Improvement of device performances by thin interlayer in conjugated polymers/methanofullerene plastic solar cell

Recent studies have reported that a thin interlayer between poly(3, 4-ethylene dioxythiophene)-poly(styrene sulfonic acid) (PEDOT: PSS) and an emissive polymer layer leads to a large increase in the performances of polymer light-emitting diodes (PLEDs) by preventing significant quenching of the radiative excitons at the PEDOT: PSS interface; therefore, acting as an efficient exciton-blocking layer. Using the similar idea, a thin interlayer was fabricated between PEDOT: PSS and the active layer of conjugated polymers/methanofullerene composites in a plastic solar cell. The interlayer consisted of a poly(fluorene)-based hole transporter spin-coated directly on top of the PEDOT: PSS layer. The devices with the interlayer exhibited a higher efficiency than in those without the interlayer.     

Synthesis and characterizations of a polyimide containing a triphenylamine derivative as an interlayer in polymer light-emitting diode

Polyimide containing triphenylamine derivative (TPD-PI) was synthesized to prepare a polymer interlayer having insolubility in common nonpolar solvent for light-emitting polymers. N,N′-diphenyl-N,N′-bis(4-aminophenyl)-1,1-biphenyl-4,4′-diamine, as a new triphenylamine-containing diamine monomer, was synthesized by the palladium-catalyzed amination reaction between 4-nitrodiphenylamine and 4,4′-dibromobiphenyl and subsequent reduction of the nitro-intermediate. The TPD-PI was prepared from the synthesized diamine monomer and 4,4′-(hexafluoropropylidene)-diphthalic anhydride by the standard two-step polymerization method, which involved ring-opening polymerization and subsequent cyclodehydration. The structures and properties of the monomer and the resulting polyimide were characterized with ¹H and ¹³C NMR, elemental analysis, gel permeation chromatography, UV-visible spectroscopy, etc. The TPD-PI is readily soluble in aprotic polar solvents such as N-methyl-2-pyrrolidinone and N,N-dimethylformamide and insoluble in nonpolar solvents such as toluene and xylene. The highest occupied molecular orbital (HOMO) level of the TPD-PI was measured to be 5.5 eV by a photoelectron spectrometer in air, and the band gap was calculated as 3.1 eV from the onset of UV-vis spectrum. The polymer light-emitting diode with the thin TPD-PI layer between a hole injection layer and an emitting polymer layer was fabricated to examine the performance of the polyimide as an polymer interlayer. Although the luminous efficiency of the device is lowered by the introduction of the TPD-PI interlayer, the lifetime of the device is improved.     

基于群体智慧的软件开发间层模型及其架构实现

减少或者避免重复劳动是应对软件危机的一个重要方法.对软件重用技术进行研究,以避免重复劳动为目标,提出利用群体智慧的间层模型来试图解决软件危机问题.提出的柠檬框架是间层模型的一个实现,具有一定的实用性.同时柠檬框架也是正在进行的一个项目.     

Effect of interlayer on structure and performance of anode-supported SOFC single cells

To lower the operating temperatures in solid oxide fuel cell (SOFC) operations, anode-supported SOFC single cells with a single dip-coated interlayer were fabricated and the effect of the interlayer on the electrolyte structure and the electrical performance was investigated. For the preparation of SOFC single cells, yttria-stabilized zirconia (YSZ) electrolyte, NiO-YSZ anode, and 50% YSZ-50% strontium-doped lanthanum manganite (LSM) cathode were used. In order to characterize the cells, scanning electron microscopy (SEM) and atomic force microscopy (AFM) were utilized and the gas (air) permeability measurements were conducted for gas tightness estimation. When the interlayer was inserted onto NiO-YSZ anode, the surface roughness of anode was diminished by about 40% and dense crack-free electrolytes were obtained. The electrical performance was enhanced remarkably and the maximum power density was 0.57W/cm(2) at 800 degrees C and 0.44W/cm(2) at 700 degrees C. On the other hand, the effect of interlayer on the gas tightness was negligible. The characterization study revealed that the enhancement in the electrical performance was mainly attributed to the increase of ion transmission area of anode/electrolyte interface and the increase of ionic conductivity of dense crack-free electrolyte layer.     

Pyroelectric properties and X-ray photoelectron spectroscopic study of R.F. magnetron-sputtering-derived PZT thin films deposited on various interlayers

PZT thin films and interlayers were fabricated by the radio frequency (r.f.) Magnetron-sputtering from the Pb_1.1Zr_0.53Ti_0.47O₃, PbO and TiO₂ target. As a result of the XPS depth profile analysis, we can confirm that the substrate temperature affects the oxidation condition of each element of interlayers and the PZT film. Compared to the PZT/Pt structure, the dielectric and pyroelectric properties of PZT thin films inserted by interlayers were measured to a relatively high value. In particular, the PZT/PbO structure had the highest pyroelectric properties (P = 189.4 μC/cm²K; F _D = 12.7×10⁻⁶ Pa^−1/2; F _V = 0.018 m²/C).     

Improved macroblock level rate control for the spatially scalable extension of H.264/AVC

An improved rate control algorithm, designed for scalable video coders incorporating interlayer prediction, is proposed. Firstly, a Rate Distortion (RD) model for interlayer prediction involving the spatial enhancement layers is devised. An optimised Mean Absolute Difference (MAD) prediction model for the spatial enhancement layers that considers both the MAD from the spatial base layer in the same frame and the MAD from the corresponding macroblock in previous frames is also proposed. Simulation results show that the resulting algorithm produces accurate rate control with an average bit rate error of less than 0.26%. Compared with the JVT-W043 default rate control algorithm of the JSVM, the proposed algorithm improves the average PSNR by up to 0.53 dB or reduces the bit rate by an average of 10.95%. Furthermore, the proposed algorithm can be combined with the existing rate control scheme for H.264/AVC, resulting in further improvements.     

High performance films of cellulose butyral derivative having a necklace-like annular structure in the side chains

We fabricated high performance films using cellulose butyral (CB) synthesized from native cellulose. Two-step reactions were adopted to produce the derivative CB, including etherification of cellulose with glycidol in NaOH/urea aqueous solution to yield O-(2,3-dihydroxypropyl) cellulose (DHPC), and butyralization of DHPC. Both DHPC and CB products were easily processed into a thin film by hot-press molding. The butyral modifier significantly improved the tenacity of highly ductile DHPC, by virtue of the possible chain-entangling action of the ring structures in the stretching process. Thereby the film toughness was markedly enhanced. The CB films exhibited excellent optical transparency and a good adhesive property to glass plates. Thus the films may be comparable to commercial poly(vinyl butyral) (PVB) films in optical and mechanical performances and therefore possess a potential applicability as interlayer for laminated glasses.     

Improving weld strength of magnesium to aluminium dissimilar joints via tin interlayer during ultrasonic spot welding

Abstract

Welding of magnesium to aluminium alloys is enormously challenging due to the formation of brittle Al₁₂Mg₁₇ intermetallic compounds (IMCs). This study was aimed at improving the strength of dissimilar joints of AZ31B-H24 magnesium alloy to 5754-O aluminium alloy by using a tin interlayer inserted in between the faying surfaces during ultrasonic spot welding. The addition of tin interlayer was observed to successfully eliminate the brittle Al₁₂Mg₁₇ IMCs, which were replaced by a layer of composite-like tin and Mg₂Sn structure. Failure during the tensile lap shear tests occurred through the interior of the blended interlayer as revealed by X-ray diffraction and SEM observations. As a result, the addition of a tin interlayer resulted in a significant improvement in both joint strength and failure energy of magnesium to aluminium dissimilar joints and also led to an energy saving because the optimal welding energy required to achieve the highest strength decreased from ～1250 to ～1000 J.     

Effects of use of higher strength interlayer and external cooling on properties of friction stir welded AA6061-T6 joints

Although sound AA6061-T6 joints can be produced by friction stir welding, a loss in strength takes place in the weld region. In this study, it was demonstrated that the strength of the nugget could be increased by the use of a higher strength interlayer during friction stir welding. This strength recovery cannot, however, be attainable in the heat affected zone. Although an external cooling was applied during welding in order to increase strength in the heat affected zone, it was not sufficient for achieving the required cooling condition for improved strength.     

复合材料层间增韧机理的有限元分析

在复合材料层间植入韧性夹层,可以有效提高层间韧性,其增韧机理在于夹层可以有效降低纤维层对裂纹尖端的约束,并降低裂纹尖端应力.文中建立层间裂纹的有限元模型,采用数值分析方法,分别计算加入夹层前后裂纹尖端的J积分值、应力强度因子以及裂纹尖端的应力场.计算结果表明,加入夹层后Ⅰ型和Ⅱ型层间裂纹尖端的J积分、应力强度因子和裂尖应力场均显著降低,并指出在夹层和相邻纤维层间界面附近出现的高应力区是造成界面失效的一个原因.