Etching technique for revelation of plastic deformation zone in low carbon steel

Abstract

In this study, an etching technique to detect the localised plastic deformation behaviour in a low carbon steel was developed. With this technique, etching with Fry solution under ultrasonic vibration was carried out on samples plastically deformed and then heated at 550°C for a certain period of time. The plastic zone was revealed by different degrees of etching in the plastically deformed and non-deformed regions; the plastic zone was found to be only slightly etched, whereas the other region was deeply etched. From the surface offset after etching, the deformation zone was found to be observable even at low magnification, such as 10 times. As the heating duration increased, the plastic zone became clearer. The mechanism for such an etching reaction is discussed on the basis of electrochemical analysis.     

Structural stability and non-catalytic nucleation inhibition effect of Si–Zr–B mould coating on undercooled superalloy melt

Abstract

The investment moulding technique was first adopted to prepare a SiO₂–ZrO₂–B₂O₃ (Si–Zr–B) substrate layer on the inner surface of the mould, by employing SiO₂ glass dust and ZrO₂ powder, SiO₂–ZrO₂ sol, and analytical grade H₃BO₃ as refractory material, binder, and softening agent, respectively. Then using sol–gel processing, seven layers of Si–Zr–B film of the same formula as the aforementioned Si–Zr–B substrate layer were compounded with the substrate layer step by step. After glassing treatment at 850°C for 60 min, this film transformed into a glass lined coating. It was shown from X-ray diffraction analysis that, after holding it at a temperature of 1500°C for 30 min, the amount of crystallinity in the Si–Zr–B coating was about 1–3% (vol.-%). Finally, the undercooling experiment showed that a large undercooling (up to 140 K) was achieved in a DD3 (Ni–Cr–Mo–Al–Ti–Co–W) single crystal superalloy melt in this coated mould. So it is concluded that a Si–Zr–B coating has got a good structural stability at high temperature and provides ideal non-catalytic nucleation inhibition for an undercooled superalloy.     

Thermal characteristics of tubular single lap adhesive joints under axial loads

When an adhesive joint is exposed to high environmental temperature, the tensile load capability of the adhesive joint decreases because both the elastic modulus and failure strength of the adhesive decrease. The thermo-mechanical properties of a structural adhesive can be improved by addition of fillers to the adhesive. In this paper, the elastic modulus and failure strength of adhesives as well as the tensile load capability of tubular single lap adhesive joints were experimentally and theoretically investigated with respect to the volume fraction of filler (alumina) and the environmental temperature. Also the tensile modulus of the filler containing epoxy adhesive was predicted using a new equation which considers filler shape, filler content, and environmental temperature. The tensile load capability of the adhesive joint was predicted by using the effective strain obtained from the finite element analysis and a new failure model, from which the relation between the bond length and the crack length was developed with respect to the volume fraction of filler.     

Hot tearing behaviour of binary Mg–1Al alloy using a contraction force measuring method

Abstract

Hot tearing (or hot cracking) is recognised in the foundry industry as a serious defect. Although it has been investigated for decades, understanding still stands at a qualitative level. In this work, investigations on hot tearing in the binary Mg–1Al (wt-%) alloy have been conducted, using a contraction stress measuring method which shows evidence of good repeatability. The results show that increasing mould temperature decreases hot tearing susceptibility for Mg–1Al due to a decreased cooling rate. The recorded contraction force curves also show that hot cracks initiate under all investigated mould temperatures; however, the crack propagation behaves differently. At lower mould temperatures, the crack propagates very fast, while at higher mould temperatures it propagates slowly. This indicates that a lower cooling rate allows a better chance for the retained liquid to refill the crack. Consequently this leads to partial or complete interruption of crack propagation.     

Initiation of SCC in nickel base alloys in primary PWR environment: studies at Studsvik since mid 1980s

Abstract

Investigations on initiation of primary water stress corrosion cracking (PWSCC) in alloys 600 and 690 in simulated primary pressurised water reactor (PWR) environments, carried out since 1985, are reviewed. A large number of tests, mostly on reverse U bend specimens, some from steam generator tubes from operating PWRs, have been conducted for periods up to 33 000 h (4 years). Most exposures were at 365 or 330°C in either high purity water with hydrogen addition or simulated primary water (representing beginning of cycle conditions). Parameters investigated include: material (composition, heat treatment (mill annealed or thermally treated), carbide distribution, yield strength, grain size, etc.), environmental (hydrogen content, boron–lithium–pH, zinc) and experimental environment control techniques. Although the PWSCC mechanism has yet to be fully explained, these studies provide an overview of important parameters for crack initiation. The present review aims to survey the evidence for PWSCC initiation in nickel base alloys. It is concluded that, within the normal range for operating PWRs, the influence of dissolved hydrogen on initiation is small. However, a weak maximum in crack growth rate is observed at 15–25 ml H₂/kg H₂O; a corresponding minimum in crack initiation time has not been confirmed but cannot be excluded. It is concluded that hydrogen must be reduced to well below 10 ml H₂/kg H₂O to achieve significant benefits. Increasing the Li content from 2–2·5 to 3·5 ppm is shown to reduce crack initiation time by 30–50%. Lithium in the range 2·2–7·5 ppm has little effect on crack growth rate at ～1200 ppm B. Boron appears to have little influence on crack initiation or growth.     

Fibre orientation structures and their effect on crack resistance of injection moulded transverse ribbed plate

Abstract

An extensive study of the fibre orientation structures developed in a transverse ribbed plate during injection moulding, and the use of these structures to investigate the effect of local fibre orientation state on crack initiation resistance, is reported. The fibre orientation results for the ribbed plate, measured using large area image analysis system developed at Leeds University, showed that after an initial settling down period, the central core region, where the fibres are aligned perpendicular to the flow direction, decreased in size monotonically, with an associated monotonic increase in the outer shell regions, where the fibres are aligned preferentially along the injection direction. Interestingly, the level of orientation in the two regions remained almost constant: only the proportions of the two regions were found to change with flow length. Across the plate, close to the gate, the central core region was found to have a lens-like shape, while at the other end of the plate the core was thinner and also consistent in thickness across the sample width. The transverse rib was found to cause little disturbance to the fibre orientation of the base plate. The different proportions of the shell and core regions at different locations over the ribbed plate provided an ideal case to test the proposition of Friedrich that the crack resistance of a short fibre reinforced material depends on the number of fibres that are perpendicular to the crack tip. The impact test results gathered in this way confirmed this hypothesis of Friedrich.     

Probabilistic modelling of fatigue crack initiation from pits and pit clusters in aluminium alloys

Abstract

A numerical model of crack initiation under high cycle fatigue loading from pits is investigated in this paper. A probability based pit growth model, which takes into account the influence of mechanical cyclic load and particle clusters present in alloys, is used for investigations. Critical pit sizes, calculated using linear elastic fracture mechanics principles, are used to determine the probability of crack initiation for different conditions. The results are critically compared to extract an insight on the parameters that control the pit growth behaviour and thereby the fatigue crack initiation.     

Influences of post-weld heat treatment on fatigue crack growth behaviour of strength mismatched HSLA steel welds

Abstract

Welding of high strength low alloy steels (HSLA) involves usage of low, even and high strength filler materials (electrodes) compared with the parent material depending on the application of the welded structures and the availability of the filler material. In the present investigation, the influences of post-weld heat treatment (PWHT) on fatigue crack growth behaviour of under matched (UM), equal matched (EM) and over matched (OM) weld metals has been studied. The base material used in this investigation is HSLA-80 steel of weldable grade. The Shielded Metal Arc Welding (SMAW) process has been used to fabricate the single 'V' butt joints. Centre Cracked Tension (CCT) specimens have been used to evaluate the fatigue crack growth behaviour of the welded joints. Fatigue crack growth experiments have been conducted using servo hydraulic controlled fatigue testing machine at constant amplitude loading (R = 0). From this investigation, it has been found that the fatigue performance of over matched joints is superior compared to under matched and equal matched joints. Moreover, PWHT reduced the magnitude of the tensile residual stress field in the weld region and subsequently enhanced the fatigue performance of the joints irrespective of weld metal strength mismatch.     

Fatigue crack growth under a constant amplitude loading of Al-6061-T6 welds obtained by modified indirect electric arc technique

Abstract

The characteristics of the fatigue crack growth in the base metal, weld metal and heat affected zone (HAZ) were quantified by testing compact type specimens of 6061-T6 welds obtained by the modified indirect electric arc technique. The fatigue crack growth depends on the microstructure imposed by the welding thermal cycle and it was observed that in the HAZ the crack growth rate is lower than that in the weld metal, but higher than that in the base metal. Microhardness maps revealed that this behaviour is due to the formation of a larger plastic zone around of the crack tip produced by loss of hardening. A comparison of fatigue crack growth of weld metal and HAZ for modified indirect electric arc and friction stir welding shows that the weld metal produced by friction stir welding exhibits better resistance to crack propagation, but both processes behaved similarly in the HAZ.     

Effect of molybdate ions as corrosion inhibitors of iron in neutral aqueous solutions

Abstract

The effect of molybdate ions on the corrosion of Fe in neutral solutions was investigated by electrochemical measurements (dc polarisation and impedance spectroscopy) together with gravimetric determinations. Studies were conducted in solutions containing sodium hydrogen/sodium sulphate salts with molybdate concentrations ranging between 10^?4 and 10^?2M at pH 8 and 9. Mass loss measurements indicated that about 10^?3M of molybdate was necessary in order to inhibit completely the corrosion of Fe at room temperature. The potentiodynamic polarisation and electrochemical impedance studies gave indications about the mechanism of action of the MoO^2?₄ ion. They also showed that the inhibiting effect of the oxyanion is increased in the presence of dissolved oxygen. Spontaneous passivation of the corroding Fe electrode could happen only in the presence of dissolved oxygen at concentrations greater than 10^?4M. However, passivity was also obtained under potentiodynamic polarisation conditions in deaerated solutions. The effect of the oxygen was attributed to displacement of the corrosion potential into the region of selfpassivation of the steel. Finally, the results indicated that the corrosion inhibition of Fe in neutral solutions by molybdate ions was largely insensitive to pH over the range from 8 to 9.