Mechanosynthesis of complex oxides and preparation of mixed conducting nanocomposites for catalytic membrane reactors

Nanopowders of LaGaO₃- and LaMnO₃-based complex perovskites (P) and ceria-based fluorites (F) were prepared by mechanosynthesis. Compatible nanocomposites F + P and P + P with mixed ion and electron conducting (MIEC) properties were prepared and sintered at moderate temperatures up to dense ceramics. The obtained materials were studied by means of XRD, SEM, TEM, electrical conductivity measurements, temperature programmed (TP) reduction/oxidation and preliminary estimations of permeability were obtained. A new strategy based on the advantages of the mechanochemical ceramic approach is proposed to design multilayer ceramic membranes for CMR. Casting technology and one-step sintering were used for the production of thin film membranes with MIEC properties on porous substrates. The coarse fraction of as-milled powders from agglomerates with density 70% was used for the porous substrate, and fine fractions of aggregates with sizes <1 μm were used in preparation of composites for thin dense films. Ceria-based composites prepared by the Pechini route and/or mechanochemical method are proposed as materials for protecting thin films.     

Production of perovskite-like La1−xCaxMnO3+δ ferromagnetic thin films by electrochemical reduction

Ferromagnetic and perovskite-like thin films (<1m) of La1–xCaxMnO3+ have been routinely prepared by heat treatment of an amorphous La–Ca–Mn precursor. The precursor was electrodeposited cathodically in the absence of oxygen and water onto polished silver substrates from a nonaqueous solution of the components' nitrates. Analysis by X-ray diffraction and SQUID magnetometry shows these materials exhibit the appropriate structural and magnetic phases indicative of colossal magnetoresistance.     

Interpretation of Temperature-Dependent Resistivity of La–Pb–MnO3: Role of Electron–Phonon Interaction

The present paper deals with the theoretical investigation of temperature-dependent resistivity of the perovskite manganites La_0.78Pb_0.22MnO_3-δ within the framework of the classical electron–phonon model of resistivity, i.e., the Bloch–Gruneisen model. Due to inherent acoustic (low-frequency) phonons (ω_ac) as well as high-frequency optical phonons (ω_op), the contributions to the electron–phonon resistivity have first been estimated. At low temperatures the acoustic phonons of the oxygen-breathing mode yield a relatively larger contribution to the resistivity as compared to the contribution of optical phonons. Furthermore, the nature of phonons changes around T = 215 K exhibiting a crossover from an acoustic to optical phonon regime with elevated temperature. The contribution to resistivity estimated by considering both phonons, i.e., ω_ac and ω_op, when subtracted from experimental data, infers a T^4.5 temperature dependence over most of the temperature range. Deduced T^4.5 temperature dependence of ρ_diff = [ρ_exp − {ρ₀ + ρ_e-ph( = ρ_ac + ρ_op)}] is justified in terms of electron–magnon scattering within the double exchange (DE) process. Within the proposed scheme, the present numerical analysis of temperature dependent resistivity shows similar results as those revealed by experiments     

La0.67-xBixSr0.33MnO3化合物多孔陶瓷样品的微结构与CMR效应

用固相反应法制备了钙钛矿型氧化物La0．67-xBixSr0．33MnO3(x=0，0．1，0．2)多孔陶瓷样品，研究了这些化合物的电磁性质和CMR效应j实验结果显示，Bi有助于晶粒的长大，并使电阻率峰值向低温方向移动。多孔样品的MR主要取决于显微结构，在0-300K温度范围内MR随温度升高单调下降。在较高的温度下观察到了低场磁电阻(LFMR)效应。与多晶致密样品相比，化合物多孔样品的电阻率峰变宽，峰值下降。     

CMR和FMI测井在碳酸盐岩储层评价中的应用

碳酸盐岩储层具有的低孔、各向异性和非均质性强的特点,常使得常规测井解释评价变得困难和不确定。应用MAXIS-500测井系列的成像测井(FMI)可以直观识别地层裂缝,确定裂缝发育状况,获取井旁地层构造等信息;核磁共振测井(CMR)可以提供精确的有效孔隙度、孔隙结构等信息。华北油田的应用实例表明,两种测井技术的有机结合可以确定储集空间类型,物性参数,为碳酸盐岩储层评价提供更精确、直观的方法。     

Extraordinary Transport Behaviors of La0.67Sr0.33Mn1-x Crx O3 (0.00≤ x ≤0.30)

M-T curves, ρ-T curves and MR-T curves of La0.67Sr0.33Mn1-xCrxO3(0.00≤ x ≤0.30) were studied. Experimental results indicate that the substitution of Cr on Mn sites is impotent in driving TC, but with an increase of Cr content, there appear two peaks in resistivity and MR response, thus the temperature range of CMR response is significantly broadened. The extraordinary transport behavior and the abnormal CMR effect could be the results of coexistence and competition of Mn3 -O-Mn4 and Mn3 -O-Cr3 channels.     

Magneto-transport properties of Fe-doped LSMO manganites

Magneto-transport measurements have been performed on La_0.67Sr_0.33Mn_1−xFe_xO₃ (x = 0.0, 0.05 and 0.07) manganites synthesized by solid state route. The overall nature of AC susceptibility is found to be frequency independent. With the substitution of Mn by Fe, the transport properties dramatically change suppressing the double-exchange interaction. This in turn weakens the ferromagnetism and consequently decreases the paramagnetic to ferromagnetic transition temperature (T_c). However, DC electrical resistivity of the samples show board hump at metal-insulator transition temperature (T_MI) in contrary with sharp transition at T_c and T_MI < T_c indicating decoupling of electrical and magnetic properties. Resistivity behavior of these samples can be well explained by the consideration of bond percolation model which is basically developed from effective approximation method.     

铁电性、高温超导电性和庞磁电阻(CMR)效应的共性特征探讨

从结构和相变两个方面探讨了铁电性，高温超导电性和庞磁电阻（CMR）效应的共性，指出这类性质是集体电子行为，是由各种结构层次（晶体结构，电子结构及自旋结构）相互作用，相互耦合共同引起的。     

RTCM与CMR差分电文格式的分析与比较

介绍了差分GPS传输载波相位差分信息的常用电文格式RTCM与CMR,比较了其优缺点,提出了在低带宽的条件下更适合采用CMR格式的结论。     

民用航海雷达占空比在信号分选中的应用

针对民用航海雷达的信号干扰会使舰艇雷达侦察告警设备出现重频分频和虚假信号增批现象的问题,提出一种民用航海雷达脉宽、重复间隔等典型特征参数的定量分析方法。通过对民用航海雷达影响侦察告警设备信号分选进行分析,得出由脉宽和重复周期确定的占空比是信号分选的重要依据,并结合实际问题,在舰载侦察告警设备信号分选处理过程中,选择合适的占空比值来检验雷达信号的真实性。分析结果表明,该方法能够有效地减少民用航海雷达产生的重频分频和虚假信号增批现象。