全文获取类型
收费全文 | 173篇 |
免费 | 0篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 10篇 |
综合类 | 1篇 |
化学工业 | 81篇 |
金属工艺 | 2篇 |
机械仪表 | 5篇 |
建筑科学 | 1篇 |
能源动力 | 4篇 |
石油天然气 | 1篇 |
无线电 | 1篇 |
一般工业技术 | 70篇 |
冶金工业 | 1篇 |
原子能技术 | 1篇 |
自动化技术 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2017年 | 7篇 |
2016年 | 4篇 |
2015年 | 9篇 |
2014年 | 4篇 |
2013年 | 23篇 |
2012年 | 10篇 |
2011年 | 20篇 |
2010年 | 8篇 |
2009年 | 9篇 |
2008年 | 5篇 |
2007年 | 4篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 3篇 |
2003年 | 6篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有180条查询结果,搜索用时 140 毫秒
1.
S. Subramanian J. J. Lesko K. L. Reifsnider W. W. Stinchcomb 《Applied Composite Materials》1994,1(4):283-300
In this study, the effect of fiber-matrix interphase on the damage modes and failure mechanisms in (0, 903), cross-ply graphite-toughened epoxy laminates is investigated. Two material systems (designated as 810 A and 810 O) with the same fiber and same matrix, but with different fiber sizings, were used to study the effect of the interphase. The system designated as 810 A contained an unreacted Bisphenol-A (epoxy) sizing, while a thermoplastic polyvinylpyrrolidone (PVP) sizing was used in the 810 O system. Damage accumulation in the cross-ply laminates under monotonic tensile loading was monitored using edge replication, x-ray radiography, acoustic emission, optical and scanning electron microscopy. Results indicate that the fiber-matrix bond strength is lower in the 810 O system compared to the 810 A system. Transverse matrix cracking initiates at a significantly lower stress level in the 810 O laminate. The 810 O laminates also exhibit longitudinal splitting, while the stronger bonding suppress this damage mode in the 810 A laminates. Numerous local delamination occur on the 0/90 interface at the intersection of 0 and 90 degree ply cracks, in the 810 O laminates. These are absent in the 810 A laminates. The failure modes are also different in the two material systems used in this study. The 810 A laminate exhibits a brittle failure, controlled by the local stress concentration effects near broken fibers. In the 810 O laminates, the presence of longitudinal splits result in the reduction of stress concentration effects near fibe fractures. This results in a global strain controlled failure in the 810 O system. It is concluded that the presence of different fiber sizings result in different damage modes and failure mechanisms in the cross-ply laminates used in this study.Research Associate, Research Assistant, Alexander Giacco Professor and Professor respectively. 相似文献
2.
Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capacity signal, due to reversible melting and crystallization. It is proposed that the magnitude of this excess contribution can be used to qualify the polymer/clay interfacial interaction, as it is directly linked to the segmental mobility of the polymer chains in the interphase region, where both the crystalline and amorphous polymer fractions are affected. It is shown that the interfacial interaction strongly depends on the type of clay filler used. These interactions play a key role in the development of specific material properties for the different types of nanocomposites. A simple interphase model for the poly(amide) 6/clay nanocomposites is proposed. 相似文献
3.
Sarabjit Singh Vajinder Singh Sweety Kumari A. Udayakumar V.V. Bhanu Prasad 《Journal of the European Ceramic Society》2021,41(1):130-135
The effect of single-layer pyrocarbon (PyC) and multilayered (PyC/SiC)n=4 interphases on the flexural strength of un-coated and SiC seal-coated stitched 2D carbon fiber reinforced silicon carbide (Cf/SiC) composites was investigated. The composites were prepared by I-CVI process. Flexural strength of the composites was measured at 1200 °C in air atmosphere. It was observed that irrespective of the type of interphase, the seal coated samples showed a higher value of flexural strength as compared to the uncoated samples. The flexural strength of 470 ± 12 MPa was observed for the seal coated Cf/SiC composite samples with multilayered interphase. The seal coated samples with single layer PyC interphase showed flexural strength of 370 ± 20 MPa. The fractured surfaces of tested samples were analyzed in detail to study the fracture phenomena. Based on microstructure-property relations, a mechanism has been proposed for the increase of flexural properties of Cf/SiC composites having multilayered interphase. 相似文献
4.
《International Journal of Hydrogen Energy》2021,46(59):30510-30522
We study the effect of grain size of austenitic and ferritic phases and volume fraction of δ-ferrite, which were obtained in different solution-treatment regimes (at 1050, 1100, 1150 and 1200 °C), on hydrogen embrittlement of high-nitrogen steel (HNS). The amount of dissolved hydrogen is similar for the specimens with different densities of interphase (γ-austenite/δ-ferrite) and intergranular (γ-austenite/γ-austenite, δ-ferrite/δ-ferrite) boundaries. Despite, the susceptibility of the specimens to hydrogen embrittlement, depth of the hydrogen-assisted surface layers, hydrogen transport during tensile tests and mechanisms of the hydrogen-induced brittle fracture all depend on grain size and ferrite content. The highest hydrogen embrittlement index IH = 32%, the widest hydrogen-affected layer and a pronounced solid-solution hardening by hydrogen atoms is typical of the specimens with the lowest fraction of the boundaries. Even though fast hydrogen transport via coarse ferritic grains provides longer diffusion paths during H-changing, the width of the H-affected surface layer in the dual-phase structure of the HNS specimens is mainly determined by the hydrogen diffusivity in austenite. In tension, hydrogen transport with dislocations increases with the decrease in density of boundaries due to the longer dislocation free path, but stress-assisted diffusion transport does not depend on grain size and ferrite fraction. The contribution from intergranular fracture increases with an increase in the density of intergranular and interphase boundaries. 相似文献
5.
In this paper we report on an unclear effect in the IV characteristics of organic light emitting diodes (OLEDs). When the thickness of the emitter layer based on a modified phenyl carbozole triplet host material (TH) in the device is increased, a significant shift of the onset voltage to higher values can be noticed. The voltage shift is not observed if the TH is substituted by an isomer with only minor variation of the molecular structure. In a previous publication we could already show that an electric interface field is necessary to describe the onset voltage behaviour. To find the origin of this interface field in the present publication the two isomers are characterized and the band alignment at the interfaces to the emitter layer is investigated using photoelectron spectroscopy. The interface energy diagrams have been measured on stepwise prepared model interfaces. A further simplification of the bipolar to a hole only device stack proofs, that band bending at the hole injecting interface to the TH layer is the origin of the interface field. In contrast an entire flat band situation is measured in case of the device using the other isomer showing no onset voltage shift. 相似文献
6.
Y.M. Lau I. Roghair N.G. Deen M. van Sint Annaland J.A.M. Kuipers 《Chemical engineering science》2011,(14):48
The present paper describes an Euler–Lagrange model utilizing a drag closure derived from direct numerical simulations (front-tracking model) for (i) single isolated bubbles and (ii) bubbles rising in bubble swarms, expressed as a function of the local gas fraction. The model is applied to the prediction of an air/water system in a bubble column and for which experimental data is available. The effect of variation in size of the mapping window for the interphase coupling between the Eulerian and Lagrangian framework is investigated for both closure relations. It is found that the drag closure as a function of the local gas fraction is an improvement over the use of the drag closure for isolated single bubbles for the prediction of bubbly flow. 相似文献
7.
Biopolymer based composites are designed using glass–silica reinforcement. Surface etching of spherical glass–silica particles is performed using chemical and physical treatments. In particular, treatment with hydrofluoric acid proved to be efficient to achieve acceptable anchoring effect. Experimental testing of thermomoulded composites confirms that samples with chemically modified microbeads have improved mechanical properties, irrespective of phase content. A quantitative evaluation of the improvement of the starch/glass–silica interphase properties is achieved using a finite element model. Generation of typical microstructures is used to simulate phase arrangement and interphase properties. Microstructures are meshed taking into account the interphase region. Finite element results indicate that for all samples, interphase Young’s modulus is lower than those of the intrinsic materials. The thickness weighted interface modulus increases for composites where the mechanical adhesion is improved using HF chemical treatment. 相似文献
8.
Surface topographical effects on the mechanical behavior of interlocking multi-stepped double scarf adhesive joints under tensile load were studied. For this purpose, finite element analysis (FEA) of the joint geometry at 10 different step angles was carried out. In the second stage, the effects of substrate voids and adhesive delaminations on the interfacial strength were studied for the scarf angle of 32.2° by FEA simulation as well as experimentally. For the cases of the missing steps (voids) and delamination (absence of bonding induced by release agent) the ratios of maximum stresses (principal, von Mises, normal, shear and transverse) between the completely bonded and altered (void or delaminated) joints were compared with the failure load ratios for the same joints to interpret the mechanism of failure. The results revealed that except for the normal stress, the maximum stress ratios reach a maximum value and then decrease with increasing scarf angle. FEA analysis with the voids showed that the strength of the joint not only depends on their size, but also on their location in the joint. When the experimental results were compared with the FEA using the stress ratio between the unmodified (completely bonded) and modified (void or disbond) cases, the results indicated that the normal stress dominates the failure behavior of the 32.2° scarf angle joint. Comparison of the experimental results for the void, and disbond cases revealed that the disbond cases can possess higher joint strength in comparison to the void cases. This finding could not be predicted by FEA, and was attributed to the presence of friction at the interface subsequent to delamination. 相似文献
9.
Fibre/matrix interphase has a dramatic influence on the composite performances. For the best understanding of interfacial phenomena, sizing has been characterized “in situ” by dynamic mechanical analysis, and sizing extract part, by different techniques. To know sizing impact on interphase nature and properties in the composite, four types of samples have been realized: three composites, which have been elaborated according to the technique of vacuum molding and differed by sizing state, and neat resin samples. The dynamic mechanical analysis (DMA) has allowed us to study both these composites and their interphases. Moreover, micro-thermal analysis has been a good technique for interphase investigation in our composites. 相似文献
10.