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排序方式: 共有265条查询结果,搜索用时 15 毫秒
1.
钟广荣 《陕西科技大学学报》2009,27(1):46-49
利用熔融淬火法制备了摩尔分数为40.8Ga2O3-58.0NaPO3-1.2Er2O3掺Er^3+镓磷酸盐玻璃,测试并研究了样品中Er^3+的吸收光谱、1.5μm发射光谱,根据Judd-Ofelt理论计算了Er^3+离子强度参量Ωt(t=2,4,6)及自发辐射概率、荧光分支比、自发辐射寿命.结果表明,Er3+1.5μm发射光谱半峰全宽达到40nm.同时,利用McCumber方法计算了Er^3+4 I13/2→^4I15/2跃迁的受激发射截面,峰值达到6.10×10^-21cm^2,测定了Er^3+4I13/2能级荧光寿命为4.88ms,^4I13/2能级量子效率为56.3%. 相似文献
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采用常规的Sol-gel工艺合成了In^3 掺杂的多孔SiO2干凝胶,In^3 离子作为间隙离子存在于SiO2网络中,展示了一种新颖的发光现象,改变了多孔SiO2干凝胶的发射光谱。这种掺杂的多孔SiO2干凝胶的激发和发射光谱均由2个带组成,短波长的发光峰在440nm(λex=380nm),其相对荧光强度约是未掺杂的多孔SiO2干凝胶的4倍;长波长的发光峰(In^3 离子在多孔SiO2干凝胶的特征发射)在600nm(λex=476nm),其相对荧光强度约是In^3 掺杂ZnS纳米晶的10倍。由此可以看出:掺杂的多孔SiO2干凝胶是一种高效的发光材料。 相似文献
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A. Bensalah Y. Guyot M. Ito A. Brenier H. Sato T. Fukuda G. Boulon 《Optical Materials》2004,26(4):375
YLiF4 (YLF) single crystals undoped and Yb3+-doped with different concentrations were grown by the Czochralski technique under CF4 atmosphere. Detailed analysis of Yb3+-doped YLF spectroscopy were made to contribute to the determination of energy levels in this host. We are dealing with temperature and concentration dependences of both π and σ polarizations of the infrared (IR) absorption and emission spectra. Raman spectra were also used to give an attempt of interpretation of electronic and vibronic levels. The radiative energy transfer (self-trapping) and strong phonon–electron coupling make the assignment of Yb3+ energy levels difficult. Evaluation of the laser potentiality of this fluoride host is also presented. 相似文献
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制备了掺钐螯合物的阶跃型聚合物光纤,研究了螯合物Sm(DBM)3(TOPO)2掺杂的聚甲基丙烯酸甲酯(PMMA)的吸收光谱、激励光谱和发射光谱.根据Judd-Ofelt(J-O)理论,从吸收光谱获得了光学跃迁的强度参数Ω2、Ω4、Ω6分别为18.53×10-20 cm2、2.87×10-20 cm2、3.71×10-20cm2.用光学强度参数计算了激发态4G5/2的辐射跃迁几率(536.19s-1)和辐射寿命(1865μs);同时,计算了4G5/2→6HJ'跃迁的受激发射截面和4G5/2→6FJ'、6HJ'的荧光分支比.分析表明,Sm(DBM)3(TOPO)2掺杂的PMMA可望用于聚合物光纤激光器和放大器. 相似文献
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Yiguang Jiang Benxue Jiang Nan Jiang Dapeng Jiang Jiang Li Liangbi Su Long Zhang 《Journal of the American Ceramic Society》2020,103(10):5808-5812
Er3+-doped CaF2 transparent ceramics are promising mid-infrared gain materials because of their utra-low phonon energy as well as excellent physical, chemical, and optical properties. However, existing hot-pressed and hot-formed CaF2 ceramics are very difficult to be used in practical applications due to residual pores and weak polycrystallization, respectively. Here, we developed the high quality Er3+-doped CaF2 transparent polycrystalline ceramic by single crystal ceramization. The sample exhibits obvious polycrystalline structure, good mechanical properties, perfectly transmittance, and excellent mid-infrared performance, which provides significant and wide-ranging opportunities for advanced mid-infrared gain materials. 相似文献
10.
Mengting Guo Chongyun Shao Yang Zhang Jingbo Yu Yan Jiao Malgorzata Guzik Georges Boulon Jinjun Ren Lili Hu 《Journal of the American Ceramic Society》2020,103(8):4275-4285
The homogeneous Yb3+/Al3+/B3+-co-doped silica glasses were prepared via a sol-gel method. The impact of B2O3 addition on the physical and optical properties and network structure was systematically studied. The network structure was investigated by the Fourier Transform Infrared (FT-IR), Raman spectra, and Solid State Nuclear Magnetic Resonance (SSNMR). Herein, B2O3 addition can continuously decrease the refractive index and density. When B2O3 is lower than 2 mol%, B2O3 addition can obviously decrease the scalar crystal field parameters, Yb3+ asymmetry degree, Yb3+ cross-sections, due to the generation of Yb–O–B bonds at the cost of partial Yb–O–Al/Si ones. When B2O3 is more than 2 mol%, FT-IR, Raman spectra, and SSNMR results indicate that further increased B atoms prefer to connect with Si and Al rather than Yb. Consequently, the above parameters are basically unchanged. Based on the results, an intuitive model of structure and properties evolution during the substitution of SiO2 by B2O3 has been established. 相似文献