Hierarchical Ni-BDC coated FeOOH nanosheets: A coordination tuning synergistic electrocatalyst with enhanced activity for water oxidation

Hierarchical composites represent a class of efficient electrocatalysts for renewable energy storage and conversion technologies owing to the porous structure and additional exposure of metal sites. Herein, a Ni-based metal organic frameworks (MOFs) (marked as Ni-BDC, BDC stands for 1,4-benzenedicarboxylic acid) nanosheet is successfully fabricated on hydroxyl iron oxide (FeOOH) array with carbon fiber cloth (CFC) as substrate. Benefit from the coordination tuning synergistic effect of the distinct chemical composition and the hierarchical structure for fast mass transportation, the as-obtained FeOOH@Ni-BDC illustrates excellent catalytic ability for electrochemical water oxidation with low overpotential of 270 mV to reach 10 mA/cm² current and good durability in alkaline electrolyte. The novelty of this work lies in the modulation of electronic structure of the FeOOH with Ni-BDC through coordination effect to enhance the activity of the hierarchical composite electrocatalyst. This work is expected to guide the preparation of efficient electrocatalyst for new type alternative energy sources exploitation in near future.     

基于调谐频率与分频处理的高分辨率反演技术

讨论了基于调谐频率与分频处理的高分辨率反演技术，给出了方法的基本原理，即利用地震数据的调谐频率和分频处理分析，半定量地确定储层厚度，并将其作为地震反演的约束条件。方法的实现过程是：通过层状地质模型的地震正演模拟，建立不同主频子波时地层厚度与调谐频率的关系；利用地震资料时-频分析技术，实现地震资料分频处理；利用合成地震记录标定地震子波主频；利用分频处理结果，借助于调谐频率分析与调谐振幅分析，给出地震反演约束条件；利用反演算法消除地震子波影响，提高和拓展地震资料的频带范围，实现储层的高分辨率成像。普光地区的应用实例表明，调谐频率与分频处理的高分辨率反演方法无需对储层空间变化规律进行假设，适用于强非均质碳酸盐岩储层的高分辨率成像。     

Wavelength and Waveband Assignment for Ring Networks Based on Parallel Multi‐granularity Hierarchical OADMs

In this paper we study the optimization issues of ring networks employing novel parallel multi‐granularity hierarchical optical add‐drop multiplexers (OADMs). In particular, we attempt to minimize the number of control elements for the off‐line case. We present an integer linear programming formulation to obtain the lower bound in optimization, and propose an efficient heuristic algorithm called global bandwidth resource assignment that is suitable for the design of large‐scale OADM networks.     

基于均匀光纤光栅的DWDM系统PMD补偿方法

提出一种基于均匀光纤Bragg光栅(FBG)的透射型密集波分复用(DWDM)系统多信道偏振模色散(PMD)补偿方案。当FBG受到横向挤压时，会产生双折射现象。当一波长的光信号从光栅带隙附近透射时，就会在快轴和慢轴之间产生时延差(DGD)。通过改变外力的大小来调节DGD的大小可以实现对PMD的补偿。通过将多个补偿光栅级联，就可以实现对DWDM系统多信道PMD的补偿。在100N外力作用下，5cm长的光栅最大可以补偿121ps的PMD，而对相邻0．8nm的信道，只引入0．2ps的DGD。     

微机械可调谐滤波器的研制

利用 Ga As/Al Ga As分布反馈 Bragg反射镜在 Ga As衬底上制作了一个微机械的调谐滤波器 .该器件在 7V调谐电压下调谐范围达28nm     

Gap modulation in MCu[Q1−xQ′x]F (M=Ba, Sr; Q, Q′=S, Se, Te) and related materials

BaCuQF (Q=S, Se, Te) materials exhibit band gaps that allow transmission of much of the visible spectrum. BaCuSF is transparent in thin-film form with a band gap of 3.1 eV. Band gap estimates for powders of the solid solution series BaCuS_1−xSe_xF were obtained from wavelength-dependent diffuse-reflectance measurements using an integrating sphere. The band gap can be tuned by the substitution of Se for S to 2.9 eV for BaCuSeF. The decrease scales almost linearly with the increase in the volume of the tetragonal unit cell, which is determined primarily by the expansion of the a lattice parameter; the overall volume increase is 7.0% from x=0 to 1. Further reduction of the band gap is observed in BaCuSe_1−xTe_xF solid solutions, where a unit cell volume increase of 5.5% produces a band gap of 2.7 eV in BaCuSe_0.5Te_0.5F. Powders and films of BaCuSF exhibit strong red luminescence under ultraviolet excitation, which is suppressed by K doping. Additional tuning of band gap and electrical properties (the materials are p-type conductors) can be achieved by replacing Ba with Sr.     

双波长稳频CO_2激光模糊控制系统的建模与优化

报导一种模糊逻辑控制系统的建模与优化方法。以此方法设计的模糊逻辑控制器，用于双波长稳频ＣＯ２激光器的控制得到令人满意的结果。     

基于体全息技术的WDM器件

利用体全息技术制作波分复用器件是一种新方法。本文介绍了此种方法的基本原理和器件的基本性能，并报道了国外对该项技术的研究进展。     

低阈值宽调谐PPLN光参量振荡

用半导体激光 (LD)抽运的声光调QNd∶YVO4 激光器做抽运源 ,实现了准位相匹配的光参量输出 ,其调谐范围为 1 4 36～ 1 7μm。非线性光学介质是多周期极化的LiNbO3 (PPLN)。光参量振荡阈值 10 3μJ(脉宽 2 2ns) ,在抽运光达到阈值 3 3倍的条件下 ,信号光输出能量 4 2 5 μJ ,斜效率 12 5 %。     

Optimal and self‐tuning fusion Kalman filters for discrete‐time stochastic singular systems

Based on the optimal fusion estimation algorithm weighted by scalars in the linear minimum variance sense, a distributed optimal fusion Kalman filter weighted by scalars is presented for discrete‐time stochastic singular systems with multiple sensors and correlated noises. A cross‐covariance matrix of filtering errors between any two sensors is derived. When the noise statistical information is unknown, a distributed identification approach is presented based on correlation functions and the weighted average method. Further, a distributed self‐tuning fusion filter is given, which includes two stage fusions where the first‐stage fusion is used to identify the noise covariance and the second‐stage fusion is used to obtain the fusion state filter. A simulation verifies the effectiveness of the proposed algorithm. Copyright © 2008 John Wiley & Sons, Ltd.