Investigation of corrosion properties with Ni–P/TiNO coating on aluminum alloy bipolar plates in proton exchange membrane fuel cell

Aluminum alloy bipolar plates have unique application potential in proton exchange membrane fuel cell (PEMFC) due to the characteristics of lightweight and low cost. However, extreme susceptibility to corrosion in PEMFC operation condition limits the application. To promote the corrosion resistance of aluminum alloy bipolar plates, a Ni–P/TiNO coating was prepared by electroless plating and closed field unbalanced magnetron sputter ion plating (CFUMSIP) technology on the 6061 Al substrate. The research results show that Ni–P interlayer improves the deposition effect of TiNO outer layer and increase the content of TiN and TiO_xN_y phases. Compared to Ni–P and TiNO single-layer coatings, the Ni–P/TiNO coating samples exhibited the lowest current density value of (1.10 ± 0.02) × 10^?6 A·cm^?2 in simulated PEMFC cathode environment. Additionally, potential cyclic polarization measurements were carried out aiming to evaluate the durability of the aluminum alloy bipolar plate during the PEMFC start-up/shut-up process. The results illustrate that the Ni–P/TiNO coating samples exhibit excellent stability and corrosion resistance.     

Micro assembly injection moulding

Injection moulding is established as one of the most common manufacturing processes of thermoplastics due to its high degree of automation and the short cycle times. Micro injection moulding is a rapidly growing technology that allows for the efficient production of very complex micro parts in high series. The “Market Analysis for Microsystems II 2002–2005” of the Nexus Task Force anticipates a yearly growth in the field of micro system technology of about 20% (Wechsung et al. 2002). This study identifies in addition to the continuous miniaturization the growing use of polymers in micro systems (Schneider et al. 2001). No other material group offers this wide range of material properties and permits to choose processing parameters and application properties according to necessities (Gächter 2000). While the production processes of micro technical components are mainly controllable, the assembly of these components to hybrid micro systems is a bottleneck to the industrial large scale production. The assembly itself represents a large fraction of the added product value and gains in importance with growing complexity and miniaturization of the systems.     

鄂尔多斯市教育培训行业创业期管理要素研究

教育培训行业竞争日趋加剧,新创培训企业如何在竞争中脱颖而出成为许多创业期企业面临的问题。提出了影响教育培训行业创业期顺利开展的管理要素,以鄂尔多斯教育培训行业为例,通过对当地教育培训机构的调研和走访,得出相关数据并对其加以分析,从中找出了影响当地教育培训企业创业成功的关键要素,并对这些要素进行了进一步的理论分析,对具体的实施过程提出了对策和建议。     

阿塞尔轧管机组轧制规格范围的确定

总结了引进的阿塞尔轧管机热负荷试车及试生产情况。通过不同径壁比荒管的轧制，实现了扩径减壁、等径减壁和减径减壁三种轧制形式，从而确定了阿塞尔轧管机组的轧制规格范围。     

不同填料曝气生物滤池启动挂膜试验研究

不同填料曝气生物滤池在相同条件下进行挂膜试验。进水流向为上流式,挂膜方式为复合接种挂膜,即先用活性污泥闷曝接种,然后逐步提高进水流速,直到滤料表面形成稳定的生物膜。结果表明:33 d后挂膜成功,在温度为16～24℃,水力停留时间(HRT)为1 h,DO为6 mg/L的情况下,陶粒BAF对CODMn和NH3—N的去除率分别为23%和80%;沸石BAF的去除率分别为27%和84%;组合填料BAF去除效果最好,去除率分别为32%和92%。     

发动机初级工况对冷却夹套隔片损伤影响分析

针对可重复使用液体火箭发动机推力室冷却夹套隔片的损伤问题,为确保发动机的工作寿命,对建立了冷却夹套隔片的夹芯梁结构模型、粘塑性模型和细化损伤模型,发动机起动过程中初级工况给冷却夹套隔片损伤发展的影响进行了仿真计算。结果表明:初级工况过高,压力等性能参数振荡明显,振幅也较大,但引起的冷却夹套隔片损伤较小;初级工况选择过低,引起的冷却夹套隔片损伤较大,且压力等性能参数振荡也比较明显,但振幅较小。通过对比分析给出了用于发动机起动的合适初级工况,采用此工况使发动机起动过程中引起的损伤较小,而且压力等性能参数的振荡也较小。     

液力偶合器在惯性圆锥破碎机的应用研究

简述惯性圆锥破碎机的结构特点、运动分析及限矩型液力偶合器的结构传动原理，讨论了加装液力偶合器后所具有的功能。在此基础上，探讨其推广应用的可行性。     

Effects of initial sediment properties on start-up times for sediment microbial fuel cells

Sediment microbial fuel cells (SMFCs) are being developed as a renewable power source to aid environmental remediation and provide remote monitoring. But long start-up times limit their use as a viable industrial approach. In this study, we sampled sediments from seven different levels of eutrophication lakes and investigated the effects of their initial sediment properties (ISP) on the start-up times of SMFCs. After 60 days, ISP showed a clear influence on SMFCs with start-up times ranging from 7 to 21 days at different sampling sites. Organic matter, especially the labile carbon pools and nitrogen (organic and inorganic) contents in sediment, were closely related to start-up times for the SMFCs. In addition, dehydrogenase activity and high-throughput sequencing revealed that microorganisms in the nutrient enrichment sediments increased organic matter degradation and produced special species such as genus Candidatus Xiphinematobacter that belong to the Verrucomicrobia phyla related to electron transfer. Such active control may improve applicability by accelerating start-up and enhancing SMFC power and bio-catalytic performance.     

Fast start-up of a diesel fuel processor for PEM fuel cells

Fuel cell systems based on liquid fuels are particularly suitable for auxiliary power generation due to the high energy density of the fuel and its easy storage. Together with industrial partners, Oel-Waerme-Institut is developing a 3 kW_el PEM fuel cell system based on diesel steam reforming to be applied as an APU for caravans and yachts. The start-up time of a fuel cell APU is of crucial importance since a buffer battery has to supply electric power until the system is ready to take over. Therefore, the start-up time directly affects the battery capacity and consequently the system size, weight, and cost.     

UASB处理纤维素乙醇废水的启动运行研究

以厌氧UASB反应器处理纤维乙醇废水为研究对象,探讨分析了UASB的启动和稳定运行过程。结果表明,采用城市污水处理厂的厌氧消化污泥作为接种污泥,在COD有效容积负荷为0.33~1.11 kgCOD/(m3·d)的条件下,UASB反应器成功启动,COD的去除率达到70%以上。启动初期,出水pH会明显高于进水,污泥呈先减少后增加的趋势,当增加进水SO42-浓度到7 250 mg/L,COD/SO42-比值2.7∶1时,会导致纤维素乙醇废水UASB处理系统的崩溃。UASB反应器运行稳定后,污泥浓度增至30~40 g/L,MLVSS/MLSS比值也达到90%左右,在HRT为14~41 h,回流比3∶1~13∶1,有效容积负荷3.45~14.67 kg COD/(m3·d)的条件下,对纤维乙醇生产废水均能保持90%以上的COD去除率,出水COD小于1 000 mg/L。