全文获取类型
收费全文 | 8126篇 |
免费 | 353篇 |
国内免费 | 60篇 |
专业分类
电工技术 | 198篇 |
综合类 | 298篇 |
化学工业 | 1607篇 |
金属工艺 | 211篇 |
机械仪表 | 1861篇 |
建筑科学 | 308篇 |
矿业工程 | 191篇 |
能源动力 | 915篇 |
轻工业 | 211篇 |
水利工程 | 71篇 |
石油天然气 | 602篇 |
武器工业 | 29篇 |
无线电 | 148篇 |
一般工业技术 | 1153篇 |
冶金工业 | 380篇 |
原子能技术 | 53篇 |
自动化技术 | 303篇 |
出版年
2024年 | 21篇 |
2023年 | 61篇 |
2022年 | 147篇 |
2021年 | 206篇 |
2020年 | 179篇 |
2019年 | 101篇 |
2018年 | 106篇 |
2017年 | 130篇 |
2016年 | 163篇 |
2015年 | 224篇 |
2014年 | 593篇 |
2013年 | 381篇 |
2012年 | 611篇 |
2011年 | 750篇 |
2010年 | 449篇 |
2009年 | 510篇 |
2008年 | 410篇 |
2007年 | 514篇 |
2006年 | 564篇 |
2005年 | 448篇 |
2004年 | 352篇 |
2003年 | 345篇 |
2002年 | 266篇 |
2001年 | 179篇 |
2000年 | 190篇 |
1999年 | 118篇 |
1998年 | 108篇 |
1997年 | 91篇 |
1996年 | 58篇 |
1995年 | 66篇 |
1994年 | 37篇 |
1993年 | 23篇 |
1992年 | 27篇 |
1991年 | 27篇 |
1990年 | 29篇 |
1989年 | 15篇 |
1988年 | 11篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有8539条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(11):6975-6985
A technology for cyclic generation of hydrogen and oxygen using electrodes made of variable valency material that does not need the use of separating ion-exchange membranes is presented. The technological solution enables to fabricate electrolyzers for uninterrupted producing high-pressure hydrogen with reduced energy intensity of the production. The total work for compressing 1 m3 of hydrogen and 0.5 m3 of oxygen has been estimated. Results of investigation of influence of discrete supply of DC current to the electrolysis cell, in order to improve the processes of gas evolution and to simplify the power systems of the electrolysis plant, have been considered. There is also considered an electrolysis installation equipped with a thermosorption compressor in which LaNi5 is used as a hydride-forming compound. The comparative characteristics of the developed electrolyzer and the currently used hydrogen generators are given. 相似文献
2.
《Ceramics International》2022,48(14):20062-20069
Photocatalytic N2 fixation is a promising and sustainable manufacturing process of ammonia (NH3); however, the NH3 production rate by this method is very low, thus severely restricting further application of this sustainable technology. Therefore, developing an efficient photocatalyst for N2 fixation under mild conditions is urgently required. Herein, ferroelectric Bi2WO6 materials with different surface oxygen defects were prepared, and the concentration of corresponding defects was controlled by adjusting the thermal reduction time. The abundant oxygen defects in Bi2WO6 can provide more reactive sites to promote the effective adsorption of N2, and the photogenerated charge carrier can be efficiently separated benefiting from the internal electric field. These would weaken the N2 triple bond and reduce the activation energy barrier for the conversion of N2 to NH3 under mild conditions. In the absence of sacrificial agents and cocatalysts, the optimized Bi2WO6 with oxygen defects shows an indigenous NH3 yield of 132.175 μmol·g-1·L-1·h-1, which is more than two times higher than that of the original Bi2WO6. Surprisingly, the Bi2WO6 with oxygen defects produced more than eight times NH3 (471.13 μmol·g-1·L-1·h-1) than that of the original Bi2WO6 when assisted by an external magnetic field, thus providing a new perspective for further enhancing the N2 fixation performance. 相似文献
3.
《International Journal of Hydrogen Energy》2019,44(11):5189-5202
Independent hydrogen production from petrochemical wastewater containing mono-ethylene glycol (MEG) via anaerobic sequencing batch reactor (ASBR) was extensively assessed under psychrophilic conditions (15–25 °C). A lab-scale ASBR was operated at pH of 5.50, and different organic loading rates (OLR) of 1.00, 1.67, 2.67, and 4.00 gCOD/L/d. The hydrogen yield (HY) progressed from 134.32 ± 10.79 to 189.09 ± 22.35 mL/gMEGinitial at increasing OLR from 1.00 to 4.00 gCOD/L/d. The maximum hydrogen content of 47.44 ± 3.60% was achieved at OLR of 4.0 gCOD/L/d, while methane content remained low (17.76 ± 1.27% at OLR of 1.0 gCOD/L/d). Kinetic studies using four different mathematical models were conducted to describe the ASBR performance. Furthermore, two batch-mode experiments were performed to optimize the nitrogen supplementation as a nutrient (C/N ratio), and assess the impact of salinity (as gNaCl/L) on hydrogen production. HY substantially dropped from 62.77 ± 4.09 to 6.02 ± 0.39 mL/gMEGinitial when C/N ratio was increased from 28.5 to 114.0. Besides, the results revealed that salinity up to 10.0 gNaCl/L has a relatively low inhibitory impact on hydrogen production. Eventually, the cost/benefit analysis showed that environmental and energy recovery revenues from ASBR were optimized at OLR of 4.0 gCOD/L/d (payback period of 7.13 yrs). 相似文献
4.
《International Journal of Hydrogen Energy》2020,45(1):1151-1157
The paper presents a calculated analysis of the equilibrium emission of nitrogen oxides on the exhaust of carburetor and diesel internal combustion engines. The temperature of fuel oxidation is assumed to be 1,400 °C while the pressure for carburetor and diesel engines is assumed to be 60 atm and 80 atm respectively. The studies have been carried out for natural and synthetic fuels such as hydrogen, ethanol, methanol, petroleum, diesel fuel and methane at the excess air coefficient corresponding to the fuel oxidation temperature of 1,400 °C. In the paper, the method for calculating the equilibrium composition based on the equilibrium constant and mass conservation equations has been applied. It is shown that with an increase in pressure from 1 atm to 60 atm for carburetor engines and up to 80 atm for diesel engines, the reaction of nitrogen dioxide formation may shift towards an increase in NO2. The formation of NO may be not affected by the increase in pressure by virtue of the fact that the reaction proceeds without changes in the amount. It has been determined that NO is the major atmospheric pollutant. However, it would be advisable to use more extensively the fuels characterized by the lowest output of nitrogen dioxide (methane and methanol), since nitrogen dioxide (NO2) related to the 2nd hazard class is appeared to be the most dangerous to humans. It has been revealed that the reduction in oxidation temperature using hydrogen as a fuel for electrochemical current generators may allow reducing nitrogen oxide emissions by more than an order of magnitude as compared to the best results for ICE. 相似文献
5.
大型往复式压缩机功率大、占地面积大,管道振动问题也更为突出。笔者结合实践经验,对大型往复式压缩机的配管设计进行探讨,说明了平面布置与管道防振设计的密切关系,并介绍了管道防振设计的方法和步骤,以及相对简单的复杂管系气柱固有频率的转移矩阵计算方法。 相似文献
6.
7.
8.
Freelance 2000 DCS在轴流机上的应用 总被引:1,自引:1,他引:0
简要介绍了Freelance 2000 DCS的功能特点以及轴流机的控制要求.结合轴流机的控制特点,用Freelance 2000 DCS对原模拟电子系统进行改造,实现并改进了轴流机流量-静叶位置调节、防喘振控制、逻辑控制、状态监测、信息管理等功能。改造后的系统可靠性高、技术先进、信息管理功能强,其设计思想和方法均可供石化企业大型压缩机控制系统的设计和改造借鉴。 相似文献
9.
10.
介绍了中国石化茂名分公司 2 .0Mt/a渣油加氢脱硫装置中的 4M80 30 /2 2 2 0 0 BX型新氢压缩机的特点、技术特征及标定情况。采用国际通用标准对压缩机气体组成、容积流量、轴功率、进排气压力和进排气温度等指标进行了测定。标定表明 ,该机组设计方案合理 ,运转平稳 ,性能指标达到设计要求 ,较好的满足了工艺操作的需要 相似文献