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1.
ABSTRACT In this study, effect of calcium and gypsum on scheelite and fluorite was investigated using sodium oleate as collector. Micro-flotation and contact angle results showed that the adsorption of calcium could inhibit the hydrophobicity of scheelite and fluorite. Moreover, sulfate could enhance the inhibition. FT-IR results showed that calcium could be priori precipitated into calcium oleate and adsorb on mineral surface. The adsorption of calcium could increase the scheelite potential to IEP, while it showed limited effect on fluorite potential. However, the interaction of calcium on scheelite and fluorite in gypsum solution was more complex than that in calcium solution. 相似文献
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Tomi Gominek Andrej Lubej Ciril Pohar 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(8):939-947
Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg2+ and Fe2+ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg2+ and Fe2+ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d50) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry 相似文献
4.
膏盐岩地层地质特征与录井技术 总被引:2,自引:0,他引:2
石油勘探实践和研究结果表明,许多油气藏的形成都与膏盐岩地层有关,也常与膏盐岩地层伴生,成功钻穿膏盐岩地层是钻井难题之一,录井技术成为钻进安全监测、膏盐岩地层准确预报的重要手段。针对上述情况,介绍了膏盐岩地层的主要类型、沉积模式以及与油气的关系,归纳总结了膏盐岩地层的录井技术经验,包括:在随钻录井过程中熟悉地质设计与邻井资料;在没有预测钻遇膏盐岩地层的情况下,通过钻井液中Cl^-的变化判定是否钻遇膏盐岩地层;预计钻遇膏盐岩地层时,使用饱和盐水钻井液;钻遇膏盐岩地层后观察盐岩是否以岩屑形式返出;同时,把握膏盐岩地层的岩性、岩性组合、层位、顶底界和厚度是非常重要的。通过S1井实例分析,论述了在膏盐岩地层中钻进时,防卡、防漏是录井人员监测和预报的重点。 相似文献
5.
Observation and Analysis of Gypsum Particleboard using SEM 总被引:2,自引:0,他引:2
冯谦 《武汉理工大学学报(材料科学英文版)》2007,22(1):44-47
The microstructures of gypsum board and gypsum particleboard were observed by SEM. The effects of retarder and waterproof agent on the shape and the average dimension of the gypsum crystal were discussed. The mechanism was investigated as well. Four typical instances, i e, the gypsum crystal shape, the gypsum combined with particles on the particles surface, the gypsum combined with particles on the wood cross section and the gypsum combined with particles inside the wood cell cavity were selected and observed. Furthermore, the agglomeration and cementation mechanism between gypsum and particle were studied. 相似文献
6.
亚硫酸钙氧化为石膏的研究 总被引:6,自引:0,他引:6
进行了亚硫酸钙氧化为二水石膏的研究 ,考察了初始 p H值、反应温度、空塔气速、固含量和停留时间对氧化率的影响 ,给出了适宜的反应条件 .在这些条件下 ,氧化率达 96 %以上 相似文献
7.
本文提出采用高分子有机材料配合,生产石膏制品防水防潮剂的生产方法和工艺。该剂还可以应用到氧化镁系列板材,同时提出开发珠光或彩色防水防潮剂,能达到满足的装饰效果,值提开发推广。 相似文献
8.
Nano SiO2 was filled into gypsum particleboard. Effect of the amount of nano SiO2 particles filled, ultrasonic dissipating duration and treating the nano particles with different coupling agents on the mechanical properties of the board were studied respectively. The results show that nano SiO2 is helpful for the improvement of the properties. Adding 3%(mass fraction) nano SiO2 is the best for the improvement of both modulus of rupture(MOR) and modulus of elasticity(MOE) of the boards formed at 30 ℃ or 40 ℃. For the boards formed at 30 ℃, their MOR and MOE can be improved by 8.77% and 12.24%, and MOR and MOE of the boards formed at 40 ℃ can be improved by 44.44% and 108.38%.3% is also the best addition proportion to improve internal bond(IB) of the boards formed at 30 ℃, while 5% is the best for that of the boards formed at 40 ℃. At room temperature, dissipating nano Si02 into flake by ultrasonic has better effect on the properties of the final products. Through ultrasonic treating for 1 h and the best treating duration, the MOR and MOE can be increased by 41.99% and 47.80%. In addition, different coupling agents have different effects on the final properties too, and silane coupling agent KH570 is better for the improvement of properties of the boards formed at room temperature. 相似文献
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10.
Recent laboratory research has indicated that coal fly ash derived from subbituminous and bituminous type coals is a sink for atmospheric mercury (Hg), however lignite-based ash was found to emit Hg to the air. Solids collected from systems with components that enhance Hg removal (i.e. activated carbon injection (ACI), flue gas desulfurization (FGD), and selective catalytic reduction (SCR) or selective non-catalytic reduction (SNCR)) may have higher Hg concentrations and therefore a higher potential for Hg release. For this study we investigated the potential for Hg release to the air and water from coal combustion products (CCPs) collected from coal-fired units with FGD equipment, SCR and SNCR equipment, and sorbent injection for Hg removal. In the laboratory study, most dry samples acted as sinks for atmospheric Hg in the dark at 25 °C. When exposed to light or increased temperature (45 °C), deposition of Hg to the fly ash substrates in most cases continued but decreased. Wet FGD samples emitted Hg. However, they became a sink for atmospheric Hg or exhibited low Hg emission rates when dried. Mercury flux in the dark at 25 °C was correlated with fly ash carbon content (LOI). Most liquid extracts derived using the synthetic precipitation leaching procedure (SPLP EPA method 1312) had very low Hg concentrations (<13 ng/l). 相似文献