全文获取类型
收费全文 | 2955篇 |
免费 | 153篇 |
国内免费 | 115篇 |
专业分类
电工技术 | 262篇 |
综合类 | 134篇 |
化学工业 | 769篇 |
金属工艺 | 163篇 |
机械仪表 | 91篇 |
建筑科学 | 188篇 |
矿业工程 | 79篇 |
能源动力 | 283篇 |
轻工业 | 194篇 |
水利工程 | 56篇 |
石油天然气 | 93篇 |
武器工业 | 4篇 |
无线电 | 274篇 |
一般工业技术 | 278篇 |
冶金工业 | 83篇 |
原子能技术 | 10篇 |
自动化技术 | 262篇 |
出版年
2024年 | 10篇 |
2023年 | 42篇 |
2022年 | 92篇 |
2021年 | 90篇 |
2020年 | 102篇 |
2019年 | 87篇 |
2018年 | 87篇 |
2017年 | 91篇 |
2016年 | 95篇 |
2015年 | 81篇 |
2014年 | 144篇 |
2013年 | 144篇 |
2012年 | 190篇 |
2011年 | 290篇 |
2010年 | 219篇 |
2009年 | 219篇 |
2008年 | 220篇 |
2007年 | 188篇 |
2006年 | 144篇 |
2005年 | 116篇 |
2004年 | 107篇 |
2003年 | 84篇 |
2002年 | 60篇 |
2001年 | 49篇 |
2000年 | 44篇 |
1999年 | 30篇 |
1998年 | 38篇 |
1997年 | 24篇 |
1996年 | 34篇 |
1995年 | 20篇 |
1994年 | 23篇 |
1993年 | 15篇 |
1992年 | 13篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3223条查询结果,搜索用时 36 毫秒
1.
《International Journal of Hydrogen Energy》2021,46(62):31778-31787
NdSrCo2O5+δ (NSCO) is a perovskite with an electrical conductivity of 1551.3 S cm−1 at 500 °C and 921.7 S cm−1 at 800 °C and has a metal-like temperature dependence. This perovskite is used as the cathode material for Ce0.8Gd0.2O2-δ (GDC)-supported microtubular solid oxide fuel cells (MT-SOFCs). The MT-SOFCs fabricated in this study consist of a bilayer anode, comprising a NiO–GDC composite layer and a NiO layer, and a NSCO–GDC composite cathode. Three cell designs with different outer tube diameters, GDC thicknesses, and NSCO/GDC ratios are designed. The MT-SOFC with an outer tube diameter of 1.86 mm, an electrolyte thickness of 180 μm, and a 5NSCO–5GDC composite cathode presents the best performance. The flexural strength of the aforementioned cell is 177 MPa, which is sufficient to confer mechanical integrity to the cell. Moreover, the ohmic and polarization resistance values of the cell are 0.22 and 0.09 Ω cm2 at 700 °C, respectively, and 0.15 and 0.03 Ω cm2 at 800 °C, respectively. These results indicate that the NSCO-GDC composite exhibits high electrochemical activity. The maximum power densities of the cell at 700 and 800 °C are 0.46 and 0.67 W cm−2, respectively, exceeding those of existing electrolyte-supported MT-SOFCs with similar electrolyte thicknesses. 相似文献
2.
In this study, 0.95?Sr0.7Ba0.3Nb2O6-0.05CaTiO3-x wt% Er2O3 ceramics (SBNCTEx; x?=?0–5) were synthesized using traditional solid-state method, and we investigated the microstructure, energy storage properties as well as the relationship between dielectric breakdown strength and interfacial polarization. As compared with pure 0.95?Sr0.7Ba0.3Nb2O6-0.05CaTiO3 ceramics, the Er2O3 dopants suppressed the grain growth of SBNCTEx, and the doped ones showed the dense microstructure. The secondary phase was found for x?≥?1 according to the EDS results, and the influence of the secondary phase on relative dielectric breakdown strength has also been studied. The dielectric breakdown strength increased from 18.1?kV/mm to 34.4?kV/mm, which is good for energy storage. The energy storage density of 0.28?J/cm3 and the energy storage efficiency of 91.4% were obtained in the SBNCTE5 ceramics. The results indicate that SBNCTE ceramics can be used as energy storage capacitors. 相似文献
3.
《Journal of the European Ceramic Society》2019,39(4):1251-1256
MgAl2-2xMn2xO4 (MAMO) with x = 0-0.12 was synthesized in a single-phase form by solid-state reaction. XRD analysis showed that the samples had the cubic center structure of the Fd-3 m space group. Electrical properties of the samples were studied over the temperature range of 300 K∼1073 K. The results showed that the DC conductivity (σDC) increased from 10−11S/cm at 300 K (MAMO, x = 0) to 10-3S/cm at 1073 K (MAMO, x = 0.12). The equivalent circuit of the complex impedance spectra suggested that the relaxation of charge carriers was of non-Debye type. The conduction was mainly caused by grain boundaries and the capacitance was mainly attributed to polarization. The complex permittivity values (ε’ and ε’’) were increased by two orders of magnitude with the increase in Mn content and temperature over the measured frequency range (1 Hz-1 MHz). Therefore, doping with Mn could be applied to modify the electrical properties of MAMO at high temperature. 相似文献
4.
5.
《Ceramics International》2022,48(2):1889-1897
SiC fiber reinforced ceramic matrix composites (SiCf-CMCs) are considered to be one of the most promising materials in the electromagnetic (EM) stealth of aero-engines, which is expected to achieve strong absorption and broad-band performance. Multiscale structural design was applied to SiCf/Si3N4–SiOC composites by construction of micro/nanoscale heterogeneous interfaces and macro double-layer impedance matching structure. SiCf/Si3N4–SiOC composites were fabricated by using SiC fibers with different conductivities and SiOC–Si3N4 matrices with gradient impedance structures to improve impedance matching effectively. Owing to its unique structure, SiCf/Si3N4–SiOC composites (A3-composites) achieved excellent EM wave absorption performance with a minimum reflection coefficient (RCmin) of ?25.1 dB at 2.45 mm and an effective absorption bandwidth (EAB) of 4.0 GHz at 2.85 mm in X-band. Moreover, double-layer SiCf/Si3N4–SiOC with an improved impedance matching structure obtained an RCmin of ?56.9 dB and an EAB of 4.2 GHz at 3.00 mm, which means it can absorb more than 90% of the EM waves in the whole X-band. The RC is less than ?8 dB at 2.6–2.8 mm from RT to 600 °C in the whole X-band, displaying excellent high-temperature absorption performance. The results provide a new design opinion for broad-band EM absorbing SiCf-CMCs at high temperatures. 相似文献
6.
7.
We investigate the effects of doping and annealing on the dielectric properties of metal ions doped TiO2 ceramics. Colossal permittivity (CP) above 104 was observed in single Nb ion doped TiO2, which was dominated by electron transport related interfacial polarization. Moreover, the CP can be dropped to 120 when simultaneously introducing Mn ion into the sample. The disappearance of CP behaviors maybe due to the multivalence of Mn which would inhibit the reduction of Ti4+ to Ti3+, and thus reduce delocalized electrons. Interestingly, the CP was recovered for the (Nb+Mn) co-doped TiO2 after post-sintering heat treatment in N2 atmosphere. The recovery of CP in the sample after annealing can be ascribed to the semiconducting grain and the insulating grain boundary, according to impedance spectroscopy. We therefore believe that this work can help us understand the mechanism of CP from a new perspective. 相似文献
8.
Effects of thermal and mechanical treatments on a titanium-based conversion coating for aluminium alloys 总被引:1,自引:0,他引:1
The influence of mechanical deformation and heating on the protective performance of a chromium-free conversion treatment for aluminium alloys has been assessed by polarisation and AC impedance measurements. Protection is unlikely to be seriously compromised by typical production operations. 相似文献
9.
Halo effects in rating specific pieces of work, as in educational grading, have received little attention. Grades awarded by 2 independent graders to undergraduate projects were analyzed with a correlated uniqueness model. Grades showed substantial halo despite being awarded by expert assessors at the time of reading the work. There was greater halo between different grades applying to the same section of the project than between grades applying to different sections. Supervisors who had regular contact with the student whose work they were grading showed no more halo than other graders. More reliable graders showed less within-section halo than graders of lower reliability but equal between-sections halo. The halo effects observed cannot be entirely attributable to a unitary general impression. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
10.