR, UV absorption, cyclic voltammetry, photoluminescence (PL), and electroluminescence (EL). The elemental analyses of the copolymers indicated that FO and PSP contents in the copolymers were very close to that of the feed compositions. Unlike the weak PL emission of PSP small molecules in a solution, PFO-PSP solutions could emit strong lights with PL quantum yields between 13 and 30%, indicating that the incorporation of the PSP into the conjugated rigid main chain could greatly restrict the rotations of the phenyl groups of the PSP units even in a solution. Compared with the solution PL, complete PL excitation energy transfer from the PFO segments to the PSP units could be achieved by film PL at lower PSP content. The films of the copolymers exhibited high absolute PL quantum yields between 55 and 84%. EL devices with a configuration of ITO/PEDOT/PFO-PSP/Ba/Al demonstrated that the PSP units could serve as powerful exciton traps, giving exclusively pure green EL emissions. A maximum external quantum efficiency of 1.51% was achieved using the PFO-PSP15 as the emissive layer. 相似文献
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Anna Calabrese Andrea PellegrinoRiccardo Po Alberto SavoiniFrancesca Tinti Nadia Camaioni 《Solar Energy Materials & Solar Cells》2011,95(12):3428-3432
The photovoltaic properties of bulk-heterojunction solar cells with an active layer made of an alternating fluorene copolymer, poly{[2,7-(9,9-bis-(2-ethylhexyl)-fluorene)]-alt-[5,5-(4,7-di-2′-thienyl-2,1,3-benzothiadiazole)]}, and [6,6]-phenyl-C71-butyric acid methylester are investigated by varying the blend composition and the incident light power intensity. An efficient donor-acceptor intermixing is reached with donor to acceptor weight ratios of at least 1:3, while at lower acceptor content charge trapping effects are evidenced by the light intensity dependent study. Reverse bias analysis demonstrates that a major limiting factor for the performance of the investigated solar cells is represented by the poor ability of the generation of free charge carriers, attributed to the low hole mobility in the polymer phase. 相似文献
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A thermally responsive rod‐coil poly[poly (N‐isopropylacrylamide)‐b‐polyfluorene‐b‐poly(N‐isopropylacrylamide)] triblock copolymer has been successfully synthesized by atom transfer radical polymerization from an end‐functionalized macroinitiator. The thermochromic behavior and relevant morphology of this polymer were investigated by UV‐vis spectra, DLS, and AFM, respectively, at various temperatures. A thermally responsive fluorescent material was achieved facilely by combining the optically active polyfluorene with temperature‐responsive poly(N‐isopropylacrylamide). All the measurements demonstrated that in the region of 25–45°C, the polymer underwent a phase transition and the corresponding change in optical properties in its water solution. However, the polymer did not show completely reversible behavior upon heating and cooling. On the basis of the comparison with two other thermally responsive conjugated polymers in literatures, a tentative mechanism has been proposed that π–π interaction induced rigid segments to remain chain conformation and packing styles as in collapsed state. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献