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利用磁控溅射方法在N2气氛下制备出了LiSiPON电解质薄膜,研究了薄膜的结构、形貌和组成,着重探讨了薄膜中N含量对薄膜离子电导率的影响。随着N2分压的增加,薄膜中的N含量逐渐增加,0.53Pa时达到最大,超过此分压N含量又逐步下降。随着薄膜中N含量的增加,离子电导率提高,最大达10.4×10^-6S/cm(室温),这对固态电解质薄膜来说是足够了。为了测量电解质薄膜的电化学稳定性,组装了LiCoO2/LiSiPON/SnO2薄膜电池,显示出了良好的循环性能。 相似文献
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The LiSiPON electrolyte films were prepared by magnetron sputtering method with different N2working pressure. The structure, morphology, composition and the relationship between ionic conductivity and N content were studied in detail. The result showed that N content in the films depended on N2partial pressure. With the N2 partial pressure increasing, N content increased firstly and gained a maximum values then decreased. N content in the LiSiPON films affected the ionic conductivity of the films.The ionic conductivity of the films increased with the N content increasing, and could reach a maximum value 10. 4× 10-6S/cm. 相似文献
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XING Guang-jian SHEN Wan YANG Zhi-min MAO Chang-hui DU Jun 《材料研究与应用》2005,(3):462-466
The LiSiPON electrolyte films were prepared by magnetron sputtering method with different N2working pressure. The structure, morphology, composition and the relationship between ionic conductivity and N content were studied in detail. The result showed that N content in the films depended on N2partial pressure. With the N2 partial pressure increasing, N content increased firstly and gained a maximum values then decreased. N content in the LiSiPON films affected the ionic conductivity of the films.The ionic conductivity of the films increased with the N content increasing, and could reach a maximum value 10. 4× 10-6S/cm. 相似文献
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1IntroductionSolid electrolyte fil ms have been attracted much attention in their application to electronic devices,high power density batteries due to their higher ionic conductivity,lower electronic conductivity andloweractivation energy[1,2].Li-ion conducting,inorganic,solid electrolyte fil ms have been used for fabricatingall-solid-state thin fil mlithiumbatteries and several kinds of materials for electrolyte fil ms have been stud-ied nowadays.Kanehori[3]reported the fabrication of all-so… 相似文献
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