有机二氟化硼配合物的合成及压致变色性能表征

以阿伏苯宗和三氟化硼为原料,经过一步反应,合成阿伏苯宗二氟化硼(BF2AVB),产物的结构经1HNMR谱确证.基于荧光光谱与X射线粉末衍射测试,对BF2AVB的压致发光性能和机理进行研究.本实验原料易得,反应条件温和,实验操作简单,反应收率高.BF2AVB的压致变色现象明显,通过探讨压致变色机理,加深同学对压致变色材料的了解.同时,该实验可以拓展学科知识,激发学生的专业热情和科研兴趣.     

应用磷灰石裂变径迹分析(AFTA)方法研究沉积盆地古地温

在应用磷灰石裂变径迹 (AFTA)方法研究沉积盆地古地温的原理、研究现状以及应用中应该注意一些问题 ,并以具体例子进行了说明。可以看出 ,应用磷灰石裂变径迹方法研究沉积盆地古地温是一种行之有效的方法 ,能够为古地温场的研究提供可靠的依据 ,并且可用于研究盆地构造运动。     

流量比对等离子体基团分布和薄膜结构的影响

使用光强标定的发射光谱(AOES)测量了CHF3／C6H6混合气体的微波电子回旋共振(ECR)放电等离子体中基团的分布状态。实验发现随着CHF3流量的增加，成膜基团CF、CF2、CH等的相对密度增大，而刻蚀基团F的密度也会增加，从而使得a—C：F薄膜的沉积速率降低。同时红外吸收谱(IR)分析表明，在高CHF3流量下沉积的a—C：F薄膜中含有更高的C—F键成分。可见在a—C：F薄膜的制备中CHF3／(CHF3 C6H6)流量比是重要的控制参量。     

溶胶-凝胶法制备HAP骨水泥材料的研究

文章对用溶胶－凝胶法（简称SOL－GEL）烧结制备HAP骨水泥材料的工艺条件进行了研究，并探索了HAP粉剂与柠檬酸水溶液构成和凝结体系的可行性，结果显示出该材料作为医用骨水泥材料的可能性。     

Preparation of Laminin-apatite-polymer Composites Using Metastable Calcium Phosphate Solutions

A synthetic polymer with a laminin-apatite composite layer on its surface would be useful as a percutaneous device. The preparation of such a composite was attempted in the present study using poly（ ethylene terephthalate ） （PET） and polyethylene （PE） as the synthetic polymer. PET and PE plates and those pretreated with an oxygen plasma were alternately dipped in calcium and phosphate ion solutions, and then immersed in a metastable calcium phosphate solution supplemented with laminin （ LCP solution ）. The PET and PE plates pretreated with an oxygen plasma formed a uniform and continuous layer of a laminin-apatite composite on their surfaces. In contrast, the PET and PE plates that had not been pretreated with an oxygen plasma did not form a continuous layer of a laminin-apatite composite on their surfaces. The hydrophilic functional groups on the PET and PE surfaces introduced by the plasma treatment were responsible for the successful laminin-apatite coruposite coating.     

羟基磷灰石涂层人工关节的应用研究

采用人工合成高纯度的羟基磷灰石粉末，喷涂在具有注册证的钛合金和钴铬钼合金人工关节上。通过生物学基础检测、动物实验和临床试用，证明所制作的各种羟基磷灰石涂层人工关节，能诱发骨质生长，起生物固定作用，对治疗丧失功能的骨胳效果甚佳。     

Design of Polarization-independent Wavelength-interleave Coupler in Fluorinated Polyimide Waveguide

Based on the measurement of dispersion characteristic and birefractive index of the fluorinated polyimide film,a statistical optimum design method is proposed and used to realize the design of 32-and 36-wavelengths optical waveguide wavelength-interleave coupler (i,e.,interleaver) with the optimization of polarization fluctuation and wavelength interval of 0.8nm at 1550nm. The largest cross coupling ratios of the two interleavers are respectively less than 1.8% and 3.5%, while the least through coupling ratios are respectively greater than 98. 2% and 96. 5%. The output differences due to polarization fluctuation are less than 1.7% and 3.2%     

2,4-二氯氟苯的合成

论述了2，4－二氯氟苯合成的新方法。以对氯硝基苯为起站原料，经氟化反应、硝化反应及氯化反应制得2，4-二氯氟苯，总收率达59．0％。本合成路线工艺简单、操作安全、原料易得、成本低廉，适合于工业化生产。     

HAP陶瓷合成的研究

本文对生物陶瓷材料－羟基磷灰石的合成进行了研究。试验将激光合成与湿法合成对比分析，着重探讨了在激光辐照下生物陶瓷的形貌，粒度，化学组成和结构等的变化规律，对激光涂敷生物陶瓷涂层有一定的指导意义。