Measurement of the Metal Surface Acidity/Electronegativity of Pt(110)

In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C₅H₄XNH⁺ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed.     

岩滩水电站由220KV升压为500KV运行

岩滩水电站升压一次成功，本文简要叙述岩滩水电站升压的各项工作和主要设备的安装试验情况。     

750kV输变电设备的国产化能力

文章介绍了750KV输变电设备国产化的进展情况，对750KV变压器，电抗器，互感器，开关设备、避雷器，高压套管和绝缘子等主要设备或部件在国内生产的基础条件，研制生产能力和生产周期进行了介绍。     

一起500kV线路计量点事故隐患的分析与思考

本文简要介绍了500kV某回线计量点验收时发现事故隐患的过程,从电容式电压互感器本身结构出发,详细分析了产生事故隐患的原因、带来的危害等,并由此提出了计量点验收工作的重要性和必要性。     

线性光耦合器LOC110的原理与应用

隔离放大器电路在通信、工业、医疗器械、电源及测试装置等仪器中是十分关键的部件，对整个系统的正常工作非常重要。LOC110是美国CLARE公司生产的线性光耦合器，本文介绍其工作原理及其在隔离放大电路中的应用。     

6 kV变频电缆终端头的制作与安装

本文结合某铝带材热连轧机组现场安装实例，详细介绍6kV变频电缆终端头的制作与安装过程。     

孟加拉HATHAZARI 132kV电缆回流线取舍探讨

针对孟加拉Hathazari 100MW重油发电机组EPC工程132kV电缆现场实际设计、采购和敷设情况,通过理论计算探讨回流线取舍问题。     

220kV线路工程滑坡地质灾害危险性分析

文章介绍了喜德县红莫升压站-鲁基升压站220kV线路工程滑坡地质灾害危险性现状评估和预测评估,确定了评估区内滑坡地质灾害对工程的影响,以及工程建设加剧已有滑坡地质灾害的危险性和自身可能遭受已存在滑坡地质灾害的危险性。据此评估结果,为工程在建设过程中提出了具体的防治处理措施建议。     

Cr3Si／Crl3Ni5Si2金属间化合物合金组织与高温滑动磨损性能的研究

利用水冷铜模激光熔炼炉制得了由初生枝晶Cr3Si和枝晶间Cr3Si／Crl3Ni5Si2共晶组成的金属间化合物合金。利用OM，SEM，TEM，EDS和XRD分析了该金属间化合物的显微组织，在400℃，500℃和600℃条件下测试了其耐磨性能。结果表明，由于Cr3Si和Crl3NisSi2硬度高、原子键合力强、组织细小、均匀，在高温滑动磨损条件下具有优良的耐磨性能。     

Highly Efficient Overall Water Splitting Through Optimization of Preparation and Operation Conditions of Layered Perovskite Photocatalysts

The layered perovskite materials were found to give the high photocatalytic activity in water splitting reaction under UV irradiation, where the electronic structure of perovskite slab constructing the layered structure (the total cation valency) was the most crucial factor to the high photocatalytic activity. Both the excessive cation valency and the layered structure were required for active photocatalysts, while the slab thickness of layered perovskites had an insignificant effect on water-splitting activity. In order to identify key variables that affected photocatalytic activity and to optimize the performance of (110) layered perovskite, La₂Ti₂O₇ was modified by various methods. The optimum amount of loaded nickel had a great effect and the amount depended on the surface area of the perovskite phase. When an alkaline-earth element such as Ba, Sr, and Ca was doped on La₂Ti₂O₇, the photocatalytic activity was enhanced markedly. Introduction of an alkaline hydroxide into the reaction system as an external additive enhanced the activity further showing extremely high quantum yields close to 50%.