Performance of compression/absorption hybrid refrigeration cycle with propane/mineral oil combination

This paper discusses the feasibility of a vapor compression/absorption hybrid refrigeration cycle for energy saving and utilization of waste heat. The cycle employs propane as a natural refrigerant and a refrigeration oil as an absorbent. A prototype of the cycle is constructed, in which a compressor and an absorption unit are combined in series. The performance of the cycle is examined both theoretically and experimentally. Although the solubility of the propane with the oil is not enough as a working pair in the absorption unit, the theoretical calculation shows that the hybrid cycle has a potential to achieve a higher performance in comparison with a simple vapor compression cycle by using the waste heat. In the experiment, the prototype cycle is operated successfully and it is found that an improvement of an absorber is necessary to achieve the good performance close to the theoretical one. The application of an AHE (absorber heat exchanger) can reduce the heat input to a generator. Further examinations on some other combinations of refrigerant/refrigeration oil and additives are desirable.     

Study on high performance ice slurry formed by cooling emulsion in ice storage (discussion on adaptability of emulsion to thermal storage material)

This study focuses on an emulsion as a new thermal storage material for ice storage. Two types of emulsions were formed using an oil–water mixture with a small amount of additive. A silicone, light and lump oils were used. The water contents of the emulsions were 70, 80 and 90%. The additive was an amino group modified silicone oil. No depression of freezing point was observed for the emulsions because of their hydrophobic properties. In order to determine the structure of the emulsions, their electrical resistances were measured. Moreover, components of the liquids separating from the emulsions were analyzed. The results indicated that one emulsion was a W/O type emulsion, while the other was an O/W type. Finally, adaptability of the two emulsions to ice storage was discussed, it was concluded that a high performance ice slurry could be formed by the W/O type emulsion.     

Flow boiling heat transfer of carbon dioxide with PAG-type lubricating oil in pre-dryout region inside horizontal tube

A flow boiling heat transfer model for horizontal tubes is proposed for CO₂ with entrained polyalkylene glycol (PAG) type lubricating oil in the pre-dryout region. A general power law-type model with a power number of 3 is used together with the average thermodynamic properties of the CO₂–oil mixture. A convective enhancement factor (F) is recommended according to the relationship between the Lockhart–Martinelli parameter and the ratio α_tp/α_l, which was obtained based on previous experimental results for CO₂ and oil. A new suppression factor (S) is introduced that comprises a suppression term for forced convection and oil concentration term for bubble generation. A comparison of six correlations showed that the proposed correlation can depict the influence of the mass and heat fluxes on both nucleate and convection boiling reasonably well.     

An experimental investigation and modelling of flow boiling heat transfer of isobutane-compressor oil solution in a horizontal smooth tube

Experimental results of local heat transfer coefficients for the boiling of working fluids (solutions of R600a with mineral naphthenic oil ISO VG 15) in a smooth tube with a small diameter (5.4 mm) are presented. The experiments have been performed in the following ranges: for the inlet pressure from 65.7 kPa to 82.2 kPa, for the heat flux from 2500 to 3300 W m⁻², and for the mass velocity of the working fluid from 11.90 to 15.99 kg m⁻² s⁻¹). The quantitative estimation in reduction of the heat transfer coefficient of the wetted surface in the evaporator at a high oil concentration in the mixture is examined. The influence of heat flux and mass velocities on the values of the local heat transfer coefficients is analyzed. The equation for the modelling of the local heat transfer coefficient for boiling of an isobutane/compressor oil solution flow in the tube is suggested.     

Ammonia evaporation in a mixed configuration chevron plate heat exchanger with and without miscible oil

An experimental study was conducted to determine the effects of miscible lubricant oil on evaporation of ammonia in a vertical chevron plate heat exchanger. The heat exchanger was configured in a U-type counter flow arrangement with mixed (30°/60°) chevron plate configuration. Experiments were carried out for four saturation temperatures ranging from −25 °C to −2 °C for a fixed ammonia mass flux rate of 6.5 kg m⁻² s⁻¹ and over a range of heat flux levels resulting in a vapor quality at the heat exchanger exit ranging between 0.5 and 0.9. For a given saturation temperature, experiments were performed for 0%, 3%, 6% and 9% oil concentrations, by volume in ammonia. The oil concentration, exit vapor quality, heat flux and saturation temperature were found to have significant effects on the heat transfer coefficient and pressure drop of ammonia. Based on the experimental data, correlations to estimate two phase Nusselt number and friction factor, generalized for the whole range of oil concentration have been presented.     

Formation of high performance ice slurry by W/O emulsion in ice storage (effective method to propagate supercooling dissolution)

This study focused ice slurry formation in an ice storage system using W/O emulsions with 70 and 80% water contents. Emulsions consisted of a silicone oil–water mixture with a small amount of amino-group-modified silicone oil additive. Ice slurry was formed by cooling the emulsion without ice adhesion to the cooling wall, as water in the emulsion did not directly contact the cooling wall. As the structure of W/O emulsion slowed the propagation rate of supercooling dissolution, voltage and ultrasonic wave were applied to the W/O emulsion to propagate dissolution more quickly and decrease maximum supercooling degree, respectively. Thus, the effects of voltage and ultrasonic wave applications on propagation rate were clarified.     

Experimental investigation of oil retention in air conditioning systems

In air conditioning and refrigeration systems a small amount of oil is carried with the refrigerant and is retained in the system components. Oil retention characteristics in the condenser, evaporator, liquid and suction lines were measured and are presented and discussed here. Refrigerants R22, R410A, and R134a with miscible and non-miscible lubricants were considered to investigate oil retention physics in the widest possible range of transport properties. A parametric analysis in the suction line showed that oil retention depends on the oil mass fraction, vapor refrigerant mass flux, mixture viscosity ratio and orientation of the pipe. In the suction line, an increase in mixture viscosity of about 55% caused a rise in oil retention in the range of 50%, depending on the oil mass fraction. Oil retention in the upward vertical suction line is about 50% higher than in the horizontal line at similar conditions.     

Real-time measurement of mixing ratio of refrigerant/refrigeration oil mixture

The mixing of refrigeration oil with refrigerant in a refrigeration cycle has great influence on cycle performance. A sampling method is the most general way to measure the mixing ratio of refrigerant and refrigeration oil. Since the sampling method is time-consuming and reduces the amount of refrigerant and oil in the cycle, a real-time measurement is desirable. In this study, a refractive index measurement was applied to measure the mixing ratio of refrigerant/oil mixture. A laser displacement sensor was used to detect any change in optical path which results from changes of the refractive index of refrigerant/oil mixture. For the practical application of real-time measurement of the oil circulation ratio (OCR) in the refrigeration cycle, a correlation between the refractive index and the mixing ratio was developed. In addition, the changes of the refractive index in a range of a few percentages of the oil concentration and under subcooled conditions were measured. Finally, a transient measurement of the OCR in a practically operating refrigeration cycle was carried out successfully.     

Continuous ice slurry formation by using W/O emulsion with higher water content

A W/O (water-in-oil) emulsion was made from a water–lamp oil mixture with higher water content and a small amount of an additive of amino group-modified silicone oil, and the emulsion could be changed into an ice slurry by cooling with stirring. By using a new continuous ice formation system proposed by one of the authors of this paper, the ice slurry could be formed continuously and stably in an ice formation vessel made of stainless steel. From the experimental results, the conditions were clarified for realizing continuous ice formation for 10 h without ice adhesion to the cooling wall. Moreover, in order to propagate supercooling dissolution of the emulsion effectively and to decrease viscosity in the ice slurry, voltages were applied to the emulsion and ice slurry formed, respectively, and it was clarified that the voltage impression was effective for both.     

Modeling absorption of pure refrigerants and refrigerant mixtures in lubricant oil

This paper addresses the problem of absorption of refrigerant vapor in a stagnant layer of lubricant oil. The bulk motion of the solute is described in terms of apparent diffusion coefficients that encompass both molecular diffusion and possible macroscopic motion induced by liquid density instability and surface tension. In absorption of refrigerant mixtures, diffusion in the vapor and liquid phases are coupled with a thermodynamic model for interfacial equilibrium. Results are compared with experimental data available in the literature for absorption of several refrigerants in polyol ester oil (POE68). The adequacy of the formulation is assessed in the light of its basic assumptions and performance of the model.