单晶高温合金定向凝固过程中初生碳化物的上浮现象SCIEI

本文在一种抗热腐蚀单晶镍基高温合金平面及胞状液-固界面定向凝固条件下,发现了初生碳化物(TiC)的上浮现象并分析了其形成原因。     

Oxidation Behavior of a Single-Crystal Ni-Base Superalloy in Air—II: At 1000, 1100, and 1150°C

The oxidation behavior of a single-crystal (SC) Ni-base superalloy was studied over the temperature range from 1000–1150°C and analysed by TGA, XRD, EDAX, and SEM. The results indicated that the SC Ni-base superalloy exhibited parabolic oxidation kinetics, which were controlled by the growth of the inner -Al₂O₃ layer. A mixed scale formed on the SC Ni-base superalloy after prolonged oxidation. The scale consisted of an outer layer of spinel, a sublayer of mainly -Al₂O₃ with small amount of spinel adjoined by a very thin and even discontinuous layer of CrTaO₄-rich oxide, and an inner -Al₂O₃ layer. The inner -Al₂O₃ layer provided good protection. No internal oxides or nitrides were observed below the inner -Al₂O₃ layer after 1000 hr at 1000°C, and after 200 hr at 1100 and 1150°C.     

介质条件对核电用镍基合金传热管SCC的影响

综述了环境因素，包括温度、ＰＨ值、溶解氧、氯离子、氢、荷性碱含硫化合物以及铅等对压水堆核电站蒸汽发生器传热管用基合金材料（８００、６００、６９０合金）和腐蚀破裂（ＳＣＣ）敏感性的影响。     

DD3单晶镍基合金蠕变—疲劳及寿命预测

从应变范围区分法(SRP),应变能区分法(SEP)的有关概念出发,研究DD3单晶镍基合金拉—拉应力状态下的蠕变—疲劳性能和保持时间的影响,并对其进行了定量计算;同时,用应变能区分法的数值法(SEP—NCM)实现对拉—拉应力状态下蠕变—疲劳的寿命预测。     

Application of High Temperature Corrosion-Resistant Materials and Coatings Under Severe Corrosive Environment in Waste-to-Energy Boilers

Corrosion-resistant materials (CRMs) and coatings are key technologies to increase power generation efficiency and reduce maintenance in waste-to-energy (WTE) plants. Corrosion environment became severe as steam temperatures have increased. The steam condition of more than 400 °C/3.9 MPa became possible in WTE boilers by using highly durable corrosion-resistant coatings, such as thermal spray of Al/80Ni20Cr alloy, HVOF-sprayed NiCrSiB alloy, Alloy 625 weld overlay for waterwall tubes and also superheater tubes. Also, the use of 310S type stainless steels and high Cr-high Mo-Ni base and high Si-Cr-Ni-Fe alloys have progressed because of a better understanding of corrosion mechanisms. Furthermore, high durability coatings using cermet and ceramic materials were applied to high temperature superheaters. This paper describes the major developments and the application of CRMs and coating technologies in the last 30 years in WTE plants, the corrosion mechanisms of alloys, the deterioration mechanisms of spray coating layers, and future subjects for the development of corrosion-resistant materials and coatings.     

镍基单晶合金枝晶典型区域相成分最优化测算法

建立了用于测算镍基单晶高温合金枝晶典型区域相成分的最优化数学模型.根据电子探针对枝晶典型区域成分的测定结果,运用BFGS拟Newton法及CONSTR约束优化算法,可以计算枝晶各典型区域中γ和γ＇相成分.以镍基单晶合金CMSX-2和CMSX-4为对象,对优化测算结果进行了分析,证实了该方法的可行性.     

细晶处理对镍基合金疲劳蠕变交互作用行为的影响

本文研究了两种晶粒度的GH 698合金在700℃疲劳蠕变交互作用下的断裂寿命和形变行为.结果表明:在疲劳蠕变应力交互作用下的断裂寿命可以分成F,FC和C三个区.在FC及C区,交变应力的存在明显地阻碍蠕变形变过程,提高了断裂寿命.细晶处理后使这种阻碍作用加强,断裂寿命提高幅度变大.在大应力的疲劳区进行细晶处理,反而使合金寿命降低.     

考虑热不协调性的镍基单晶合金细观力学分析SCIEI

基于镍基单晶合金的细观结构特征，本文建立两个微胞模型对热不协调性作了系统的模型计算和分析．微胞模型１是以一个γ和γ’为考察对象，微胞模型２是以多个γ和γ’为考察对象，详细的分析表明，这两个模型有一定的等效性，但模型２可分析边界条件更宽的情况．基于微胞模型，对两相合金的临界分切应力进行了分析，结果表明，宏观临界分切应力可用考虑热不协调性的有限元法来处理，所得结果还可推广到较大的γ’相体积分数ｆ的情况．考察了热不协调性对回火状态时γ’形状变化的影响，初步的定量分析表明，热内应力是γ’粗化的一个主要驱动力．     

Joining alumina to inconel 600 and UMCo-50 superalloys using an Sn10Ag4Ti active filler metal

Alumina ceramics were brazed to Inconel 600 and UMCo-50 superalloys at 900 °C for 10 min using an Sn10Ag4Ti active filler metal. The brazing filler showed good wettability on alumina and superalloys. The flexural strengths were 69 and 57 MPa for alumina/Inconel 600 and alumina/UMCo-50 joints, respectively. In both cases, the brazed specimens fractured along the Sn10Ag4Ti/superalloy interfaces after four-point bending tests. Electron probe microanalysis (EPMA) elemental mapping revealed that the Ni of Inconel 600 and the Co of UMCo-50 dissolved into Sn10Ag4Ti filler metal, which serves to reinforce the weak Sn10Ag4Ti matrix.     

镍基高温合金真空感应熔炼脱氮的研究

研究了采用CaO坩埚真空感应熔炼镍基高温合金过程中的脱氮行为.试验表明在精炼过程中加Al对脱氮有促进作用;加Ti则对脱氮有明显不利影响;提高熔炼时的真空度是促进脱氮的有力措施.